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CAS: 7758-89-6
分子式: ClCu
分子量: 99.00
沸点: 1490℃
熔点: 430℃
中文名称: 
氯化铜(Ⅰ)
一氯化铜
氯化亚铜
英文名称: 
Copper(I)chloride solution
Copper(I)chloride,ACS
Copper(I)chloride
Copper(I) chloride
Cuprous chloride
chlorid medny
copper chloride (cucl)
copper monochloride
copper(1+) chloride
cuprous dichloride
dicopper dichloride
cuprous chloride(cu2cl2)
cuprouschloride(cu2cl2)
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格
C805352MACKLIN氯化亚铜≥99.95% metals basis78元/5g;   236元/25g;   638元/100g;   2598元/500g;   咨询
储存:室温,惰性气体保护
状态:白色到灰白色或灰色或浅绿色粉末
折射率:1.93
C805351MACKLIN氯化亚铜99.999% metals basis107元/1g;   295元/5g;   757元/25g;   2436元/100g;   9466元/500g;   咨询
储存:室温
状态:白色到灰色或浅绿色粉末或晶体
折射率:1.93
C798746MACKLIN氯化亚铜ACS, ≥90%588元/100g;   1999元/500g;   咨询
储存:室温, 干燥
C805349MACKLIN氯化亚铜试剂级, 97%40元/100g;   109元/500g;   436元/2.5kg;   1688元/10kg;   1297元/12X500g;   咨询
储存:室温
状态:白色到灰色或浅绿色粉末或晶体
折射率:1.93
C2162TCICopper(I) Chloride190元/25G;   310元/100G;   520元/500G;   咨询

基本信息

分子式/分子量CuCl = 99.00
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1098236
Merck Index (14)2633
MDL编号MFCD00010971

技术规格

AppearanceWhite to Gray powder to crystal
Puritymin. 98.0 %

物性(参考值)

熔点430 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H373 : 长期或反复接触可能损害器官。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P391 : 收集溢出物。
P314 : 如感觉不适,须求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#GL6990000

运输信息

UN编号UN2802
类别8
包装类别 III
监管条件代码(*)
952467J&KCopper(I) Chloride98%67元/25G;   122元/50g;   咨询

基本信息

分子式CuCl
分子量98.99
熔点430
沸点1490
密度4.14
MDL编码MFCD00010971
Merck14,2660
EINECS 编号231-842-9

安全信息

图形或危害标志
提示语Danger
危险说明H302
H318
H410
防范说明P273
P301+P310
UN号码2802
危险分类8
WGK3
RTECSGL6990000
TSCA
29-0360StremCopper(I) Chloride(99.99%-Cu) PURATREM868元/10g;   3675元/50g;   咨询
93-2914StremCopper(I) chloride, anhydrous97+%543元/250g;   1740元/1kg;   咨询
011871Alfa AesarCopper(I) Chloride97%425元/100g;   737元/500g;   2210元/2kg;   咨询

应用
It is precursor to many copper compounds including copper oxychloride and many organocuprate compounds of synthetic interest. It is used as a catalyst as well as a reagent in many organic reactions including Gatterman-Koch, Sandmeyer, Grignard and Gilman reactions. It catalyzes 1,4-addition of Grignard reagents to alpha,beta-unsaturated ketones. It is also used as a doping salt to enhance the cationization of polystyrene in matrix-assisted laser desorption/ionization mass spectrometry. It is also an intermediate formed in the Wacker process.

备注
Incompatible with oxidizing agents, potassium, and water. Air, light and moisture sensitive.

基本信息

MDL
MFCD00010971

EINECS
231-842-9

分子式
CuCl

分子量
98.99

熔点
430°

沸点
1490°

密度
4.14

折射率
1.93

灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures.

形态
Powder

溶解性
Very soluble in concentrated HCl. Soluble in ammonium hydroxide. Insoluble in ethanol and acetone. Sparingly soluble in water.

