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CAS: 828927-96-4
分子式: C38H30N3P
分子量: 559.6400  
中文名称: 
(S)-(-)-4-[2-(二苯基膦)- 1 -萘]- n-[(R)- 1-苯乙基] -1-二氮杂萘胺
英文名称: 
(S)-(-)-4-[2-(diphenylphosphino)-1-naphthalenyl]-n-[(R)-1-phenylethyl]-1-phthalazinamine
推荐供应商
货号品牌产品名称规格包装、参考价格
S946364MACKLIN(S)-4-[2-(二苯基膦)-1-萘]-N-[(R)-1-苯乙基]-1-二氮杂萘胺98%500元/100mg;   1196元/250mg;   4768元/1g;   咨询
储存：2-8°C
15-1786Strem(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinaminemin. 97%1695元/250mg;   5085元/1g;   咨询

Technical Notes:

1.. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)

2. With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.

3.With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.

References:

1.Angew. Chem. Int. Ed., 2004, 43, 5971.

2.Org. L ett 2006, 8, 2437

3.J. Am. Chem. Soc., 2005, 127, 9682.

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