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CAS: 80-59-1
分子式: C5H8O2
分子量: 100.12
沸点: 198.4℃
熔点: 61-65℃
中文名称: 
(E)-2-甲基-2-丁烯酸
惕各酸
反式-2-甲基巴豆酸
英文名称: 
cevadic acid
(E)-α-Methylcrotonic acid
tiglinic acid
trans-α,β-Dimethylacrylic acid
trans-2,3-dimethylacrylic acid
(E)-2-methylbut-2-enoic acid
trans-2-methyl-2-butenoic acid
crotonolic acid
trans-2-methylcrotonic acid
trans-2,3-Dimethylacrylsαure
trans-alpha,beta-dimethylacrylic acid
trans-2-Methyl-2-butensαure
trans-2-Methylcrotonsαure
2-Methyl-trans-but-2-en-sαure
tiglic
tiglic acid,[corrosive solid]
tiglicacid
Trans-2-methyl crotonic acid
trans-2-methyl-but-2-enoic acid
(E)-2-Methyl-2-butensαure
(E)-2-Methylcrotonsαure
2-methyl-, (E)-2-Butenoic acid
Tiglinsαure
(e)-2,3-dimethylacrylic acid
2-Butenoic acid,2-methyl-,(2E)-
(e)-2-methyl-2-butenoic acid
2-Butenoic acid,2-methyl-,(E)-
(e)-2-methylcrotonic acid
Crotonic acid,2-methyl-,(E)-
展开更多英文名
用途: 用于医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T819159MACKLIN惕格酸98%29元/5g;   39元/25g;   128元/100g;   601元/500g;   展开
储存:2~8°C
状态:白色到灰白色粉末或晶体
T798490MACKLIN惕格酸10mM in DMSO186元/1ml;   展开
储存:-20°C
T0246TCITiglic Acid>98.0%(GC)(T)400元/25G;   860元/100G;   2915元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C5H8O2 = 100.12
外观与形状(20℃)固体
储存温度0-10℃
应避免的情况加热
Reaxys-RN1236500
PubChem物质ID87576228
SDBS (AIST Spectral DB)4079
Merck Index (14)9433
MDL编号MFCD00066864

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point61.0 to 66.0 ℃

物性(参考值)

熔点64 ℃
沸点82 ℃/8 mmHg
水溶性微溶
溶解性(可溶于)乙醚,醇

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

相关法规

RTECS#GQ5430000

运输信息

UN编号UN3261
类别8
包装类别 III
监管条件代码(*)
228327J&Ktrans-2,3-Dimethylacrylic acid98%253元/25G;   741元/100G;   1654元/500G;   展开

基本信息

分子式C5H8O2
分子量100.12
熔点61-64
沸点95-96
密度0.969
MDL编码MFCD00066864
Beilstein1236500
Merck14,9433
EINECS 编号201-295-0
存储条件Store at 2-8℃ Flammables

安全信息

图形或危害标志
提示语Danger
危险说明H315
H319
H335
防范说明P261
P280
P301+P310
P302+P352
P305+P351+P338
UN号码3261
危险分类8
包装等级II
WGK2
RTECSGQ5430000
TSCA
A13905Alfa AesarTiglic Acid97+%803元/25g;   1889元/100g;   8713元/500g;   展开

基本信息

MDL
MFCD00066864

EINECS
201-295-0

分子式
C5H8O2

分子量
100.12

熔点
62-66°

沸点
198-199°

闪点
101°(213°F)

密度
0.969

灵敏度
Ambient temperatures.

形态
Crystalline powder

Beilstein
1236500

Merck
14,9433

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
GQ5430000

TSCA

C13897Alfa Aesartrans-2,3-Dimethylacrylic acid98%752元/25g;   2130元/100g;   8138元/500g;   展开

基本信息

Ref#
13897

MDL
66864

分子式
C5 H8 O2

分子量
100.12

闪点
95

密度
0.96

安全信息

危险等级
8

包装组
III

W359904Sigma-Aldrichtrans-2-Methyl-2-butenoic acid≥99%, FG416.55元/;   658.47元/100 G;   1641.89元/1 KG;   展开

基本信息

线性分子式CH3CH=C(CH3)COOH
分子量100.12
FEMA编号3599
Beilstein1236500
EC 号201-295-0
欧洲委员会编号10168
MDL编号MFCD00066864
PubChem化学物质编号24901804
Flavis编号8.064
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
agencyfollows IFRA guidelines
meets purity specifications of JECFA
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 178/2002
测定≥99%
bp95-96 ℃/12 mmHg (lit.)
mp61-64 ℃ (lit.)
密度0.969 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查brown; spicy
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物no known allergens
SMILES stringC\C=C(/C)C(O)=O
InChI1S/C5H8O2/c1-3-4(2)5(6)7/h3H,1-2H3,(H,6,7)/b4-3+
InChI keyUIERETOOQGIECD-ONEGZZNKSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)203.0 °F
闪点(C)95 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
T35203Sigma-Aldrichtrans-2,3-Dimethylacrylic acid98%669.39元/100 G;   展开

产品说明

包装

100 g in glass bottle

其他说明

Tandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. T35203.pdf Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.

基本信息

线性分子式CH3CH=C(CH3)COOH
分子量100.12
Beilstein1236500
EC 号201-295-0
MDL编号MFCD00066864
PubChem化学物质编号24900147
NACRESNA.22

产品性质

质量水平200
测定98%
bp95-96 ℃/12 mmHg (lit.)
mp61-64 ℃ (lit.)
密度0.969 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringC\C=C(/C)C(O)=O
InChI1S/C5H8O2/c1-3-4(2)5(6)7/h3H,1-2H3,(H,6,7)/b4-3+
InChI keyUIERETOOQGIECD-ONEGZZNKSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)203.0 °F
闪点(C)95 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
545226FluorochemTiglic Acid98%242元/25g;   展开

基本信息

CAS Number80-59-1
MDL NumberMFCD00066864
Melting Point61-65℃
Density0.969

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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