Merck
14,2660

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H400-H410
Harmful if swallowed.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P264-P270-P301+P312a-P330-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Rinse mouth.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-50/53
Harmful if swallowed.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
22-60-61
Do not breathe dust.This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
GL6990000

TSCA

041837Alfa AesarCopper(I) Chloride99% (metals basis)1904元/100g;   6523元/500g;   咨询

应用
Copper(I) chloride is precursor to many copper compounds including copper oxychloride and many organocuprate compounds of synthetic interest. It is used as a catalyst as well as a reagent in many organic reactions including Gatterman-Koch, Sandmeyer, Grignard and Gilman reactions. It catalyzes 1,4-addition of Grignard reagents to alpha,beta-unsaturated ketones. It is also used as a doping salt to enhance the cationization of polystyrene in matrix-assisted laser desorption/ionization mass spectrometry. It is also an intermediate formed in the Wacker process.

备注
Incompatible with oxidizing agents, potassium, and water. Air, light and moisture sensitive.

基本信息

MDL
MFCD00010971

EINECS
231-842-9

分子式
CuCl

分子量
98.99

熔点
430°

沸点
1490°

密度
4.14

折射率
1.93

灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures.

形态
-80 Mesh Powder

溶解性
Very soluble in concentrated hydrochloric acid. Soluble in ammonium hydroxide. Insoluble in ethanol and acetone. Sparingly soluble in water.

Merck
14,2660

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H400-H410
Harmful if swallowed.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P264-P270-P301+P312a-P330-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Rinse mouth.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-50/53
Harmful if swallowed.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
22-60-61
Do not breathe dust.This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
GL6990000

TSCA

014644Alfa AesarCopper(I) Chloride99.999% (metals basis)1200元/5g;   2821元/25g;   3366元/100g;   咨询

应用
Copper(I) chloride is precursor to many copper compounds including copper oxychloride and many organocuprate compounds of synthetic interest. It is used as a catalyst as well as a reagent in many organic reactions including Gatterman-Koch, Sandmeyer, Grignard and Gilman reactions. It catalyzes 1,4-addition of Grignard reagents to alpha,beta-unsaturated ketones. It is also used as a doping salt to enhance the cationization of polystyrene in matrix-assisted laser desorption/ionization mass spectrometry. It is also an intermediate formed in the Wacker process.

备注
Incompatible with oxidizing agents, potassium, and water. Air, light and moisture sensitive.

基本信息

MDL
MFCD00010971

EINECS
231-842-9

分子式
CuCl

分子量
98.99

熔点
430°

沸点
1490°

密度
4.14

折射率
1.93

灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures.

形态
Powder

溶解性
Very soluble in concentrated HCl. Soluble in ammonium hydroxide. Insoluble in ethanol and acetone. Sparingly soluble in water.

Merck
14,2660

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H400-H410
Harmful if swallowed.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P264-P270-P301+P312a-P330-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Rinse mouth.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-50/53
Harmful if swallowed.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
22-60-61
Do not breathe dust.This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
GL6990000

TSCA

C19964Alfa AesarCopper(I) Chloride97%, pure683元/25g;   1007元/500g;   2870元/2.5kg;   咨询

基本信息

Ref#
19964

MDL
10971

分子式
Cl Cu

分子量
99

密度
4.14

形态
Powder

安全信息

危险等级
8

包装组
III

C20839Alfa AesarCopper(I) Chloride99%, extra pure, purified1509元/25g;   3679元/100g;   16100元/500g;   咨询

基本信息

Ref#
20839

MDL
10971

分子式
Cl Cu

分子量
99

密度
4.14

形态
Powder

安全信息

危险等级
8

包装组
III

C21242Alfa AesarCopper(I) Chloride99.99%, (trace metal basis), extra pure1213元/10g;   6581元/100g;   咨询

