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CAS: 85-85-8
分子式: C15H11N3O
分子量: 249.28
熔点: 138-141℃
中文名称: 
1-(2-联氮吡啶)-2-萘酚
1-(2-吡啶偶氮)-2-萘酚
英文名称: 
2-Naohthalenol,1-(2-pyridinylazo)-
1-(2-pyridinylazo)-2-Naohthalenol
1-(2-Pyridylazo)-2-naphthol
1-(2-pyridinylazo)-2-naphthaleno
性质描述: 橙红色无定形粉末。熔点141℃,溶于甲醇、乙醇、苯、醚、氯仿和热稀碱液,不溶于水。溶液在pH12以上时呈粉红色,在弱酸中呈橙红色,在浓硫酸中呈紫色。其金属络合物呈粉红色或红色。
生产方法: 由2-氨基吡啶经重氮化后,与2-萘酚偶合而得。将无水乙醇与金属钠反应生成乙醇钠,然后加入2-氨基吡啶的乙醇溶液,通入亚硝酸乙酯蒸气于45-50℃反应。能毕,保温8小时,过滤出重氮盐用乙醚洗涤。将重氮盐加入2-萘酚的乙醇溶液中,在45-50℃通入二氧化碳进行偶合反应,6小时后过滤出结晶,用蒸馏水洗涤后再用乙醇重结晶,干燥即为成品。
用途: 该品为络合指标剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
P991924MACKLINPAN指示剂0.2g/L in Ethanol65元/100ml;   展开
储存:2-8°C
状态:液体
P991923MACKLINPAN指示剂1g/L in Ethanol69元/100ml;   220元/500ml;   展开
储存:2-8°C
状态:液体
P991922MACKLINPAN指示剂2g/L in Ethanol69元/100ml;   220元/500ml;   展开
储存:2-8°C
状态:液体
P997287MACKLIN1-(2-吡啶偶氮)-2-萘酚(PAN)95%39元/1g;   122元/5g;   382元/25g;   1022元/100g;   展开
储存:室温
状态:浅黄色到琥珀色到深绿色和橙色到非常暗橙色和棕色和暗红色-橙色和非常暗红棕色粉末或晶体或块状
P815771MACKLIN1-(2-吡啶偶氮)-2-萘酚(PAN)98%68元/1g;   212元/5g;   799元/25g;   2405元/100g;   展开
储存:室温
状态:橙色到红色或棕色粉末
P815770MACKLIN1-(2-吡啶偶氮)-2-萘酚(PAN)试剂级, 90.0%30元/1g;   72元/5g;   172元/25g;   362元/100g;   1442元/500g;   展开
储存:室温
状态:橙色到红棕色到棕色粉末或晶体
A5000TCIPAN [=1-(2-Pyridylazo)-2-naphthol] [Metal indicator and spectrophotometric reagent for transition metals]>98.0%(T)(HPLC)355元/1G;   990元/5G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C15H11N3O = 249.27
外观与形状(20℃)固体
Reaxys-RN480206
PubChem物质ID87563094
SDBS (AIST Spectral DB)5040
MDL编号MFCD00004071

技术规格

AppearanceLight yellow to Amber to Dark green powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 98.0 %
Melting point138.0 to 143.0 ℃
Absorbancemin. 0.600(10mg/L, Methanol, 463.0 to 467.0 nm)
Solubility in Methanolalmost transparency
SensitivenessColoring by copper sulfate solution. Fading by EDTA2Na.

物性(参考值)

熔点142 ℃
水溶性实际上不溶
溶解性(可溶于)氯仿,乙醚,醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
A17475Alfa Aesar1-(2-Pyridylazo)-2-naphthol98%335元/1g;   1061元/5g;   4120元/25g;   展开

应用
1-(2-Pyridylazo)-2-naphthol is widely used as an indicator for complexometry. It is used as a reagent for the extraction and spectrophotometric determination (for colorimetric analysis) of many transition metal elements like arsenic, chromium, cobalt, copper, cadmium, manganese, zinc and zirconium. It is also used for the analysis of uranium and thorium in solutions.

