CAS 84680-95-5; 1,1'-双(二-叔丁基膦基)二茂铁; 1,1'-Bis(di-tert-butylphosphino)ferrocene

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CAS:

84680-95-5

分子式:

C₂₆H₄₄FeP₂

分子量:

474.43

熔点:

181-182°C (dec.)

中文名称:

1,1'-双(二-叔丁基膦基)二茂铁

英文名称:

1,1'-Bis(di-tert-butylphosphino)ferrocene

Bis[(di-tert-butylphosphino)cyclopentadienyl]iron

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货号

品牌

产品名称

规格

包装、参考价格

详情

B801912

MACKLIN

1,1'-双(二叔丁基膦基)二茂铁

98%

26元/250mg; 34元/1g; 97元/5g; 481元/25g;

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储存：室温
状态：橙色到红色和/或块状粉末,固体,晶体

B2711

TCI

1,1'-Bis(di-tert-butylphosphino)ferrocene

>95.0%(T)

205元/100MG; 1130元/1G;

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基本信息

纯度/分析方法	>95.0%(T)
分子式/分子量	C₂₆H₄₄FeP₂ = 474.43
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气
PubChem物质ID	87558722

技术规格

Appearance	Orange to Amber to Dark red powder to crystal
Purity(Chelometric Titration)	min. 95.0 %
Melting point	73.0 to 77.0 ℃

物性(参考值)

熔点

75 ℃

26-0150

Strem

1,1'-Bis(di-t-butylphosphino)ferrocene

min. 98%

617元/500mg; 1980元/2g; 7920元/10g;

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Technical Notes:

1.Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular he teroannulation.

2.Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions .

3.Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing Y-coupling products .

4.Ligand for the copper-catalyzed system for the ß-boration of of a variety of a,ß-unsaturated amides.

5.Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium- catalyzed a-arylation.

6.Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.

7.Ligand for the palladium-catalyzed ßC-glycosylation by decarboxylative allylation to normal pyran systems, and cis-2,6-disubstituted tetrahydropyrans.

8.Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation .

9.Ligand for the copper- DTBPF catalyzed cH activation and carboxylation of terminal alkynes.

695149

Sigma-Aldrich

dtbpf

1370.42元/1 G;

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产品说明

包装

1 g in glass bottle
250 mg in glass bottle

应用

形成二烯络合物；羰基插入；环加成；还原和脱氧。

基本信息

经验(实验)分子式	C₂₆H₄₄FeP₂
分子量	474.42
MDL编号	MFCD01630818
PubChem化学物质编号	329761720
NACRES	NA.22

产品性质

reaction suitability	reagent type: catalyst reaction type: Cross Couplings reagent type: ligand reaction type: Arylations reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction reagent type: ligand reaction type: Indole Forming Reactions reagent type: ligand reaction type: Suzuki-Miyaura Coupling
质量水平	100
mp	73-75 ℃
官能团	phosphine
SMILES string	[Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]2[CH][CH][CH][CH]2)C(C)(C)C
InChI	1S/2C13H22P.Fe/c21-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h27-10H,1-6H3;
InChI key	FPLSJBJGQLJLSV-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

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