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CAS: 832-53-1
分子式: C6F5ClO2S
分子量: 266.57
沸点: 210-211 °C(lit.)
英文名称: 
Pentafluorobenzenesulfonyl chloride
Benzenesulfonyl chloride,pentafluoro-
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货号品牌产品名称规格包装、参考价格详情
P835738MACKLIN五氟苯磺酰氯98%73元/1g;   237元/5g;   735元/25g;   2837元/100g;   展开
储存:室温
状态:无色到浅黄色液体
折射率:n20/D 1.479(lit.)
P0934TCIPentafluorobenzenesulfonyl Chloride>98.0%(GC)605元/5G;   2235元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C6ClF5O2S = 266.57
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN2142325
PubChem物质ID87575051
SDBS (AIST Spectral DB)18090
MDL编号MFCD00007427

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点210 ℃
闪点90 ℃
比重1.81
折射率1.48

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H227 : 可燃液体。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3265
类别8
包装类别 II
监管条件代码(*)
285666J&KPentafluorobenzenesulfonyl Chloride97.5%168元/1G;   587元/5G;   2036元/25G;   展开

基本信息

分子式C6ClF5O2S
分子量266.57
沸点210-211
闪点90
密度1.796
折光率(n20D)1.4790
MDL编码MFCD00007427
Beilstein2142325
EINECS 编号212-620-0

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3265
危险分类8
包装等级II
WGK3
TSCA
A17676Alfa Aesar2,3,4,5,6-Pentafluorobenzenesulfonyl chloride98+%639元/1g;   1700元/5g;   7712元/25g;   展开

应用
Pentafluorobenzenesulfonyl chloride is used as derivatizing reagent for simultaneous determination of fluoxetine and p-trifluoromethylphenol, an O-dealkylated metabolite of fluoxetine in human liver microsomes. It is also used for electrophore labeling of small tyrosyl peptides for their analysis by gas chromatography with electron-capture detection. It is also employed as derivatizing reagent for amphetamine in determination of amphetamine in human plasma samples using gas chromatography with electron-capture detection.

备注
Moisture Sensitive. Store away from oxidizing agents, active metals and bases, water/moisture. Keep the container tightly closed in a cool, dry place. Store under inert gas.

基本信息

MDL
MFCD00007427

EINECS
212-620-0

分子式
C6ClF5O2S

分子量
266.57

沸点
210-211°

闪点
90°(194°F)

密度
1.796

折射率
1.4790

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Soluble in water (reacts slowly).

Beilstein
2142325

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

C14711Alfa AesarPentafluorobenzenesulfonyl Chloride99%5725元/25g;   557元/1g;   1367元/5g;   展开

基本信息

Ref#
14711

MDL
7427

分子式
C6 Cl F5 O2 S

分子量
266.57

闪点
90

密度
1796

形态
Colourless liquid

安全信息

危险等级
8

包装组
II

103764Sigma-AldrichPentafluorobenzenesulfonyl Chloride99%722.53元/5 G;   2635.49元/25 G;   展开

产品说明

一般描述

Pentafluorobenzenesulfonyl chloride reacts with benzene and thiophene derivatives in the presence of a ruthenium (II) catalyst to form corresponding perfluorophenylated compounds.

应用

Pentafluorobenzenesulfonyl chloride was used as derivatizing reagent for simultaneous determination of fluoxetine and p-trifluoromethylphenol, an O-dealkylated metabolite of fluoxetine in human liver microsomes. Pentafluorobenzenesulfonyl chloride was used for electrophore labeling of small tyrosyl peptides for their analysis by gas chromatography with electron-capture detection.

包装

5, 25 g in ampule

生化/生理作用

Pentafluorobenzenesulfonyl chloride is derivatizing reagent for amphetamine in determination of amphetamine in human plasma samples using gas chromatography with electron-capture detectio.

基本信息

线性分子式C6F5SO2Cl
分子量266.57
Beilstein2142325
EC 号212-620-0
MDL编号MFCD00007427
PubChem化学物质编号24846621
NACRESNA.22

产品性质

质量水平200
测定99%
折射率n20/D 1.479 (lit.)
bp210-211 ℃ (lit.)
密度1.796 g/mL at 25 ℃ (lit.)
SMILES stringFc1c(F)c(F)c(c(F)c1F)S(Cl)(=O)=O
InChI1S/C6ClF5O2S/c7-15(13,14)6-4(11)2(9)1(8)3(10)5(6)12
InChI keyUOJCTEGNHXRPKO-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
危险分类Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)194.0 °F - closed cup
闪点(C)90 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
006949FluorochemPentafluorobenzenesulfonyl Chloride99%220元/1g;   638元/5g;   1870元/25g;   展开

基本信息

CAS Number832-53-1
MDL NumberMFCD00007427
Boiling Point210-211℃
Density1.797

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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