CAS 80480-15-5; 1-bromoacetylpyrene

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CAS:

80480-15-5

分子式:

C₁₈H₁₁BrO

分子量:

323.18

熔点:

129-131℃

英文名称:

1-bromoacetylpyrene

1-(bromoacetyl)pyrene

用途:

1-(Bromoacetyl)pyrene (BAP)[8] is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene.Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

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货号

品牌

产品名称

规格

包装、参考价格

B923162

MACKLIN

1-(溴乙酰)芘

97%

243元/250mg; 669元/1g; 2157元/5g;

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储存：室温

394408

Sigma-Aldrich

1-(Bromoacetyl)pyrene

97%

2904.6元/5 G;

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产品说明

一般描述

1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

应用

1-(Bromoacetyl)pyrene is suitable for use in the following studies:

As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.

It may also be used in the following studies:

As a photoremovable protecting group for carboxylic acids and amino acids.
As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.

包装

5 g in glass bottle

基本信息

经验(实验)分子式	C₁₈H₁₁BrO
分子量	323.18
MDL编号	MFCD00191839
PubChem化学物质编号	24864593
NACRES	NA.22

产品性质

质量水平	100
测定	97%
mp	129-131 ℃ (lit.)
SMILES string	BrCC(=O)c1ccc2ccc3cccc4ccc1c2c34
InChI	1S/C18H11BrO/c19-10-16(20)14-8-6-13-5-4-11-2-1-3-12-7-9-15(14)18(13)17(11)12/h1-9H,10H2
InChI key	KAEDEGFCOPIKKM-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314 - H413
预防措施声明	P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Aquatic Chronic 4 - Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

213398

Fluorochem

2-Bromo-1-(pyren-1-yl)ethanone

95%

836元/250mg;

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基本信息

CAS Number	80480-15-5
MDL Number	MFCD00191839

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