| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| E859353 | MACKLIN | 4,4,4-三氟丁炔-2-酸乙酯 | 97% | 160元/1g; 576元/5g; 1920元/25g; 5280元/100g; | 咨询 |
|
| 422169 | J&K | Ethyl 4,4,4-trifluoro-2-butynoate | 97% | 2195元/250MG; 7230元/1G; | 咨询 |
基本信息 | 分子式 | C6H5F3O2 | | 分子量 | 166.10 | | 沸点 | 96-98 | | 闪点 | 6 | | 密度 | 1.162 | | 折光率(n20D) | 1.3500 | | MDL编码 | MFCD00192167 | | Beilstein | 3539414 |
安全信息 | 图形或危害标志 |   | | 提示语 | Danger | | 危险说明 | H225
H315
H319
H335 | | 防范说明 | P210
P261
P305+P351+P338 | | UN号码 | 3272 | | 危险分类 | 3 | | 包装等级 | II | | WGK | 3 | | TSCA | 否 |
|
| H53425 | Alfa Aesar | Ethyl 4,4,4-trifluoro-2-butynoate | 97% | 7432元/1g; 26432元/5g; | 咨询 |
应用
Ethyl 4,4,4-trifluoro-2-butynoate is the suitable reagent used to investigate the regioselectivity of the insertion reaction with cyclometalated iridium and rhodium complexes. It may be used in the preparation of ethyl (Z)-3-iodo-4,4,4-trifluoro-2-butenoate. 备注
Stable under recommended storage conditions. Incompatible with oxidizing agents. 基本信息 MDL
MFCD00192167 分子式
C6H5F3O2 分子量
166.10 沸点
96-98° 闪点
6°(43°F) 密度
1.162 折射率
1.350 灵敏度
Ambient temperatures. 形态
Liquid 溶解性
Soluble in water (partly). Beilstein
3539414 GHS危害和防范说明 GHS符号
Hazard Statements
H225-H315-H319-H335
Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
3 包装组
II 危险类别
11-36/37/38
Highly flammable.Irritating to eyes, respiratory system and skin. 安全等级
16-23-26-37
Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 欧盟危险品标志
 TSCA
否 |
| C39932 | Alfa Aesar | Ethyl 4,4,4-trifluoro-2-butynoate | 97% | 3130元/500mg; | 咨询 |
基本信息 Ref#
39932 MDL
192167 分子式
C6 H5 F3 O2 分子量
166.1 闪点
6 密度
1.62 安全信息 危险等级
3 包装组
II |
| 401455 | Sigma-Aldrich | Ethyl 4,4,4-trifluoro-2-butynoate | 97% | 803.31元/500 MG; | 咨询 |
产品说明 一般描述 Ethyl 4,4,4-trifluoro-2-butynoate is an unsymmetrical internal alkyne. 应用 Ethyl 4,4,4-trifluoro-2-butynoate has been used to investigate the regioselectivity of the insertion reaction with cyclometalated iridium and rhodium complexes.
It may be used in the synthesis of the following compounds : - (2S,4aR,6aR,7R,9S,10aS,10bR)-methyl 9-acetoxy-2-(5-(ethoxycarbonyl)-6-(trifluoromethyl)-7-oxabicyclo[2.2.1]hepta-2,5-dien-2-yl)-6a,10b-dimethyl-4,10-dioxododecahydro-1H-benzo[f]isochromene-7-carboxylate
- (2S,4aR,6aR,7R,9S,10aS,10bR)-methyl 9-acetoxy-2-(6-(ethoxycarbonyl)-5-(trifluoromethyl)-7-oxabicyclo[2.2.1]hepta-2,5-dien-2-yl)-6a,10b-dimethyl-4,10-dioxododecahydro-1Hbenzo[f]isochromene-7-carboxylate
包装 500 mg in amber glass bottle 基本信息 | 线性分子式 | CF3C≡CCO2C2H5 | | 分子量 | 166.10 | | Beilstein | 3539414 | | MDL编号 | MFCD00192167 | | PubChem化学物质编号 | 24865017 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 97% | | 折射率 | n20/D 1.350 (lit.) | | bp | 96-98 ℃ (lit.) | | 密度 | 1.162 g/mL at 25 ℃ (lit.) | | SMILES string | CCOC(=O)C#CC(F)(F)F | | InChI | 1S/C6H5F3O2/c1-2-11-5(10)3-4-6(7,8)9/h2H2,1H3 | | InChI key | SFDRHPQGYUYYNX-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H225 - H315 - H319 - H335 | | 预防措施声明 | P210 - P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 3 - Flammable liquids | | WGK | WGK 3 | | 闪点(F) | 42.8 °F - closed cup | | 闪点(C) | 6 ℃ - closed cup | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
|
| 080257 | Fluorochem | Ethyl 4,4,4-trifluorobutynoate | 95% | 506元/250mg; 1188元/1g; 4158元/5g; | 咨询 |
基本信息 | CAS Number | 79424-03-6 | | MDL Number | MFCD00192167 | | Boiling Point | 96 - 98 ℃ | | Density | 1.162 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H225: Highly flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use CO2, powder or sand for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
|
|
m.cnreagent.com