| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| T819036 | MACKLIN | 三苯基氧膦 | 98% | 29元/25g; 34元/100g; 100元/500g; 332元/2.5kg; 1292元/10kg; | 咨询 |
储存：室温 状态：白色到黄色到棕褐色粉末,晶体或块状 |
| T0625 | TCI | Triphenylphosphine Oxide | >98.0%(GC) | 230元/25G; 535元/100G; 1645元/500G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(GC) | | 分子式/分子量 | C18H15OP = 278.29 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 745854 | | PubChem物质ID | 87576517 | | SDBS (AIST Spectral DB) | 7867 | | MDL编号 | MFCD00002080 |
技术规格 | Appearance | White to Orange to Green powder to crystal | | Purity(GC) | min. 98.0 % | | Melting point | 155.0 to 159.0 ℃ |
物性(参考值) | 熔点 | 156 ℃ | | 沸点 | 360 ℃ | | 水溶性 | 不溶 | | 溶解性(可溶于) | 丙酮,甲醇 |
安全信息 | 图形或危害标志 |   | | 信号词 | 警告 | | 危险性说明 | H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H411 : 对水生生物有毒并具有长期持续影响。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P391 : 收集溢出物。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。
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相关法规 运输信息 | UN编号 | UN3077 | | 类别 | 9 | | 包装类别 | III | | 监管条件代码(*) | |
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| 128860 | J&K | Triphenylphosphine Oxide | 98% | 81元/25g; 196元/100g; 780元/500g; | 咨询 |
基本信息 | 分子式 | C18H15OP | | 分子量 | 278.28 | | 熔点 | 150-157 | | 闪点 | 180 | | MDL编码 | MFCD00002080 | | Beilstein | 745854 | | EINECS 编号 | 212-338-8 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H302
H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 2 | | RTECS | SZ1676000 | | TSCA | 是 |
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| 15-6750 | Strem | Triphenylphosphine Oxide | 98% | 528元/25g; 1432元/100g; | 咨询 |
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| A12455 | Alfa Aesar | Triphenylphosphine Oxide | 99% | 284元/25g; 755元/100g; 2790元/500g; | 咨询 |
应用
Triphenylphosphine oxide is used as a catalyst, Lewis base, ligand for metals and starting material for the preparation of other phosphorus compounds. It is also used in epoxidations, Michael reactions and coupling reactions. It reacts with copper(II) halides and form coordination complexes of Copper(II). Further, it acts as a crystallization aid for chemical compounds. In addition to this, it is used for processing, extraction, separation and spectrophotometric determination of cadmium and mercury. 备注
Incompatible with strong oxidizing agents. 基本信息 MDL
MFCD00002080 EINECS
212-338-8 分子式
C18H15OP 分子量
278.29 熔点
153-159° 沸点
360° 闪点
180°(356°F) 密度
1.200 灵敏度
Ambient temperatures. 形态
Crystalline powder 溶解性
Soluble in polar organic solvents. Slightly soluble in hexane and diethyl ether. Insoluble in water. Beilstein
745854 GHS危害和防范说明 GHS符号
Hazard Statements
H302-H402-H412
Harmful if swallowed.Harmful to aquatic life.Harmful to aquatic life with long lasting effects. Precautionary Statements
P264-P270-P301+P312a-P330-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Rinse mouth.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
22-52/53
Harmful if swallowed.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 安全等级
36-60-61
Wear suitable protective clothing.This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets. 欧盟危险品标志
 RTECS
SZ1676000 TSCA
是 |
| 08902 | Supelco | Triphenylphosphine Oxide | analytical standard | 1786.91元/100MG; | 咨询 |
产品说明 分析说明 根据质量平衡原理计算纯度，并在 CoA 中提出。 其他说明 Ion Mobility: TWCCSN2 value of 160 Å2 [M+H]+ and 179.6 Å2 [M+Na]+
The collision cross section (CCS) measurement was provided by Waters Corporation, using the SYNAPT XS mass spectrometer.
For a description and overview of how ion mobility enables the measurement of the CCS of an ion visit ims.waters.com.
Further information on the SYNAPT XS mass spectrometer can be found on the IMS microsite and product webpage.
TWCCS measurements are expected to be within 2% of this reference value.
