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关键词:       仅模糊查询
CAS: 86-73-7
分子式: C13H10
分子量: 166.22
沸点: 298℃
熔点: 112-116℃
中文名称: 
2,2'-亚甲基联苯
邻亚联苯基甲烷
甲基联苯
二亚苯基甲烷
芴
9H-芴
二苯并五环
二亚苯基甲烷
英文名称: 
Fluorene solution
Fluorene
9H-Fluorene
Diphenylenemethane
2,2'-methylenebiphenyl
2,3-benzindene
alpha-diphenylenemethane
diphenylene-methan
o-biphenylenemethane
o-biphenylmethane
2,2'-Methylemebiphemyl
Fluoren
展开更多英文名
性质描述: 白色小片状结晶，不纯时有荧光。熔点115-116℃，沸点297.9℃，闪点151℃，相对密度1.203，熔化热350J/g，蒸发热120.9J/g。不溶于水，溶于乙醇、乙醚、苯、二硫化碳等有机溶剂。在高真空易升华。
生产方法: 在高温焦油中的芴约含1.0-2.0%。从洗油馏分中切取290-310℃的芴馏分段，用相当于115块理论塔板的蒸馏塔进行精密分馏，回流比为15：1，切取292-302℃窄馏分。通过冷却，结晶，离心分离，得到粗芴，再用1：25的苯或二甲苯重结晶，则得工业芴。将工业芴溶于苯中，用40%的硫酸洗涤，再经中和水洗，脱溶，将芴重新蒸馏，馏出物用汽油和乙醇重结晶，得纯度为95%的纯芴。
用途: 用作有机合成原料。可制成三硝基芴酮，用于静电复印；合成芳基透明尼龙；可代替蒽醌合成阴丹士林染料；用于制造抗痉挛药、镇静药，镇痛药，降血压药；合成杀虫剂，除草剂；制备抗冲击有机玻璃和芴醛树脂；亦可用作湿润剂，洗涤剂，液体闪光剂，消毒剂等。
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货号品牌产品名称规格包装、参考价格详情
F809541MACKLIN芴99%33元/5g;   80元/25g;   171元/100g;   639元/500g;   展开
储存：室温
状态：白色到浅棕色结晶粉末
F809539MACKLIN芴97%30元/25g;   49元/100g;   186元/500g;   780元/2.5kg;   展开
储存：室温
状态：白色到灰白色固体
F809540MACKLIN芴Standard for GC,≥99%(HPLC)110元/1g;   展开
储存：室温
状态：白色至灰白色固体
F0017TCIFluorene>95.0%(GC)185元/25G;   390元/100G;   1410元/500G;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C13H10 = 166.22
外观与形状(20℃)固体
Reaxys-RN1363491
PubChem物质ID87569831
SDBS (AIST Spectral DB)1721
Merck Index (14)4155
MDL编号MFCD00001111

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 95.0 %
Melting point114.0 to 116.0 ℃
Solubility in Toluenealmost transparency

物性(参考值)

熔点115 ℃
沸点295 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P391 : 收集溢出物。

相关法规

RTECS#LL5670000

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
F0061TCIFluorene Zone Refined (number of passes:70)>99.5%(GC)895元/1SAMPLE;   展开

基本信息

纯度/分析方法>99.5%(GC)
分子式/分子量C13H10 = 166.22
外观与形状(20℃)固体
Reaxys-RN1363491
PubChem物质ID87569865
SDBS (AIST Spectral DB)1721
Merck Index (14)4155
MDL编号MFCD00001111

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 99.5 %
Melting point114.0 to 116.0 ℃

物性(参考值)

熔点115 ℃
沸点295 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P391 : 收集溢出物。

相关法规

RTECS#LL5670000

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
334723J&KFluorene98%114元/25G;   374元/100G;   1052元/500G;   展开

基本信息

分子式C13H10
分子量166.22
熔点112-116
沸点298
闪点151
密度1.2
MDL编码MFCD00001111
Beilstein1363491
Merck14,4155
EINECS 编号201-695-5

安全信息

图形或危害标志
提示语Warning
危险说明H410
防范说明P273
UN号码3077
危险分类9
包装等级III
WGK3
RTECSLL5670000
TSCA是
L02124Alfa AesarFluorene98+%309元/25g;   865元/100g;   3326元/500g;   展开

应用
Fluorene is used in the preparation of dyes such as 2,7-diiodofluorene, 2-aminofluorene and 3,6-bis-(dimethylamino)fluorine as well as resins. It acts as a precursor to other fluorene compounds and to prepare fluorenone. It is utilized in the study of the extraction of specific semiconducting single-wall carbon nanotubes. Its polymer, polyfluorene finds application in electrically conductive and electroluminescent as well as in solar cells. In addition to this, it is used as a luminophore inorganic light-emitting diodes

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00001111

EINECS
201-695-5

分子式
C13H10

分子量
166.22

熔点
113-117°

沸点
295°

闪点
151°(303°F)

密度
1.202

灵敏度
Ambient temperatures.

溶解性
Soluble in hot alcohol, ether, benzene and glacial acetic acid. Insoluble in water.

