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关键词:       仅模糊查询
CAS: 86-52-2
分子式: C11H9Cl
分子量: 176.64
沸点: 291-292℃
熔点: 20-22℃
中文名称: 
1-(氯甲基)萘
1-氯甲基萘
英文名称: 
Naphthalene,1-(chloromethyl)-
-Naphthylmethyl chloride
-Menaphthyl chloride
1-Chloromethylnaphthalene
1-(chloromethyl)-Naphthalene
1-chloromethyl-naphthalen
1-(chlormethyl)naftalen
1-chloromethyl naphthalene
1-menaphthyl chloride
1-naphthylmethyl chloride
alpha-(chloromethyl)naphthalene
alpha-naphthylmethyl chloride
1-(chloromethyl)-naphthalen
alpha-chloromethyl-naphthalen
1-(chloromethyl)naphthalene
展开更多英文名
性质描述: 叶状体结晶。熔点47℃，沸点168-170℃（2.67kPa）。溶于苯、乙醇。
生产方法: 由2-甲基萘经侧链氯化而得。将2-甲基萘和芳香族氯化物溶剂加热到190-210℃，在光照下边搅拌边通氯，反应得2-（氯甲基）萘。
用途: 农药、医药、助剂的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C0667TCI1-(Chloromethyl)naphthalene>95.0%(GC)(T)170元/25G;   1620元/500G;   展开

基本信息

纯度/分析方法>95.0%(GC)(T)
分子式/分子量C11H9Cl = 176.64
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解),加热
Reaxys-RN636885
PubChem物质ID87565757
SDBS (AIST Spectral DB)5939
MDL编号MFCD00004042

技术规格

AppearanceWhite or Colorless to Light yellow powder to lump to clear liquid
Purity(GC)min. 95.0 %
Purity(Argentometric Titration)min. 95.0 %

物性(参考值)

熔点28 ℃
沸点292 ℃
溶解性(可溶于)苯

安全信息

图形或危害标志
信号词危险
危险性说明H302 + H312 : 吞咽或皮肤接触有害。
H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

相关法规

RTECS#QJ2800000

运输信息

UN编号UN3261
类别8
包装类别 II
监管条件代码(*)
B24385Alfa Aesar1-(Chloromethyl)naphthalene94%943元/100g;   1378元/250g;   展开

应用
1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields.

备注
Store at room temperature. Incompatible with oxidizing agents and bases.

基本信息

MDL
MFCD00004042

EINECS
201-678-2

分子式
C11H9Cl

分子量
176.65

熔点
31-33°

沸点
291-292°

闪点
132°(270°F)

密度
1.181

折射率
1.6370

灵敏度
Ambient temperatures.

形态
Solid

溶解性
Insoluble in water.

Beilstein
636885

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H314-H318
Harmful if swallowed.Harmful in contact with skin.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
8

包装组
II

危险类别
21/22-34
Harmful in contact with skin and if swallowed.Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

RTECS
QJ2800000

TSCA
是

C10945Alfa Aesar1-(Chloromethyl)naphthalene95%610元/100g;   524元/5g;   2210元/500g;   展开

基本信息

Ref#
10945

MDL
4042

分子式
C11 H9 Cl

分子量
176.65

闪点
>110

密度
1.17

安全信息

危险等级
8

包装组
II

C54201Sigma-Aldrich1-(Chloromethyl)naphthalene90%533.26元/100 G;   展开

产品说明

包装

100 g in glass bottle

其他说明

残留物为 2-(氯甲基)萘

基本信息

线性分子式C10H7CH2Cl
分子量176.64
Beilstein636885
EC 号201-678-2
MDL编号MFCD00004042
PubChem化学物质编号24892781
NACRESNA.22

产品性质

质量水平100
测定90%
折射率n20/D 1.635 (lit.)
bp167-169 ℃/25 mmHg (lit.)
mp32 ℃ (lit.)
密度1.18 g/mL at 25 ℃ (lit.)
SMILES stringClCc1cccc2ccccc12
InChI1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2
InChI keyXMWGTKZEDLCVIG-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语：Danger
危险声明H302 + H312 - H314
预防措施声明P260 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)269.6 °F
闪点(C)132 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
25170Sigma-Aldrich1-(Chloromethyl)naphthalenetechnical, ≥97.0% (GC)655.68元/50 ML;   展开

产品说明

一般描述

Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.

包装

50 mL in glass bottle

基本信息

线性分子式C10H7CH2Cl
分子量176.64
Beilstein636885
EC 号201-678-2
MDL编号MFCD00004042
PubChem化学物质编号57648117
NACRESNA.22

产品性质

质量水平100
等级technical
测定≥97.0% (GC)
颜色deep brown
折射率n20/D 1.635 (lit.)
n20/D 1.635
bp167-169 ℃/25 mmHg (lit.)
mp32 ℃ (lit.)
密度1.18 g/mL at 25 ℃ (lit.)
SMILES stringClCc1cccc2ccccc12
InChI1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2
InChI keyXMWGTKZEDLCVIG-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语：Danger
危险声明H302 + H312 - H314
预防措施声明P260 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)269.6 °F
闪点(C)132 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
224633Fluorochem1-(Chloromethyl)naphthalene95%220元/1g;   286元/25g;   902元/100g;   展开

基本信息

CAS Number86-52-2
MDL NumberMFCD00004042
Density1.18

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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