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CAS: 851942-89-7
分子式: C42H36BrF6N
分子量: 748.64
熔点: 224-229 °C
中文名称: 
(11bs)-(+)-4,4-二丁基-4,5-二氢-2,6-双(3,4,5-三氟苯基)-3h-二萘[2,1-c:1′,2′-e]氮杂卓溴化物
(11bs)-(+)-4,4-dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3h-dinaphth[2,1-c:1′,2′-e]azepinium bromide
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货号品牌产品名称规格包装、参考价格
S983663MACKLIN(11bS)-(+)-4,4-二丁基-4,5-二氢-2,6-双(3,4,5-三氟苯基)-3H-二萘[2,1-c:1′,2′-e]氮杂卓溴化物≥98%2836元/50mg;   咨询
储存:2-8°C, 密封, 干燥
07-0381Strem(11bS)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide3480元/50mg;   15240元/250mg;   咨询

Technical Notes:

1.2nd Generation Maruoka chiral phase transfer catalyst, for enantios elective alkylation of a-amino acid derivatives, that is easily recycled by extraction with fluorous solvent.

2.Catalyst for asymmetric conjugate addition of a-substituted-a-cyanoacetates to a,ß-unsaturated acetylenic esters .

3.Phase transfer catalyzed enantioselective a-alkylation.

4.Asymmetric amination of ß-keto esters.

5.Diastereo- and enantioselective conjugate addition of a-substituted nitroacetates to maleimides .

6.Efficient asymmetric synthesis of spiro-2(3H)-furanones via phase-transfer-catalyzed alkynylation.

7.Phase-transfer catalyzed asymmetric synthesis of a,ß-unsaturated v,y-disubstituted y-lactams.

677086Sigma-Aldrich(11bS)-(+)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide2752.75元/50 MG;   咨询

基本信息

经验(实验)分子式C42H36BrF6N
分子量748.64
MDL编号MFCD09264271
PubChem化学物质编号24885352
NACRESNA.22

产品性质

mp224-229 ℃
SMILES stringCCCC[N+]1(CCCC)Cc2c(cc3ccccc3c2-c4c(C1)c(cc5ccccc45)-c6cc(F)c(F)c(F)c6)-c7cc(F)c(F)c(F)c7
InChI1S/C42H36F6N.BrH/c1-3-5-15-49(16-6-4-2)23-33-31(27-19-35(43)41(47)36(44)20-27)17-25-11-7-9-13-29(25)39(33)40-30-14-10-8-12-26(30)18-32(34(40)24-49)28-21-37(45)42(48)38(46)22-28;/h7-14,17-22H,3-6,15-16,23-24H2,1-2H3;1H/q+1;/p-1
InChI keyLOMUZNOWQYZTRP-UHFFFAOYSA-M

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
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