[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 81-64-1
关键词:       仅模糊查询
CAS: 81-64-1
分子式: C14H8O4
分子量: 240.21
沸点: 450℃
熔点: 191-193℃
中文名称: 
1,4-二羟基蒽醌
醌茜
奎札因
1,4-二羟基-9,10-蒽二酮
1,4-蒽醌二酚
英文名称: 
solvent orange 86
1,4-Dihydroxyanthraquinone
10-Anthracenedione, 1,4-dihydroxy-9
Quinizarin
1,4-dihydroxy-anthraquinon
1,4-dihydroxy-9,10-anthracenedione
1,4-dihydroxy-9,10-anthraquinone
1,4-dihydroxyanthrachinon
1,4-dioxyanthraquinone
1,4-doa
1,4-dihydroxy-10-anthracenedione
c.i. 58050
chinizarin
ci 58050
quinizarine
smoke orange r
anthraquinone,1,4-dihydroxy-
9,10-anthracenedione,1,4-dihydroxy-
1,4-dihydroxy-9,10(9H,10H)anthracenedione
1,4-Dihydroxy-anthraquinone
Quinizalin
I,4-Diosyanthrachinon
展开更多英文名
性质描述: 从乙酸中析出者为橙色结晶,熔点200-203℃。从乙醚中析出者为橙色片状结晶。从乙醇、苯、甲苯及二甲苯中析出者为深红色针状结晶,熔点196℃。微溶于水;溶于浓硫酸、氢氧化钠溶液、氯苯、甲苯、二甲苯、二氯苯;适量溶于乙醇呈红色;溶于乙醚呈棕色并显黄色荧光;溶于苛性碱液及氨中呈紫色。遇二氧化碳产生黑色沉淀,1g能溶于约13g的沸冰醋酸。能在高真空中升华。
生产方法: 苯酐和对苯二酚在硼酸存在下于浓硫酸中缩合,再经稀释、水洗、中和、氧化、压滤,得成品。原料消耗定额:对苯二酚550kg/t、苯酐1280kg/t、硼酸550kg/t、硫酸4300kg/t。
用途: 该品是重要的染料中间体。本身为分散棕GL(C.I.58050)。用来制造分散蓝HSR、分散蓝5R、分散蓝B、分散深蓝RB、酸性蒽醌蓝R、弱酸艳蓝RAW弱酸绿GS、还原灰BG、还原棕BR等;以及用来生产中间体1,4-二氨基蒽醌。由1,4-二羟基醌经磺化可得1,4-二羟基蒽醌-2-磺酸。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D769126MACKLIN1,4-二羟基蒽醌purum,≥98.0%(HPLC),粉末,红棕色339元/50g;   899元/250g;   展开
储存:室温
D806790MACKLIN1,4-二羟基蒽醌96%28元/25g;   50元/100g;   142元/500g;   625元/2.5kg;   展开
储存:室温
状态:橙色到红棕色粉末
D0243TCIQuinizarin>97.0%(HPLC)180元/25G;   260元/100G;   965元/500G;   展开

基本信息

纯度/分析方法>97.0%(HPLC)
分子式/分子量C14H8O4 = 240.21
外观与形状(20℃)固体
Reaxys-RN1914036
PubChem物质ID87566949
SDBS (AIST Spectral DB)4917
Merck Index (14)8064
颜色58050
MDL编号MFCD00001209

技术规格

AppearanceLight yellow to Brown powder to crystal
Purity(HPLC)min. 97.0 area%
Melting point196.0 to 202.0 ℃

物性(参考值)

熔点196 ℃
沸点450 ℃
溶解性(可溶于)

安全信息

图形或危害标志
信号词警告
危险性说明H320 : 造成眼刺激。
H341 : 怀疑可造成遗传性缺陷。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P405 : 存放处须加锁。

相关法规

RTECS#CB6600000
389325J&K1,4-Dihydroxyanthraquinone97%60元/5G;   94元/25G;   171元/100G;   1535元/1KG;   展开

基本信息

分子式C14H8O4
分子量240.21
熔点198-199
沸点450
闪点222
MDL编码MFCD00001209
Beilstein1914036
Merck14,8064
EINECS 编号201-368-7

安全信息

图形或危害标志
提示语Warning
危险说明H410
防范说明P273
P501
UN号码3077
危险分类9
包装等级III
WGK2
RTECSCB6600000
TSCA
A11010Alfa Aesar1,4-Dihydroxyanthraquinone95%1173元/250g;   3387元/1000g;   14577元/5000g;   展开