备注
Incompatible with strong bases and strong oxidizing agents.

基本信息

MDL
MFCD00004071

EINECS
201-637-9

分子式
C15H11N3O

分子量
249.27

熔点
138-141°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Insoluble in water.

Beilstein
206390

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

C14631Alfa Aesar1-(2-Pyridylazo)-2-naphthol98%, pure, indicator grade2716元/5g;   4382元/10g;   13235元/50g;   展开

基本信息

Ref#
14631

MDL
4071

分子式
C15 H11 N3 O

分子量
249.27

形态
Powder

P381-5Alfa AesarPAN INDICATOR CERTIFIED 5G1537元/5g;   展开

基本信息

Ref#
F52713

1.07531Supelco1-(2-Pyridylazo)-2-naphthol (PAN)metal indicator Reag. Ph Eur2244.11元/5 G;   展开

产品说明

分析说明

Identity (UV/VIS-Spectrum): passes test
Appearance: brick-red to orange-brown fine powder,eventually cohesive
Appearance of solution (1.0 g/l; ethanol): Clear to almost clear, red-orange to brown-orange
Melting point: 136 - 141 °C
Absorption maximum λmax. (Ethanol): 461 - 465 nm
Spec. Absorptivity A 1%/1cm (λmax; 0.01 g/l; Ethanol): 670 - 720
Suitability as indicator (for metal titration): passes test
Sensitivity test (Reag. Ph Eur): passes test

基本信息

经验(实验)分子式C15H11N3O
分子量249.27
MDL编号MFCD00004071
EC索引号201-637-9

产品性质

agencyreag. Ph. Eur.
质量水平200
mp136-141 ℃
堆积密度190 kg/m3
储存温度2-30℃
InChI1S/C15H11N3O/c19-13-9-8-11-5-1-2-6-12(11)15(13)18-17-14-7-3-4-10-16-14/h1-10H,(H,16,17)/b18-15-
InChI keyRAXUMGMWXZYADR-SDXDJHTJSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
101036Sigma-Aldrich1-(2-Pyridylazo)-2-naphtholindicator grade1956.6元/5 G;   6410.6元/25 G;   展开

产品说明

一般描述

1-(2-吡啶偶氮)-2-萘酚 (PAN) 是一种橙色染料,常用作酸碱指示剂。它能与金属离子形成螯合物,是络合滴定中的一种有价值的指示剂。PAN 也是一种分光光度法试剂,可将金属螯合物萃取到有机溶剂中。

包装

5, 25 g in glass bottle

基本信息

经验(实验)分子式C15H11N3O
分子量249.27
Beilstein206390
EC 号201-637-9
MDL编号MFCD00004071
PubChem化学物质编号24846530
NACRESNA.47

产品性质

质量水平200
等级indicator grade
technique(s)titration: suitable
颜色 green to red, upon chelation with metal
orange-red, as an amorphous solid
yellow, when dissolved in organic solvent
mp138-141 ℃ (lit.)
λmax462 nm
SMILES stringOc1ccc2ccccc2c1\N=N\c3ccccn3
InChI1S/C15H11N3O/c19-13-9-8-11-5-1-2-6-12(11)15(13)18-17-14-7-3-4-10-16-14/h1-10,19H/b18-17+
InChI keyLLYOXZQVOKALCD-ISLYRVAYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
969978Amethyst1-(2-Pyridylazo)-2-naphthol90%, 用于分析122元/5G;   344元/25G;   展开

基本信息

分子式C15H11N3O
分子量249.27
熔点138-141
MDL编码MFCD00004071
Beilstein206390
EINECS 编号201-637-9

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
UN号码3234
危险分类4.1
WGK3
TSCA
463605Fluorochem1-(Pyridin-2-yldiazenyl)naphthalen-2-ol95%418元/1g;   1144元/5g;   4268元/25g;   15884元/100g;   展开

基本信息

CAS Number85-85-8
MDL NumberMFCD00004071

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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