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CAS: 822-87-7
分子式: C6H9ClO
分子量: 132.59
沸点: 82-83℃(1
熔点: 23-83℃
中文名称: 
2-氯环己酮
英文名称: 
2-chlorocyclohexanone
alpha-chlorocyclohexanone
2-chloro-cyclohexanon
2-chloro-cyclohexanone
2-Chloro-1-cyclohexanone
性质描述: 熔点22-23℃,沸点90-91℃(1.86Pa-2kPa),82-83℃(1.33kPa),79℃(0.93kPa),相对密度1.161(20/15℃),折光率1.4825。闪点82℃。
生产方法: 由环己酮经氯化而得。将氯气通入环己酮水溶液进行氯化,反应结束后分出2-氯环己酮液层,水层用乙醚提取。提取液与氯环己酮液层合并,先用水洗,再用氯化钠饱和溶液洗,以无水硫酸钠干燥。过滤后蒸去乙醚,再进行减压蒸馏,收集2-氯环己酮馏分。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C804464MACKLIN2-氯环己酮>95.0%(GC) ,含0.2 % CaCO3/MgO (1:1)稳定剂39元/2g;   121元/10g;   510元/50g;   1998元/250g;   展开
储存:2~8°C
状态:白色到黄色到棕色和无色到黄色到棕色固体或液体
折射率:n20/D 1.484(lit.)
C0965TCI2-Chlorocyclohexanone (stabilized with HQ + CaCO3)>96.0%(GC)490元/25G;   展开

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C6H9ClO = 132.59
外观与形状(20℃)液体
储存温度<0℃
应避免的情况加热
Reaxys-RN774100
PubChem物质ID87566010
SDBS (AIST Spectral DB)15187
MDL编号MFCD00001626

技术规格

AppearanceWhite or Colorless to Yellow powder to lump to clear liquid
Purity(GC)min. 96.0 %

物性(参考值)

熔点20 ℃
沸点107 ℃/50 mmHg
闪点82 ℃
比重1.16
折射率1.48

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H317 : 可能造成皮肤过敏反应。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P272 : 受沾染的工作服不得带出工作场地。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#GW1225000
414244J&K2-Chlorocyclohexanone95%104元/5G;   392元/25G;   1292元/100G;   展开

基本信息

分子式C6H9ClO
分子量132.59
熔点23
沸点82-83
闪点82
密度1.161
折光率(n20D)1.4840
MDL编码MFCD00001626
Beilstein774100
EINECS 编号212-505-5
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H315
H317
H319
H335
防范说明P261
P280
P305+P351+P338
WGK3
RTECSGW1225000
TSCA
A18613Alfa Aesar2-Chlorocyclohexanone97%, stab. with calcium carbonate/magnesium oxide666元/10g;   2332元/50g;   9223元/250g;   展开

应用
2-Chlorocyclohexanone, is an intermediate in the synthesis of variety of pharmaceutical compounds. It is also an intermediate in the synthesis of 1-Chloro-2-methylenecyclohexane .

备注
Store away from oxidizing agents and heat. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep refrigerated at -20?°C.

基本信息

MDL
MFCD00001626

EINECS
212-505-5

分子式
C6H9ClO

分子量
132.59

熔点
22-24°

沸点
82-83°/10mm

闪点
82°(180°F)

密度
1.161

折射率
1.4840

灵敏度
Store at -20°C. Store under Argon.

形态
Liquid

溶解性
Insoluble in water.

Beilstein
774100

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H317-H335
Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38-43
Irritating to eyes, respiratory system and skin.May cause sensitization by skin contact.

安全等级
24-26-37-60
Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
GW1225000

TSCA

C10896Alfa Aesar2-Chlorocyclohexanone95%, stabilized457元/5g;   1381元/25g;   4914元/100g;   展开

基本信息

Ref#
10896

MDL
1626

分子式
C6 H9 Cl O

分子量
132.59

闪点
82

密度
1.16

形态
White solid or colorless liquid

C32607Sigma-Aldrich2-Chlorocyclohexanone98%1825.84元/25 G;   6354.39元/100 G;   展开

基本信息

线性分子式ClC6H9(=O)
分子量132.59
Beilstein774100
EC 号212-505-5
MDL编号MFCD00001626
PubChem化学物质编号24892597
NACRESNA.22

产品性质

质量水平100
测定98%
折射率n20/D 1.484 (lit.)
bp82-83 ℃/10 mmHg (lit.)
mp23 ℃ (lit.)
密度1.161 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringClC1CCCCC1=O
InChI1S/C6H9ClO/c7-5-3-1-2-4-6(5)8/h5H,1-4H2
InChI keyCCHNWURRBFGQCD-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H317 - H319 - H335
预防措施声明P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)179.6 °F - closed cup
闪点(C)82 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
235014Fluorochem2-Chlorocyclohexanone95%1254元/25g;   展开

基本信息

CAS Number822-87-7
MDL NumberMFCD00001626

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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