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CAS: 80149-80-0
分子式: C12H17NO5Si
分子量: 283.35
熔点: 35-40℃
英文名称: 
4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate
2-(Trimethylsilyl)ethyl 4-nitrophenyl carbonate
2-(trimethylsilyl)ethyl p-nitrophenyl carbonate
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货号品牌产品名称规格包装、参考价格详情
T834737MACKLIN4-[2-(三甲基硅基)乙氧基羰氧基]硝基苯≥95%105元/1g;   439元/5g;   2100元/25g;   7150元/100g;   展开
储存:2~8°C,密封
状态:浅黄色结晶粉末
T2872TCI4-[2-(Trimethylsilyl)ethoxycarbonyloxy]nitrobenzene>98.0%(HPLC)1950元/5G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C12H17NO5Si = 283.36
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (分解),加热
Reaxys-RN4320585
PubChem物质ID160871334
MDL编号MFCD00042930

技术规格

AppearanceLWhite to Yellow powder to crystal
Purity(HPLC)min. 98.0 area%
Elemental analysis(Nitrogen)4.7 to 5.1 %
Melting point37.0 to 41.0 ℃

物性(参考值)

熔点39 ℃
溶解性(可溶于)甲醇
353626J&K4-Nitrophenyl 2-(Trimethylsilyl)ethyl Carbonate98%488元/1G;   1948元/5G;   展开

基本信息

分子式C12H17NO5Si
分子量283.35
熔点37-41
MDL编码MFCD00042930
Beilstein4320585
EINECS 编号279-406-7
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK3
H60466Alfa Aesar4-Nitrophenyl 2-(Trimethylsilyl)ethyl Carbonate95%1048元/1g;   3470元/5g;   展开

应用
It is employed as a reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-.

备注
Moisture & Light Sensitive. Store at 2-8?°C.

基本信息

MDL
MFCD00042930

EINECS
279-406-7

分子式
C12H17NO5Si

分子量
283.35

熔点
35-40°

灵敏度
Keep Cold. Moisture Sensitive. Light Sensitive. Store under Nitrogen.

形态
Solid

溶解性
Slightly soluble in water.

Beilstein
4320585

安全信息

TSCA

C44007Alfa Aesar4-Nitrophenyl 2-(Trimethylsilyl)ethyl Carbonate95%4929元/5g;   17980元/25g;   展开

基本信息

Ref#
44007

MDL
42930

分子式
C12 H17 N O5 Si

分子量
283.36

92748Sigma-Aldrich4-Nitrophenyl 2-(Trimethylsilyl)ethyl Carbonate≥97.0%1103.57元/5 G;   4441.43元/25 G;   展开

产品说明

应用

4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate can be used as:

  • A protecting group for an amine in one of the key synthetic steps of kottamide E total synthesis.
  • A starting material to prepare a cis-butene derivative, which is used as a polymer terminating agent in the synthesis of monotelechelic glycopolymers.

包装

5, 25 g in glass bottle

其他说明

用于引入 TEOC-氨基保护基团的试剂,TEOC-氨基保护基团可被 F- 裂解

基本信息

经验(实验)分子式C12H17NO5Si
分子量283.35
Beilstein4320585
EC 号279-406-7
MDL编号MFCD00042930
PubChem化学物质编号57653487
NACRESNA.22

产品性质

质量水平100
测定≥97.0%
mp35-40 ℃
application(s)peptide synthesis
储存温度2-8℃
SMILES stringC[Si](C)(C)CCOC(=O)Oc1ccc(cc1)[N+]([O-])=O
InChI1S/C12H17NO5Si/c1-19(2,3)9-8-17-12(14)18-11-6-4-10(5-7-11)13(15)16/h4-7H,8-9H2,1-3H3
InChI keyZAQWGGKIMQIVGM-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
051077Fluorochem4-Nitrophenyl 2-(Trimethylsilyl)ethyl Carbonate95%616元/1g;   2090元/5g;   展开

基本信息

CAS Number80149-80-0
MDL NumberMFCD00042930
Melting Point35-40℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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