基本信息

Ref#
21242

MDL
10971

分子式
Cl Cu

分子量
99

密度
4.14

形态
Powder

安全信息

危险等级
8

包装组
III

1.02739SupelcoCopper(I) Chloridefor analysis EMSURE® ACS8295.74元/250 G;   咨询

产品说明

分析说明

Assay (manganometric): ≥ 97.0 %
Substances insoluble in acid: ≤ 0.02 %
Sulfate (SO₄): ≤ 0.05 %
As (Arsenic): ≤ 0.0002 %
Ca (Calcium): ≤ 0.01 %
Fe (Iron): ≤ 0.005 %
K (Potassium): ≤ 0.02 %
Na (Sodium): ≤ 0.05 %
Pb (Lead): ≤ 0.02 %
Substances not precipitated by hydrogen sulfide (as SO₄): ≤ 0.5 %
Corresponds to ACS

法律信息

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

基本信息

经验(实验)分子式ClCu
分子量99.00
MDL编号MFCD00010971
EC索引号231-842-9

产品性质

质量水平300
等级ACS reagent
测定≥97.0% (manganometric)
形式solid
效能336 mg/kg LD50, oral (Rat)
pH值(酸碱度)5 (20 ℃, 50 g/L in H2O, slurry)
bp1367 ℃/1013 hPa
mp422 ℃
密度4.14 g/cm3 at 25 ℃
堆积密度1600‑1800 kg/m3
痕量阴离子sulfate (SO42-): ≤0.05%
痕量阳离子As: ≤ 0.0002%
Ca: ≤ 0.01%
Fe: ≤ 0.005%
K: ≤ 0.02%
Na: ≤ 0.05%
Pb: ≤ 0.02%
储存温度2-30℃
InChI1S/ClH.Cu/h1H;/q;+1/p-1
InChI keyOXBLHERUFWYNTN-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H318 - H410
预防措施声明P264 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
212946Sigma-AldrichCopper(I) Chloridereagent grade, 97%642.31元/25 G;   719.76元/500 G;   1908.05元/2 KG;   咨询

产品说明

一般描述

Cu 在 CuCl 中以 + 1(亚铜)价态存在。CuCl 是一种具有宽带隙的半导体。由于其晶格与硅相似,因此是硅光电器件的一种很有前途的候选材料。参与格氏试剂的各种反应。

应用

作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。
氯化铜 (I)(氯化亚铜,CuCl)已用于合成 7-((叔 -丁基二甲基硅基)氧)七-2,4-二炔-1-醇。CuCl 可用于环共轭二烯的立体定向合成。它可用作研究氯化铜络合物在水热溶液中稳定性的反应物。

包装

2 kg in poly bottle
25, 500 g in poly bottle

基本信息

线性分子式CuCl
分子量99.00
EC 号231-842-9
MDL编号MFCD00010971
PubChem化学物质编号329752134
NACRESNA.55

产品性质

质量水平200
等级reagent grade
蒸汽压1.3 mmHg ( 546 ℃)
测定97%
形式powder
reaction suitabilityreagent type: catalyst
core: copper
pH值(酸碱度)5 (20 ℃, 50 g/L)
bp1490 ℃ (lit.)
mp430 ℃ (lit.)
溶解性dimethyl sulfide: partially soluble(lit.)
water: insoluble(lit.)
SMILES stringCl[Cu]
InChI1S/ClH.Cu/h1H;/q;+1/p-1
InChI keyOXBLHERUFWYNTN-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H318 - H410
预防措施声明P264 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
651745Sigma-AldrichCopper(I) ChlorideAnhydroBeads, ≥99.99% trace metals basis849.47元/5 G;   2539元/25 G;   咨询

产品说明

一般描述

铜 (I) 氯化物的结构在室温下与闪锌矿晶体相似,在 407℃ 时结构为纤锌矿,在更高的温度下形成铜 (I) 氯化物蒸气(通过质谱测定)。

应用

作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。
CuCl 可作为引发剂用于 α,β-不饱和酮的湿法锡化及其它类似自由基反应。

包装

5, 25 g in ampule

法律信息

AnhydroBeads is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式CuCl
分子量99.00
EC 号231-842-9
MDL编号MFCD00010971
PubChem化学物质编号24883859

