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CAS: 823-96-1
分子式: C3H9B3O3
分子量: 125.54
沸点: 78-80℃
熔点: -38-38℃
中文名称: 
三甲基环三硼氧烷
三甲基硼氧环烷
英文名称: 
2,4,6-Trimethyl-cyclotriboroxane
trimethylboroxin,
trimethylboroxin,mbx,in tetrahydrofuran
trimethylboroxin,mbx,intetrahydrofuran
trimethylboroxine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T875631MACKLIN三甲基环三硼氧烷3.5mol/L(50wt.%)inTHF601元/25ml;   展开
储存:室温,易燃物区域
状态:无色到黄色液体
折射率:n20/D 1.362(lit.)
106089J&KTrimethylboroxine, 3.5 M solution in THF3.5 M 四氢呋喃溶液1749元/25ML;   5466元/100ML;   展开

基本信息

分子式C3H9B3O3
分子量125.53
熔点-38
沸点78-80
闪点-9
密度0.89
MDL编码MFCD00013354
Beilstein1757008

安全信息

图形或危害标志
提示语Danger
危险说明EUH019
H225
H315
H318
H335
防范说明P210
P240
P261
P280
P302+P352
P305+P351+P338
P310
UN号码2924
危险分类3
次要危险性8
包装等级II
WGK3
C29752Alfa AesarTrimethylboroxine3.5M (50 wt.%) solution in THF6542元/25ml;   15517元/100ml;   展开

基本信息

Ref#
29752

MDL
13354

分子式
C3 H9 B3 O3

分子量
125.54

闪点
-9

密度
0.89

安全信息

危险等级
3

包装组
II

C42919Alfa AesarTrimethylboroxine3.5M (50 wt.%) solution in THF, AcroSeal™11323元/100ml;   展开

基本信息

Ref#
42919

MDL
13354

分子式
C3 H9 B3 O3

分子量
125.54

闪点
-9

密度
0.89

安全信息

危险等级
3

包装组
II

903965Sigma-AldrichTrimethylboroxine50% THF solution314.14元/5 ML;   1492.17元/25 ML;   6752.32元/250 ML;   展开

产品说明

应用

Trimethylboroxine (TMB) is a cyclic anhydride of methyl-boronic acid. It can be used as a:

  • Methylating agent for the methylation of various aromatic halides and C(sp3)−H bonds using palladium catalyst.
  • Reagent in the preparation of polymer supported CBS (Corey, Bakshi, and Shibata) catalysts.

其他说明

Organoboranes. 39. Convenient procedures for the preparation of methylboronic acid and trimethylboroxin

基本信息

经验(实验)分子式C3H9B3O3
分子量125.53
MDL编号MFCD00013354

产品性质

形式liquid
折射率n/D 1.3880
密度0.89962 g/mL

安全信息

象形图GHS02GHS05GHS07GHS08
警示用语:Danger
危险声明H225 - H314 - H335 - H351
预防措施声明P201 - P210 - P233 - P261 - P280 - P370 + P378
危险分类Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
补充剂危害EUH019
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)-5.8 °F
闪点(C)-21 ℃
967396AmethystTrimethylboroxine, for synthesis, 3.5 M solution in THF用于合成, 3.5 M 四氢呋喃溶液147元/5ML;   473元/25ML;   854元/100ML;   展开

基本信息

分子式C3H9B3O3
分子量125.53
熔点-38
沸点78-80
闪点-9
密度0.89
MDL编码MFCD00013354
Beilstein1757008

安全信息

图形或危害标志
提示语Danger
危险说明EUH019
H225
H315
H318
H335
防范说明P210
P240
P261
P280
P302+P352
P305+P351+P338
P310
UN号码2924
危险分类3
次要危险性8
包装等级II
WGK3
513169FluorochemTRIMETHYLBOROXINE (W/W 50% SOLUTION IN THF)95%374元/1g;   1562元/5g;   4686元/25g;   11704元/100g;   展开

基本信息

CAS Number823-96-1
MDL NumberMFCD00013354
Boiling Point78 - 80 ℃
Melting Point-38 ℃
Density0.898

安全信息

图形或危害标志
危险性说明 H225: Highly flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
防范说明 P210: Keep away from – No smoking.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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