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CAS: 82-45-1
分子式: C14H9NO2
分子量: 223.23
熔点: 251℃
中文名称: 
A-氨基蒽醌
α-氨基蒽醌
1-氨基蒽醌
英文名称: 
1-Amino-anthraquinone
alpha.-Aminoanthraquinone
-Aminoanthraquinone
9,10-Anthracenedione,1-amino-
.alpha.-Aminoanthraquinone
1-Aminoanthraquinone
10-Anthracenedione, 1-amino-9
1-amino-anthraquinon
1-amino-9,10-anthracenedione
1-amino-9,10-anthraquinone
1-aminoanthrachinon
1-amino-10-anthracenedione
alpha-aminoanthraquinone
alpha-anthraquinonylamine
c.i. 37275
diazo fast red al
展开更多英文名
性质描述: 红色或橙红色针状结晶。熔点253-254℃。溶于乙醇、乙醚、氯仿、丙酮、苯、冰醋酸、热硝基苯及盐酸、硫酸中,不溶于水。
生产方法: 1.蒽醌磺化氧化法 蒽醌在少量汞盐存在下用烟硫酸磺化,生成蒽醌-1-磺酸,再用氢氧化钾中和为蒽醌磺酸钾盐,在高温高压下,氨与蒽醌磺酸钾盐作用生成1-氨基蒽醌,同时生成的亚硫酸盐与产品再度反应而使产品质量下降。因此通常采用硝基苯磺酸盐为氧化剂,使亚硫酸盐氧化为硫酸盐,其本身则还原为间氨基苯磺酸。这一工艺由于磺化阶段用汞作定位剂,产生大量含汞污水,因此又发展了蒽醌硝化还原法。2.蒽醌硝化还原法 蒽醌用混酸硝化,经稀释、中和、过滤、洗涤后用亚硫酸钠精制,再经硫化钠还原、精制干燥而得成品。原料消耗定额:蒽醌(≥96%)1626kg/t、亚硫酸钠(93%)1214kg/t、硝酸(97%)2182kg/t、保险粉(85%)998kg/t、硫酸(92.5%)7874kg/t。
用途: 重要的染料中间体。可用于生产还原咔叽2G、还原红棕R、还原橄榄绿B、橄榄T、橄榄R 还原灰M、分散红3B 以及活性艳蓝KN-R、活性艳蓝M-BR。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A801120MACKLIN1-氨基蒽醌97%30元/25g;   67元/100g;   264元/500g;   展开
储存:室温
状态:红色到暗棕色粉末
A890237MACKLIN1-氨基蒽醌99%38元/10g;   84元/100g;   335元/500g;   展开
储存:室温
状态:橙色到棕色到暗红色粉末到晶体
A0590TCI1-Aminoanthraquinone>98.0%(N)250元/25G;   2250元/500G;   展开

基本信息

纯度/分析方法>98.0%(N)
分子式/分子量C14H9NO2 = 223.23
外观与形状(20℃)固体
Reaxys-RN396360
PubChem物质ID87562174
SDBS (AIST Spectral DB)7276
Merck Index (14)417
MDL编号MFCD00001213

技术规格

AppearanceOrange to Brown to Dark red powder to crystal
Purity(with Total Nitrogen)min. 98.0 %

物性(参考值)

熔点257 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H320 : 造成眼刺激。
H373 : 长期或反复接触可能损害器官。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P264 : 作业后彻底清洗皮肤。
P391 : 收集溢出物。
P314 : 如感觉不适,须求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。

相关法规

RTECS#CB5075000

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
537341J&K1-Aminoanthraquinone98%110元/25G;   256元/100G;   927元/500G;   展开

基本信息

分子式C14H9NO2
分子量223.23
熔点253-255
MDL编码MFCD00001213
Beilstein396360
Merck14,417
EINECS 编号201-423-5

安全信息

WGK1
RTECSCB5075000
TSCA
B22901Alfa Aesar1-Aminoanthraquinone97%559元/25g;   605元/100g;   2187元/500g;   展开

应用
In the manufacturing of dyes and pharmaceuticals

基本信息

MDL
MFCD00001213

EINECS
201-423-5

分子式
C14H9NO2

分子量
223.23

熔点
252-255°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in alcohol, benzene, chlroform, ether, glacial acetic acid, HCl

Beilstein
396360

Merck
14,417

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
CB5075000

TSCA

A39009Sigma-Aldrich1-Aminoanthraquinone97%684.97元/100 G;   展开

产品说明

包装

100, 500 g in glass bottle

生化/生理作用

1-氨基蒽醌具有增加蒽醌衍生物在超临界二氧化碳中溶解度的能力。

基本信息

经验(实验)分子式C14H9NO2
分子量223.23
颜色索引号37275
Beilstein396360
EC 号201-423-5
MDL编号MFCD00001213
PubChem化学物质编号24890825
NACRESNA.47

产品性质

质量水平100
测定97%
形式powder, crystals or chunks
mp253-255 ℃ (lit.)
application(s)diagnostic assay manufacturing
hematology
histology
储存温度room temp
SMILES stringNc1cccc2C(=O)c3ccccc3C(=O)c12
InChI1S/C14H9NO2/c15-11-7-3-6-10-12(11)14(17)9-5-2-1-4-8(9)13(10)16/h1-7H,15H2
InChI keyKHUFHLFHOQVFGB-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
8.41590Sigma-Aldrich1-Aminoanthraquinonefor synthesis511.46元/100 G;   展开

产品说明

分析说明

Assay (HPLC, area%): ≥ 96.0 % (a/a)
Melting range (lower value): ≥ 250 °C
Melting range (upper value): ≤ 255 °C
Identity (IR): passes test

基本信息

经验(实验)分子式C14H9NO2
分子量223.23
MDL编号MFCD00001213
EC索引号201-423-5

产品性质

质量水平200
测定≥96.0% (HPLC)
mp251-254 ℃
储存温度2-30℃
InChI1S/C14H9NO2/c15-11-7-3-6-10-12(11)14(17)9-5-2-1-4-8(9)13(10)16/h1-7H,15H2
InChI keyKHUFHLFHOQVFGB-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
R-061NAccuStandard1-Aminoanthraquinone154元/50mg;   展开
1-Aminoanthraquinone1-氨基蒽醌82-45-1
242859Fluorochem1-Aminoanthracene-9,10-dione95%330元/100g;   展开

基本信息

CAS Number82-45-1
MDL NumberMFCD00001213

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H373: May cause damage to organs Blood system. Kidney. Spleen..
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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