Beilstein
1363491

Merck
14,4155

GHS危害和防范说明

GHS符号

Hazard Statements
H400-H410
Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

安全信息

危险等级
9

包装组
III

危险类别
50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
60-61
This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
LL5670000

TSCA
是

C15613Alfa AesarFluorene98%400元/25g;   837元/100g;   3030元/500g;   展开

基本信息

Ref#
15613

MDL
1111

分子式
C13 H10

分子量
166.22

闪点
151

密度
1.2

形态
White crystalline powder

安全信息

危险等级
9

包装组
III

128333Sigma-AldrichFluorene98%452.89元/5 G;   604.87元/100 G;   1863.97元/500 G;   展开

产品说明

应用

芴被用来研究特定的、半导体单壁碳纳米管 (SWCNT) 的提取 。

包装

5 g in glass bottle
100, 500 g in poly bottle

基本信息

经验(实验)分子式C13H10
分子量166.22
Beilstein1363491
EC 号201-695-5
MDL编号MFCD00001111
PubChem化学物质编号24847846
NACRESNA.22

产品性质

质量水平100
测定98%
形式chunks
crystalline powder
crystals
powder
solid
bp298 ℃ (lit.)
mp111-114 ℃ (lit.)
SMILES stringC1c2ccccc2-c3ccccc13
InChI1S/C13H10/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)12/h1-8H,9H2
InChI keyNIHNNTQXNPWCJQ-UHFFFAOYSA-N

安全信息

象形图GHS09
警示用语：Warning
危险声明H410
预防措施声明P273 - P391 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)303.8 °F - closed cup
闪点(C)151.0 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type N95 (US)
56849SupelcoFluorenecertified reference material, TraceCERT®1614.69元/100 MG;   展开

产品说明

一般描述

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com.

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

法律信息

TraceCERT is a registered trademark of sigma-aldrich Co. LLC

基本信息

经验(实验)分子式C13H10
分子量166.22
Beilstein1363491
EC 号201-695-5
MDL编号MFCD00001111
PubChem化学物质编号329758242
NACRESNA.24

产品性质

质量水平300
等级certified reference material
TraceCERT®
产品线TraceCERT®
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
bp298 ℃ (lit.)
mp111-114 ℃ (lit.)
application(s)environmental
格式neat
SMILES stringC1c2ccccc2-c3ccccc13
InChI1S/C13H10/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)12/h1-8H,9H2
InChI keyNIHNNTQXNPWCJQ-UHFFFAOYSA-N

安全信息

象形图GHS09
警示用语：Warning
危险声明H410
预防措施声明P273 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)303.8 °F - closed cup
闪点(C)151.0 ℃ - closed cup
48568SupelcoFluoreneanalytical standard1039.51元/5000 MG;   展开

产品说明

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Fluorene has been used as a test material in studying its electronic transitions in gas and crystalline phases, and in stretched polymer sheets, measured with synchrotron radiation.

基本信息

经验(实验)分子式C13H10
分子量166.22
Beilstein1363491
EC 号201-695-5
MDL编号MFCD00001111
PubChem化学物质编号24872116

产品性质

等级analytical standard
CofAcurrent certificate can be downloaded
包装ampule of 5000 mg
technique(s)HPLC: suitable
gas chromatography (GC): suitable
bp298 ℃ (lit.)
mp111-114 ℃ (lit.)
application(s)environmental
格式neat
储存温度2-30℃
SMILES stringC1c2ccccc2-c3ccccc13
InChI1S/C13H10/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)12/h1-8H,9H2
InChI keyNIHNNTQXNPWCJQ-UHFFFAOYSA-N

安全信息

象形图GHS09
警示用语：Warning
危险声明H410
预防措施声明P273 - P391 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)303.8 °F - closed cup
闪点(C)151.0 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type N95 (US)
975097AmethystFluorene98%56元/25G;   展开

基本信息

分子式C13H10
分子量166.22
熔点112-116
沸点298
闪点151
密度1.2
MDL编码MFCD00001111
Beilstein1363491
Merck14,4155
EINECS 编号201-695-5

安全信息

图形或危害标志
提示语Warning
危险说明H410
防范说明P273
UN号码3077
危险分类9
包装等级III
WGK3
RTECSLL5670000
TSCA是
APP-9-109AccuStandardFluorene ,100 μg/mL in MeOH100 μg/mL in MeOH232元/1mL;   展开
Fluorene芴86-73-7100 µg/mL
APP-9-109-10XAccuStandardFluorene ,1000 μg/mL in MeOH1000 μg/mL in MeOH386元/1mL;   展开
Fluorene芴86-73-7100 µg/mL
AS-E0078AccuStandardFluorene ,5.0 mg/mL in MeOH5.0 mg/mL in MeOH494元/1mL;   展开
Fluorene芴86-73-75 mg/mL
H-146NAccuStandardFluorene402元/100mg;   展开
Fluorene芴86-73-7
M-8310-FL-12AccuStandardFluorene,0.5 mg/mL in Acetonitrile0.5 mg/mL in Acetonitrile309元/1mL;   展开
Fluorene芴86-73-7.5 mg/mL
Z-013-12AccuStandardFluorene,0.2 mg/mL in MeOH0.2 mg/mL in MeOH232元/1mL;   展开
Fluorene芴86-73-7.2 mg/mL
094650FluorochemFluorene98%220元/1g;   330元/25g;   594元/100g;   1276元/250g;   展开

基本信息

CAS Number86-73-7
MDL NumberMFCD00001111
Melting Point111-114℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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