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CAS: 86-93-1
分子式: C7H6N4S
分子量: 178.21
熔点: 143℃
中文名称: 
1-苯基-5-硫基四唑
1-苯基四氮唑-5-硫醇
5-巯基-1-苯基四氮唑
1-苯基-5-巯基四氮唑
苯基-硫醇-四唑
1-苯基-5-巯基四唑
1-苯基-1H-四唑-5-硫醇
5-疏基-1-苯基-四氮唑
1-苯基-5-巯基-1H-1,2,3,4-四氮唑
英文名称: 
1,2-dihydro-1-phenyl-5H-Tetrazole-5-thione
1-phenyl-1h-tetrazole-5-thio
1-phenyl-5-mercapto-1,2,3,4-tetrazole
1-phenyl-5-mercaptotetrazole
1-phenyltetrazole-5-thiol
5-mercapto-1-phenyltetrazole
1,2-dihydro-1-phenyl-5h-tetrazole-5-thion
mercaptophenyltetrazole
phenylmercaptotetrazole
1-phenyl-1h-tetrazole-5-thiol
1-phenyl-1tetrazole-5-thiol
1-phenyl-5-mercapto-tetranitrazole
5H-Tetrazole-5-thione,1,2-dihydro-1-phenyl-
1-Phenyltetrazoline-5-thiol
1-phenyl-5mercapto terazatle
5-Mercapto-1-phenyl-1H-tetrazole
1-Phenyl-5-mercapto-1H-tetrazole
展开更多英文名
性质描述: 白色结晶。熔点为150℃(分解)。溶于乙醇、氯仿、四氯化碳。
生产方法: 由异硫氰酸苯酯与叠氮化钠反应而得。将150ml水、67.5g异硫氰酸苯酯和9.8g叠氮化钠搅拌混合,回流反应至澄清为止,约需5-6h。经冷却,过滤得1-苯基四氮唑-5-硫醇钠盐(1-Phenyl-1H-tetrazole-5-thiol sodium salt [15052-19-4])将钠盐(滤液)用盐酸酸化至pH值为2,析出白色固体。滤出结晶,用水洗涤,烘干得粗品;用稀乙醇重结晶,得成品,收率在90%以上。
用途: 该品为照相防灰剂,也用作试剂及驱虫药的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
P831414MACKLIN5-疏基-1-苯基-四氮唑98%30元/5g;   58元/25g;   218元/100g;   965元/500g;   4798元/2.5kg;   展开
储存:室温,密封
状态:白色固体
P0640TCI5-Mercapto-1-phenyl-1H-tetrazole>98.0%(T)(HPLC)330元/25G;   920元/100G;   3050元/500G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C7H6N4S = 178.21
外观与形状(20℃)固体
Reaxys-RN609354
PubChem物质ID87574799
SDBS (AIST Spectral DB)3418
MDL编号MFCD00003129

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

熔点145 ℃(dec.)
溶解性(可溶于)丙酮,氯仿,醇

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H228 : 易燃固体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P241 : 使用防爆的电气/通风/照明设备。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#XF7700000

运输信息

UN编号UN1325
类别4.1
包装类别 II
监管条件代码(*)
287974J&K1-Phenyl-1H-tetrazole-5-thiol99%224元/25G;   740元/100G;   2556元/500G;   展开

基本信息

分子式C7H6N4S
分子量178.21
熔点145
MDL编码MFCD00003129
EINECS 编号201-710-5

安全信息

图形或危害标志
提示语Danger
危险说明H228
H302
防范说明P210
UN号码1325
危险分类4.1
包装等级II
WGK1
RTECSXF7700000
TSCA
A12656Alfa Aesar1-Phenyl-1H-tetrazole-5-thiol99%941元/25g;   3628元/100g;   15108元/500g;   展开

应用
1-Phenyl-1H-tetrazole-5-thiol is an effective inhibitor of aluminum corrosion in 1M HCl solution. 1-Phenyl-1H-tetrazole-5-thiol was used in the synthesis of oxacyclic building blocks via highly stereoselective radical cyclization and olefin metathesis reactions. It was also used in the synthesis of metalated tetradecyl sulfone. It is also used in the spectrophotometric determination of Pt and Bi.

备注
Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from oxidizing agents.

基本信息

MDL
MFCD00003129

EINECS
201-710-5

分子式
C7H6N4S

分子量
178.22

熔点
ca 145° dec.

闪点
138°(280°F)

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in 5% ethanol, water (partly), acetone, chloroform, and methanol.

Beilstein
139068

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H302
Flammable solid.Harmful if swallowed.

Precautionary Statements
P210-P280-P240-P241-P301+P312a-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves/protective clothing/eye protection/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.1

包装组
II

危险类别
11-22-44
Highly flammable.Harmful if swallowed.Risk of explosion if heated under confinement.

安全等级
7-16
Keep container tightly closed.Keep away from sources of ignition - No smoking.

欧盟危险品标志

RTECS
XF7700000

TSCA

580707Amethyst1-Phenyl-1H-tetrazole-5-thiol99%, 用于合成58元/5G;   134元/25G;   401元/100G;   1420元/500G;   展开

基本信息

分子式C7H6N4S
分子量178.21
熔点145
MDL编码MFCD00003129
EINECS 编号201-710-5

安全信息

图形或危害标志
提示语Danger
危险说明H228
H302
防范说明P210
UN号码1325
危险分类4.1
包装等级II
WGK1
RTECSXF7700000
TSCA
341759Fluorochem5-Mercapto-1-phenyl-1H-tetrazole95+%220元/1g;   220元/5g;   462元/25g;   1672元/100g;   展开

基本信息

CAS Number86-93-1
MDL NumberMFCD00003129

安全信息

图形或危害标志
危险性说明 H228: Flammable solid.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use CO2, dry powder or foam for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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