应用
1,4-Dihydroxyanthraquinone is used to color gasoline and some heating oils. It is used as an intermediate for the synthesis of indanthrene- and alizarin-derived dyes. It is also used to form lake pigments with calcium, barium and lead. It may be used in the synthesis of cyclopentanoids by cyclization of α,β-unsaturated aldehyde with 1, 4 1,4-Dihydroxyanthraquinone. It has been studied as a long range emissive ratiometric fluorescent probe for live cell imaging.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00001209

EINECS
201-368-7

分子式
C14H8O4

分子量
240.21

熔点
195-198°

沸点
ca 450°

闪点
222°(431°F)

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in water.

Beilstein
1914036

Merck
14,8064

安全信息

危险等级
9

包装组
III

危险类别
50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
3-57-60
Keep in a cool place.Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

RTECS
CB6600000

TSCA

C13218Alfa Aesar1,4-Dihydroxyanthraquinone96%459元/5g;   482元/100g;   3002元/1kg;   展开

基本信息

Ref#
13218

MDL
1209

分子式
C14 H8 O4

分子量
240.21

闪点
222

形态
Powder

37480Sigma-Aldrich1,4-Dihydroxyanthraquinonepurum, ≥98.0% (HPLC), powder, red-brown339元/50 G;   749.17元/250 G;   展开

产品说明

一般描述

1,4-Dihydroxyanthraquinone is an organic dye molecule with an aromatic structure. It is a derivative of anthraquinone bearing hydroxyl moieties. They may find uses in pharmacological, biochemical and dye industries. Anthraquinone dye are resistant to degradation.

应用

1,4-Dihydroxyanthraquinone may be used in the synthesis of cyclopentanoids by cyclization of α,β-unsaturated aldehyde with 1, 4 1,4-Dihydroxyanthraquinone. It has been studied as a long range emissive ratiometric fluorescent probe for live cell imaging.

基本信息

经验(实验)分子式C14H8O4
分子量240.21
Beilstein1914036
EC 号201-368-7
MDL编号MFCD00001209
PubChem化学物质编号329755654
NACRESNA.23

产品性质

质量水平200
等级purum
测定≥98.0% (HPLC)
形式powder
灼烧残渣≤1.0%
颜色 red-brown
mp195-200 ℃
SMILES stringOc1ccc(O)c2C(=O)c3ccccc3C(=O)c12
InChI1S/C14H8O4/c15-9-5-6-10(16)12-11(9)13(17)7-3-1-2-4-8(7)14(12)18/h1-6,15-16H
InChI keyGUEIZVNYDFNHJU-UHFFFAOYSA-N

安全信息

象形图GHS09
警示用语:Warning
危险声明H410
预防措施声明P273
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)431.6 °F
闪点(C)222 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type N95 (US)
8.20259Sigma-Aldrich1,4-Dihydroxyanthraquinonefor synthesis292.18元/5 G;   461.56元/250 G;   展开

产品说明

应用

1,4-Dihydroxyanthraquinone for synthesis. CAS 81-64-1, molar mass 240.21 g/mol.

分析说明

Assay (acidimetric): ≥ 97.0 %
Melting range (lower value): ≥ 195 °C
Melting range (upper value): ≤ 198 °C
Identity (IR): passes test

基本信息

经验(实验)分子式C14H8O4
分子量240.21
MDL编号MFCD00001209
EC索引号201-368-7

产品性质

质量水平200
蒸汽压1.3 hPa ( 197 ℃)
测定≥97.0% (acidimetric)
效能>5000 mg/kg LD50, oral (Rat)
bp450 ℃/1013 hPa
mp195-198 ℃
转变温度flash point 222 ℃
堆积密度350 kg/m3
储存温度2-30℃
InChI1S/C14H8O4/c15-9-5-6-10(16)12-11(9)13(17)7-3-1-2-4-8(7)14(12)18/h1-6,15-16H
InChI keyGUEIZVNYDFNHJU-UHFFFAOYSA-N

安全信息

象形图GHS09
警示用语:Warning
危险声明H410
预防措施声明P273 - P391 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)431.6 °F
闪点(C)222 ℃
130900Fluorochem1,4-Dihydroxyanthraquinone95+%220元/25g;   352元/100g;   展开

基本信息

CAS Number81-64-1
MDL NumberMFCD00001209
Melting Point195-198℃
Density1.54

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9