P/N 08902 is part of the Waters Extractables & Leachables UNIFI scientific library which can be downloaded from Waters Marketplace. 基本信息 | 线性分子式 | (C6H5)3PO | | 分子量 | 278.28 | | Beilstein | 745854 | | EC 号 | 212-338-8 | | MDL编号 | MFCD00002080 | | PubChem化学物质编号 | 329748641 | | NACRES | NA.24 |
产品性质 | 等级 | analytical standard | | 质量水平 | 100 | | 测定 | ≥98.5% (HPLC) | | 保质期 | limited shelf life, expiry date on the label | | technique(s) | HPLC: suitable
gas chromatography (GC): suitable | | mp | 150-157 ℃ (lit.) | | application(s) | pharmaceutical | | 格式 | neat | | SMILES string | O=P(c1ccccc1)(c2ccccc2)c3ccccc3 | | InChI | 1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H | | InChI key | FIQMHBFVRAXMOP-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H302 - H412 | | 预防措施声明 | P264 - P270 - P273 - P301 + P312 - P501 | | 危险分类 | Acute Tox. 4 Oral - Aquatic Chronic 3 | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 2 | | 闪点(F) | 356.0 °F | | 闪点(C) | 180 ℃ |
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| T84603 | Sigma-Aldrich | Triphenylphosphine Oxide | 98% | 362.54元/25 G; 677.85元/100 G; | 咨询 |
产品说明 应用 高三苯基氧化膦可用于： - 用作无环伯醇和仲醇的Appel型氯化反应的催化剂。
- 用作α,β-不饱和酸酯和andβ,γ-不饱和酮酯α-化合物在立体选择性聚和二溴化的催化剂。
- 用作启动子，通过乙醇与呋核亚硝脲碘化物的非对映选择性合成α呋喃糖苷
包装 25, 100 g in poly bottle 基本信息 | 线性分子式 | (C6H5)3PO | | 分子量 | 278.28 | | Beilstein | 745854 | | EC 号 | 212-338-8 | | MDL编号 | MFCD00002080 | | PubChem化学物质编号 | 24900532 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 98% | | reaction suitability | reagent type: ligand
reaction type: Coupling Reactions
reagent type: ligand
reaction type: Epoxidations
reagent type: ligand
reaction type: Michael Reaction | | mp | 150-157 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | O=P(c1ccccc1)(c2ccccc2)c3ccccc3 | | InChI | 1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H | | InChI key | FIQMHBFVRAXMOP-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H302 - H412 | | 预防措施声明 | P264 - P270 - P273 - P301 + P312 - P501 | | 危险分类 | Acute Tox. 4 Oral - Aquatic Chronic 3 | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 2 | | 闪点(F) | 356.0 °F | | 闪点(C) | 180 ℃ | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| PHR2544 | Supelco | Orlistat Related Compound C | Pharmaceutical Secondary Standard; Certified Reference Material | 6214.6元/50 MG; | 咨询 |
产品说明 一般描述 Pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards 分析说明 These secondary standards offer multi-traceability to the USP, EP and BP primary standards, where they are available. 其他说明 This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis. 附注 To see an example of a Certificate of Analysis for this material enter LRAC4611 in the Documents slot below. This is an example certificate only and may not be the lot that you receive. 基本信息 | 线性分子式 | (C6H5)3PO | | 分子量 | 278.28 | | Beilstein | 745854 | | MDL编号 | MFCD00002080 |
产品性质 | 等级 | certified reference material
pharmaceutical secondary standard | | 形式 | solid | | CofA | current certificate can be downloaded | | 包装 | pkg of 50 mg | | mp | 150-157 ℃ (lit.) | | 药典可追溯性 | traceable to USP 1478833 | | 储存温度 | 2-30℃ | | SMILES string | O=P(c1ccccc1)(c2ccccc2)c3ccccc3 | | InChI | 1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H | | InChI key | FIQMHBFVRAXMOP-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H302 - H412 | | 预防措施声明 | P264 - P270 - P273 - P301 + P312 - P501 | | 危险分类 | Acute Tox. 4 Oral - Aquatic Chronic 3 | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 2 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable |
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| 1478833 | USP | Orlistat Related Compound C | United States Pharmacopeia (USP) Reference Standard | 15211.1元/25 MG; | 咨询 |
产品说明 一般描述 This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia. 分析说明 These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind. 其他说明 USP issued SDS can be found here.
Sales restrictions may apply. 基本信息 | 线性分子式 | (C6H5)3PO | | 分子量 | 278.28 | | Beilstein | 745854 | | MDL编号 | MFCD00002080 | | PubChem化学物质编号 | 329750619 | | NACRES | NA.24 |
产品性质 | 等级 | pharmaceutical primary standard | | manufacturer/tradename | USP | | mp | 150-157 ℃ (lit.) | | application(s) | pharmaceutical (small molecule) | | 格式 | neat | | SMILES string | O=P(c1ccccc1)(c2ccccc2)c3ccccc3 | | InChI | 1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H | | InChI key | FIQMHBFVRAXMOP-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H302 - H412 | | 预防措施声明 | P264 - P270 - P273 - P301 + P312 - P501 | | 危险分类 | Acute Tox. 4 Oral - Aquatic Chronic 3 | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 2 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable |
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| NMIQNMR001 | | Triphenylphosphine Oxide | NMI Australia | 2832.31元/100 MG; | 咨询 |
基本信息 | 经验(实验)分子式 | C18H15OP | | 分子量 | 278.28 |
产品性质 | agency | NMI Australia certified reference material | | 质量水平 | 100 | | manufacturer/tradename | NMI Australia | | 格式 | neat | | 储存温度 | −20℃ | | InChI | 1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H | | InChI key | FIQMHBFVRAXMOP-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H302 - H412 | | 预防措施声明 | P264 - P270 - P273 - P301 + P312 - P501 | | 危险分类 | Acute Tox. 4 Oral - Aquatic Chronic 3 | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 2 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable |
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| 976733 | Amethyst | Triphenylphosphine Oxide | 98%, 用于合成 | 52元/25G; 68元/100G; 278元/500G; | 咨询 |
基本信息 | 分子式 | C18H15OP | | 分子量 | 278.28 | | 熔点 | 150-157 | | 闪点 | 180 | | MDL编码 | MFCD00002080 | | Beilstein | 745854 | | EINECS 编号 | 212-338-8 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H302
H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 2 | | RTECS | SZ1676000 | | TSCA | 是 |
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| 215187 | Fluorochem | Triphenylphosphine Oxide | 99% | 220元/10g; 352元/100g; 1232元/500g; | 咨询 |
基本信息 | CAS Number | 791-28-6 | | MDL Number | MFCD00002080 | | Melting Point | 150 - 157 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H412: Harmful to aquatic life with long lasting effects.
| | 防范说明 | P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P501: Dispose of contents/container to in accordance with local regulation .
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