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CAS: 822-36-6
分子式: C4H6N2
分子量: 82.10
沸点: 263℃
熔点: 52-56℃
中文名称: 
4-甲基-1H-咪唑
5-甲基咪唑
4-甲基咪唑
4-甲基甘恶啉
英文名称: 
4-MI)4-Methylimidazole
4-methyl-1(3)H-imidazole
4-Methyl-1H-imidazole
1H-Imidazole,4-methyl-
1H-Imidazole,4-methyl
4(5)-Methylimidazole
4(5)-Methylglyoxaline
1H-Imidazole, 4-methyl
5-Methylimidazole
4-methyl-imidazol
4-methyl-1h-imidazol
4-methylimidazole
展开更多英文名
性质描述: 熔点56℃,沸点263℃,120-125℃(26.7Pa)。溶于水、乙醇。
生产方法: 由丙酮醛、乙醛和氨反应而得。
用途: 医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M813676MACKLIN4-甲基咪唑98%30元/25g;   67元/100g;   295元/500g;   1469元/2.5kg;   展开
储存:2~8°C,密封
状态:白色到黄色晶体到粉末和/或块状
M0636TCI4-Methylimidazole>98.0%(GC)350元/25G;   750元/100G;   1990元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C4H6N2 = 82.11
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,湿气 (吸湿)
Reaxys-RN1453
PubChem物质ID87572655
SDBS (AIST Spectral DB)3676
MDL编号MFCD00005201

技术规格

AppearanceWhite to Yellow powder to lump
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 97.0 %
Melting point52.0 to 56.0 ℃

物性(参考值)

熔点52 ℃
沸点263 ℃
水溶性可溶
溶解性(可溶于)醇,甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H351 : 怀疑致癌。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

相关法规

RTECS#NI7350000

运输信息

UN编号UN3263
类别8
包装类别 III
监管条件代码(*)
297356J&K4-Methylimidazole98%60元/10G;   82元/50G;   展开

基本信息

分子式C4H6N2
分子量82.11
熔点44-47
沸点263
闪点157
MDL编码MFCD00005201
Beilstein1453
EINECS 编号212-497-3

安全信息

图形或危害标志
提示语Danger
危险说明H302
H312
H314
防范说明P280
P305+P351+P338
P310
UN号码3263
危险分类8
包装等级III
WGK2
RTECSNI7350000
TSCA
B24139Alfa Aesar4-Methylimidazole98%577元/10g;   1095元/50g;   3644元/250g;   展开

应用
4-Methylimidazole is used for the curing agent of epoxy resin, the main raw material of medicine cimetidine. It can also be used for synthesis of antibacterial agent.

备注
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents, acids, acid chlorides and acid anhydrides.

基本信息

MDL
MFCD00005201

EINECS
212-497-3

分子式
C4H6N2

分子量
82.11

熔点
49-57°

沸点
263°

闪点
157°(314°F)

密度
1.020

灵敏度
Ambient temperatures.

形态
Solid

溶解性
Soluble in water.

Beilstein
1453

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
22-34
Harmful if swallowed.Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
NI7350000

TSCA

C19033Alfa Aesar4-Methylimidazole98%910元/50g;   2985元/250g;   展开

基本信息

Ref#
19033

MDL
5201

分子式
C4 H6 N2

分子量
82.11

闪点
157

形态
White to cream solid

安全信息

危险等级
6.1

包装组
III

R11208Alfa Aesar4-Methylimidazole Standard solution100ppm210元/1ml;   展开
04535Supelco4(5)-Methylimidazoleanalytical standard1133.55元/100 MG;   展开

基本信息

经验(实验)分子式C4H6N2
分子量82.10
Beilstein1453
EC 号212-497-3
MDL编号MFCD00005201
PubChem化学物质编号329747940
NACRESNA.24

产品性质

质量水平100
等级analytical standard
测定≥98.0% (GC)
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
杂质≤1.0% water
bp263 ℃ (lit.)
mp44-47 ℃ (lit.)
application(s)cleaning products
cosmetics
food and beverages
forensics and toxicology
personal care
veterinary
格式neat
储存温度2-8℃
SMILES stringCc1c[nH]cn1
InChI1S/C4H6N2/c1-4-2-5-3-6-4/h2-3H,1H3,(H,5,6)
InChI keyXLSZMDLNRCVEIJ-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 + H312 - H314
预防措施声明P280 - P305 + P351 + P338 - P310
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 2
闪点(F)314.6 °F - closed cup
闪点(C)157 ℃ - closed cup
199885Sigma-Aldrich4(5)-Methylimidazole98%691.37元/50 G;   2665.77元/250 G;   展开

产品说明

一般描述

采用GC-MS 法对咖啡中的 4 (5)-甲基咪唑进行定量 。

包装

50, 250 g in glass bottle

基本信息

经验(实验)分子式C4H6N2
分子量82.10
Beilstein1453
EC 号212-497-3
MDL编号MFCD00005201
PubChem化学物质编号24851942
NACRESNA.22

产品性质

质量水平100
测定98%
bp263 ℃ (lit.)
mp44-47 ℃ (lit.)
溶解性H2O: soluble, clear, colorless to yellow (50 mg/mL)
SMILES stringCc1c[nH]cn1
InChI1S/C4H6N2/c1-4-2-5-3-6-4/h2-3H,1H3,(H,5,6)
InChI keyXLSZMDLNRCVEIJ-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 + H312 - H314
预防措施声明P260 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 2
闪点(F)314.6 °F - closed cup
闪点(C)157 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
FAC-001NAccuStandard4-Methylimidazole (4-MEI)232元/100mg;   展开
4-Methylimidazole (4-MEI)4-甲基咪唑822-36-6
078608Fluorochem4-Methylimidazole> 95%330元/25g;   880元/100g;   4114元/500g;   7414元/1kg;   展开

基本信息

CAS Number822-36-6
MDL NumberMFCD00005201

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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