| CAS: | 856407-37-9 | ||
| 分子式: | C25H23P | ||
| 分子量: | 354.423881 | ||
| 沸点: | 505.6±50.0 °C | ||
| 熔点: | 148-149 °C | ||
| 中文名称: |
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| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |||
| R906297 | MACKLIN | (11aR)-5,6,10,11,12,13-六氢-5-苯基-4H-二茚并[7,1-cd:1',7'-ef]磷 | 98% | 499元/10mg; | 咨询 | ||
储存：2-8°C 状态：白色到灰白色固体 | |||||||
| 15-5184 | Strem | (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin | min. 97% | 1500元/25mg; 4500元/100mg; | 咨询 | ||
Technical Notes: 1.Chiral catalyst for the intra and intermolecular v addition of nitrogen nucleophiles to Y substituted alkynoates or allenoates. 2.Phosphine catalyzed ß ,v-umpolung domino reaction of allenic es ters: facile synthesis of tetrahydrobenzofuranones bearing a chiral tetrasubstituted stereogenic carbon center. 3.Phosphine catalyzed highly enantiose;ective 3 +3cycloaddition of Morita- B aylis -Hillman c arbonates with C,N-cyclic azomethine imines . References : 1. Angew. Chom. Int. Ed.. 2013, 52,. 2525. 2.Angew. Chem. Int. Ed., 2015, 54, 1511. 3. J, Am. Chom. Soc, 2015, 137, 4316. | |||||||
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