CAS 80049-61-2; trisacetonitrilecyclopentadienylrutheniumhexachlorophosphate

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T819935

MACKLIN

三(乙腈基)环戊二烯六氟磷酸钌(II)

98%

473元/100mg; 956元/250mg; 2992元/1g; 10981元/5g;

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储存：2~8°C
状态：无色液体

T3079

TCI

Tris(acetonitrile)cyclopentadienylruthenium(II) Hexafluorophosphate

>98.0%(HPLC)

1590元/200MG;

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基本信息

纯度/分析方法	>98.0%(HPLC)
分子式/分子量	C₁₁H₁₄F₆N₃PRu = 434.29
外观与形状(20℃)	固体
储存温度	0-10℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,加热
Reaxys-RN	14432805
PubChem物质ID	253661000
MDL编号	MFCD02684569

技术规格

Appearance	Light yellow to Brown powder to crystal
Elemental analysis(Nitrogen)	9.10 to 10.10 %

物性(参考值)

熔点	149 ℃(dec.)

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

44-7870

Strem

Tris(acetonitrile)cyclopentadienylruthenium(II) Hexafluorophosphate

min. 98%

1793元/250mg; 5380元/1g; 21765元/5g;

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Technical Notes:

1.Catalyst used for the coupling of allene with activated olefines to form 1 ,3-diene.

2.Catalyst used for the dimerization of propargyl alcohols.

3.Catalyst used in the Trost's ruthenium-catalyzed ene-yne cross-coupling reaction.

4.Catalyst for asymmetric cyclization of w-hydroxy allyl alcohols to give a-alkenylcyclic ethers .

5.Catalyst for synthesis of furans from bis(alkynes) and DMSO.

References:

1.J. Am. Chem. Soc., 2001, 123, 12466.

2.J. Am. Chem. Soc., 2001, 123, 8862.

3.J. Am. Chem. Soc., 2000, 122, 714.

4. Angew. Chem. Int. Ed., 2009, 48, 8948.

5. J. Am. Chem. Soc., 2012, 134, 7660.

C37789

Alfa Aesar

Tris(acetonitrile)cyclopentadienylruthenium(II) Hexafluorophosphate

98%

2689元/250mg; 7618元/1g;

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基本信息

Ref#
37789

MDL
02684569

分子式
C11 H14 F6 N3 P Ru

分子量
434.29

安全信息

危险等级
6.1

包装组
III

673307

Sigma-Aldrich

Tris(acetonitrile)cyclopentadienylruthenium(II) Hexafluorophosphate

1352.93元/250 MG; 4808.06元/1 G;

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产品说明

应用

Catalyst for:

Regioselective and stereoselective dehydrative allylation of nucleophiles
O-H Insertion and condensation reactions
Hydrosilylation
Decarboxylative allylic etherification
Claisen rearrangement of unactivated allyl vinyl ethers

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

线性分子式	[(C₅H₅)Ru(CH₃CN)₃]PF₆
分子量	434.28
MDL编号	MFCD02684569
PubChem化学物质编号	329760546

产品性质

质量水平	100
reaction suitability	core: ruthenium reagent type: catalyst
储存温度	2-8℃
SMILES string	[Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F
InChI	1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;31-2-3;1-7(2,3,4,5)6;/h1-5H;31H3;;/q;;;;-1;+1
InChI key	HJQVFVSAQOQXRG-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

547421

Fluorochem

Tris(acetonitrile)cyclopentadienylruthenium(II) Hexafluorophosphate

98+%

2222元/250mg; 7238元/1g;

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基本信息

CAS Number	80049-61-2
MDL Number	MFCD02684569
Melting Point	117-118℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .