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CAS: 80655-81-8
分子式: C20H12Br2O2
分子量: 444.12
熔点: 92-96℃
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货号品牌产品名称规格包装、参考价格详情
S808165MACKLIN(|S|)-(+)-6,6'-二溴-1,1'-联-2-萘酚98.0%39元/250mg;   153元/1g;   502元/5g;   2459元/25g;   展开
储存:室温
D2730TCI(S)-(+)-6,6'-Dibromo-1,1'-bi-2-naphthol>98.0%(HPLC)1200元/1G;   4420元/5G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C20H12Br2O2 = 444.12
外观与形状(20℃)固体
Reaxys-RN2061036
PubChem物质ID87569138
MDL编号MFCD00798290

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 96.0 %
Specific rotation [a]20/D+43.0 to +49.0 deg(C=2,THF)

物性(参考值)

比旋光度 [α]D45° (C=2,THF)
溶解性(微溶于)四氢呋喃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
489899J&K(S)-(+)-6,6'-Dibromo-1,1'-bi-2,2'-naphthol98%427元/250MG;   1406元/1G;   4655元/5G;   展开

基本信息

分子式C20H12Br2O2
分子量444.12
熔点195-199
比旋光度([α]20D)+42° to +47° (C=2, THF)
MDL编码MFCD00798290

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
08-0186Strem(S)-(+)-6,6'-Dibromo-1,1'-bi-2-naphthol98% (99% ee)1230元/500mg;   3675元/2g;   展开
08-0606Strem(S)-(+)-6,6'-Dibromo-1,1'-bi-2-naphtholmin. 98%1950元/500mg;   5850元/2g;   展开

Technical Notes:

1. L igand used to prepare a chiral zirconium catalyst useful in asymmetric Strecker reactions. Ligand used in the zinc-catalyzed enantioselective Hetero Diels-Alder reaction.

2.L igand used in asymmetric Friedel-Crafts reactions of pyrroles with glyoxylates .

References:

1.J. Am. Chem. Soc., 2000, 122, 762. 2.Org. L ett., 2002, 4, 4349.

3.Org. L ett., 2003, 5, 1091.

4.Org. L ett., 2011, 13, 5944.

Y11401Alfa Aesar(S)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol171元/250mg;   展开

基本信息

分子量
444.12

545022Fluorochem(S)-(+)-6,6'-Dibromo-[1,1'-binaphthalene]-2,2'-diol97%374元/250mg;   748元/1g;   2816元/5g;   展开

基本信息

CAS Number80655-81-8
MDL NumberMFCD00798290
Melting Point195-199℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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