| CAS: | 849950-53-4 | ||
| 分子式: | C42H48BF4P2Rh | ||
| 分子量: | 804.49 | ||
| 中文名称: |
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| 英文名称: |
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| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |||
| B975102 | MACKLIN | 1,2-二[(2S,5S)-2,5-二苯基磷杂环戊烷基]乙烷(1,5-环辛二烯)铑(I)四氟硼酸盐 | 98% | 261元/50mg; 341元/100mg; 834元/250mg; | 咨询 | ||
储存：2-8°C, 惰性气体 | |||||||
| 45-0202 | Strem | (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | min. 98% | 1543元/100mg; 6590元/500mg; 23100元/2g; | 咨询 | ||
Technical Notes: 1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation. 2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides. 3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents. 4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins. References: 1. Org. Lett., 2003, 5, 1273. 2. Tetrahedron Lett, 2004, 45, 9277. 3. Angew. Chem. Int. Ed., 2005, 44, 5834. | |||||||
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