| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| T819841 | MACKLIN | 三(4-甲氧苯基)膦 | 95% | 25元/1g; 48元/5g; 231元/25g; 761元/100g; 3710元/500g; | 展开 |
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| T0861 | TCI | Tris(4-methoxyphenyl)phosphine | >97.0%(T) | 280元/5G; 1200元/25G; | 展开 |
基本信息 | 纯度/分析方法 | >97.0%(T) | | 分子式/分子量 | C21H21O3P = 352.37 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 2815911 | | PubChem物质ID | 87576691 | | SDBS (AIST Spectral DB) | 7594 | | MDL编号 | MFCD00014896 |
技术规格 | Appearance | White to Yellow to Orange powder to crystal | | Purity(Iodometric Titration) | min. 97.0 % | | Melting point | 130.0 to 135.0 ℃ |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 265496 | J&K | Tris(4-methoxyphenyl)phosphine | 95% | 181元/1G; 722元/5G; | 展开 |
基本信息 | 分子式 | C21H21O3P | | 分子量 | 352.37 | | 熔点 | 131-134 | | MDL编码 | MFCD00014896 | | EINECS 编号 | 212-723-0 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| 15-8000 | Strem | Tris(p-methoxyphenyl)phosphine | 98% | 528元/1g; 1862元/5g; | 展开 |
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| A15596 | Alfa Aesar | Tris(4-methoxyphenyl)phosphine | 98% | 728元/1g; 2882元/5g; 7969元/25g; | 展开 |
应用
It is employed in Suzuki reaction. It is also used in the kinetic study of the effect of catalysts on the curing of biphenyl epoxy resin. 备注
Air sensitive. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. 基本信息 MDL
MFCD00014896 EINECS
212-723-0 分子式
C21H21O3P 分子量
352.37 熔点
130-132° 灵敏度
Air Sensitive. Ambient temperatures. 形态
Crystalline powder 溶解性
Insoluble in water. Beilstein
2815911 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
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| C42224 | Alfa Aesar | Tris(4-methoxyphenyl)phosphine | 95% | 773元/1g; 5159元/10g; | 展开 |
基本信息 Ref#
42224 MDL
14896 分子式
C21 H21 O3 P 分子量
352.36 形态
Crystalline |
| 395102 | Sigma-Aldrich | Tris(4-methoxyphenyl)phosphine | 95% | 185.39元/1 G; 593.84元/5 G; | 展开 |
基本信息 | 线性分子式 | (CH3OC6H4)3P | | 分子量 | 352.36 | | EC 号 | 212-723-0 | | MDL编号 | MFCD00014896 | | PubChem化学物质编号 | 24864644 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 95% | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings | | mp | 131-134 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | COc1ccc(cc1)P(c2ccc(OC)cc2)c3ccc(OC)cc3 | | InChI | 1S/C21H21O3P/c1-22-16-4-10-19(11-5-16)25(20-12-6-17(23-2)7-13-20)21-14-8-18(24-3)9-15-21/h4-15H,1-3H3 | | InChI key | UYUUAUOYLFIRJG-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 930448 | Amethyst | Tris(4-methoxyphenyl)phosphine | 95%, 用于合成 | 65元/1G; 176元/5G; 526元/25G; 1733元/100G; | 展开 |
基本信息 | 分子式 | C21H21O3P | | 分子量 | 352.37 | | 熔点 | 131-134 | | MDL编码 | MFCD00014896 | | EINECS 编号 | 212-723-0 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| 216528 | Fluorochem | Tris(4-methoxyphenyl)phosphine | 95% | 462元/1g; 858元/5g; 1452元/10g; 2882元/25g; | 展开 |
基本信息 | CAS Number | 855-38-9 | | MDL Number | MFCD00014896 | | Melting Point | 133℃ |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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