产品性质

质量水平100
蒸汽压1.3 mmHg ( 546 ℃)
产品线AnhydroBeads
测定≥99.99% trace metals basis
reaction suitabilityreagent type: catalyst
core: copper
杂质≤ 100.0  ppm Trace Metal Analysis
bp1490 ℃ (lit.)
mp430 ℃ (lit.)
溶解性slightly soluble 0.47 g/L at 20 ℃
application(s)battery manufacturing
SMILES stringCl[Cu]
InChI1S/ClH.Cu/h1H;/q;+1/p-1
InChI keyOXBLHERUFWYNTN-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H318 - H410
预防措施声明P264 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
229628Sigma-AldrichCopper(I) Chloride≥99.995% trace metals basis1254.64元/10 G;   5352.45元/100 G;   咨询

产品说明

一般描述

氯化铜(I)的结构在室温下类似于闪锌矿晶体;根据质谱分析,该结构在407℃下会成为纤锌矿,在较高温度下,会形成氯化铜(I)蒸气。

应用

作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。
CuCl可以用作α ,α -不饱和酮的锡氢化作用,以及其他类似自由基反应的引发剂。
其显示出作为自由基反应(例如α ,β-不饱和酮的锡氢化作用)引发剂的独特性质。

包装

10, 100 g in poly bottle

基本信息

线性分子式CuCl
分子量99.00
EC 号231-842-9
MDL编号MFCD00010971
PubChem化学物质编号24853291
NACRESNA.23

产品性质

质量水平200
蒸汽压1.3 mmHg ( 546 ℃)
测定≥99.995% trace metals basis
形式powder
reaction suitabilityreagent type: catalyst
core: copper
technique(s)mass spectrometry (MS): suitable
杂质≤50.0  ppm Trace Rare Earth Analysis
bp1490 ℃ (lit.)
mp430 ℃ (lit.)
溶解性slightly soluble 0.47 g/L at 20 ℃
application(s)battery manufacturing
SMILES stringCl[Cu]
InChI1S/ClH.Cu/h1H;/q;+1/p-1
InChI keyOXBLHERUFWYNTN-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H318 - H410
预防措施声明P264 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
224332Sigma-AldrichCopper(I) ChlorideReagentPlus®, purified, ≥99%1619.75元/25 G;   2390.41元/100 G;   咨询

产品说明

一般描述

Cu在CuCl中以+1(亚铜)价态存在。CuCl是一种具有宽带隙的半导体。由于其晶格类似于硅,因此它是一种可用于硅基光电的有前途的候选材料。它可与格氏试剂一起参与各种反应。

应用

作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。
氯化铜(I)(CuCl)已被用于合成铜纳米环结构。 它还被用作在导电氮掺杂石墨烯(NG)上制备有序TiO2纳米阵列的前体。

包装

25, 100 g in poly bottle

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式CuCl
分子量99.00
EC 号231-842-9
MDL编号MFCD00010971
PubChem化学物质编号329752318
NACRESNA.21

产品性质

蒸汽压1.3 mmHg ( 546 ℃)
质量水平100
产品线ReagentPlus®
测定≥99%
形式powder
reaction suitabilityreagent type: catalyst
core: copper
pH值(酸碱度)5 (20 ℃, 50 g/L)
bp1490 ℃ (lit.)
mp430 ℃ (lit.)
SMILES stringCl[Cu]
InChI1S/ClH.Cu/h1H;/q;+1/p-1
InChI keyOXBLHERUFWYNTN-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H318 - H410
预防措施声明P264 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
903127AmethystCopper(I) Chloride97%, 用于分析59元/100G;   188元/500G;   734元/2.5KG;   咨询

基本信息

分子式CuCl
分子量98.99
熔点430
沸点1490
密度4.14
MDL编码MFCD00010971
Merck14,2660
EINECS 编号231-842-9

安全信息

图形或危害标志
提示语Danger
危险说明H302
H400
H410
防范说明P273
P301+P310
UN号码2802
危险分类8
WGK3
RTECSGL6990000
TSCA
094486FluorochemCopper (I) Chloride98%242元/25g;   396元/100g;   792元/250g;   咨询

基本信息

CAS Number7758-89-6
MDL NumberMFCD00010971
Boiling Point1490℃
Melting Point430℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P391: Collect spillage.
P501: Dispose of contents/container to local regulations.
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