[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 7681-65-4
关键词:       仅模糊查询
CAS: 7681-65-4
分子式: CuI
分子量: 190.45
沸点: 1290 °C
熔点: 605 °C(lit.)
中文名称: 
碘化铜
碘化铜(Ⅰ)
一碘化铜
英文名称: 
copper(i)iodide
copper(i} iodide
cuprousiodide
Copper(I)iodide,Puratronic
推荐供应商
货号品牌产品名称规格包装、参考价格
C804589MACKLIN碘化亚铜99.9% metals basis37元/1g;   111元/5g;   343元/25g;   909元/100g;   2965元/500g;   咨询
储存:室温, 避光, 惰性气体保存
状态:灰色到棕色固体
折射率:2.346
C708083MACKLIN碘化亚铜超干级, 99.99%599元/5g;   1078元/10g;   咨询
储存:室温, 避光, 惰性气体保存
折射率:2.346
C804587MACKLIN碘化亚铜试剂级, ≥99%37元/10g;   102元/50g;   160元/100g;   398元/250g;   1510元/1kg;   7200元/5kg;   咨询
储存:室温, 避光, 惰性气体保存
状态:灰色到棕褐色到棕色粉末,纤维或晶体
折射率:2.346
C2163TCICopper(I) Iodide>98.0%(T)150元/25G;   590元/100G;   1990元/500G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量CuI = 190.45
外观与形状(20℃)固体
Reaxys-RN11405916
Merck Index (14)2662
MDL编号MFCD00010978

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(Chelometric Titration)min. 98.0 %

物性(参考值)

熔点601 ℃
水溶性不溶

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
H373 : 长期或反复接触可能损害器官。
H317 : 可能造成皮肤过敏反应。
H335 : 可能造成呼吸道刺激。
H400 : 对水生生物毒性极大。
H411 : 对水生生物有毒并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P272 : 受沾染的工作服不得带出工作场地。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P391 : 收集溢出物。
P314 : 如感觉不适,须求医/就诊。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
988790J&KCopper(I) Iodide98%200元/50G;   763元/250G;   咨询

基本信息

分子式CuI
分子量190.45
熔点605
沸点1290
MDL编码MFCD00010978
Merck14,2662
EINECS 编号231-674-6

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
H410
防范说明P261
P273
P305+P351+P338
UN号码3077
危险分类9
包装等级III
WGK3
TSCA
29-0485StremCopper(I) Iodide(99.999%-Cu) PURATREM780元/10g;   2595元/50g;   咨询
29-0490StremCopper(I) iodide/cesium carbonate admixture5.50 wt% CuI540元/5g;   1905元/25g;   咨询

Technical Note:

1.Copper catalyst/base admixture useful for screening reactions involving the N-arylation of nitrogen- containing heterocycles .

Reference:

1. J. Org. Chem., 2007. 72, 8535.

93-2936StremCopper(I) Iodide98%540元/100g;   2190元/500g;   咨询
011606Alfa AesarCopper(I) Iodide98%1597元/250g;   4817元/1kg;   咨询

应用
It is used as a catalyst in organic synthesis, cathode ray tube coating, cloud seeding, and as temperature indicator with HgI2. It catalyzes the conversion of aryl, heteroaryl, and vinyl bromides into the corresponding iodides, which are employed in coupling reactions such as Suzuki, Stille, Sonogashira, Heck and Ullmann reactions.

备注
It is generally stable in air and is photosensitive.

基本信息

MDL
MFCD00010978

EINECS
231-674-6

分子式
CuI

分子量
190.45

熔点
605°

沸点
ca 1290°

密度
5.63

折射率
2.346

灵敏度
Moisture Sensitive. Air Sensitive. Light Sensitive. Ambient temperatures.

形态
Powder

溶解性
Copper(I) iodide is soluble in ammonia, thiosulfate, sodium and potassium iodide solutions. Insoluble in water and dilute acids.

Merck
14,2662

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335-H400-H410
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
22-36/37/38-50/53
Harmful if swallowed.Irritating to eyes, respiratory system and skin.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-36/37-57-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

043153Alfa AesarCopper(I) IodidePuratronic庐, 99.998% (metals basis)768元/5g;   2597元/25g;   8003元/100g;   咨询

应用
Copper(I) iodide is used as a catalyst in organic synthesis, cathode ray tube coating, cloud seeding, and as temperature indicator with HgI2. It catalyzes the conversion of aryl, heteroaryl, and vinyl bromides into the corresponding iodides, which are employed in coupling reactions such as Suzuki, Stille, Sonogashira, Heck and Ullmann reactions.

备注
It is generally stable in air and is photosensitive.

基本信息

MDL
MFCD00010978

EINECS
231-674-6

分子式
CuI

分子量
190.45

熔点
605°

沸点
ca 1290°

密度
5.63

折射率
2.346

灵敏度
Moisture Sensitive. Air Sensitive. Light Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Chunks/powder

溶解性
Copper(I) iodide is soluble in ammonia, thiosulfate, sodium and potassium iodide solutions. Insoluble in water and dilute acids.

Merck
14,2662

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335-H400-H410
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
22-36/37/38-50/53
Harmful if swallowed.Irritating to eyes, respiratory system and skin.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-36/37-57-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C20150Alfa AesarCopper(I) Iodide99.995%, (trace metal basis)791元/5g;   2658元/25g;   5657元/100g;   咨询

基本信息

Ref#
20150

MDL
10978

分子式
Cu I

分子量
190.45

形态
Powder

安全信息

危险等级
9

包装组
III

C19490Alfa AesarCopper(I) Iodide98%1585元/250g;   5166元/1kg;   21682元/5kg;   咨询

基本信息

Ref#
19490

MDL
10978

分子式
Cu I

分子量
190.45

安全信息

危险等级
9

包装组
III

215554Sigma-AldrichCopper(I) Iodide99.999% trace metals basis806.81元/5 G;   2736.65元/25 G;   4957.97元/100 G;   59140.1元/1 KG;   咨询

产品说明

包装

25, 100 g in poly bottle
5 g in amber poly bottle
1 kg in poly bottle

应用

用于硅杂环丙烷与羰基化合物的立体选择性和区域选择性反应的最佳催化剂。
胺和氨基酸 N-芳基化的催化剂;次磺酰胺的合成。

基本信息

经验(实验)分子式CuI
分子量190.45
EC 号231-674-6
MDL编号MFCD00010978
eCl@ss38150105
PubChem化学物质编号24852902
NACRESNA.23

产品性质

质量水平200
蒸汽压10 mmHg ( 656 ℃)
测定99.999% trace metals basis
形式powder and chunks
杂质≤15.0  ppm Trace Metal Analysis
bp1290 ℃/1 atm (decomp)(lit.)
mp605 ℃ (lit.)
溶解性dilute aqueous acid: insoluble(lit.)
密度5.62 g/mL at 25 ℃ (lit.)
application(s)battery manufacturing
SMILES string[Cu+].[I-]
InChI1S/Cu.HI/h;1H/q+1;/p-1
InChI keyLSXDOTMGLUJQCM-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H317 - H318 - H410
预防措施声明P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
205540Sigma-AldrichCopper(I) Iodide98%572.04元/50 G;   1106.26元/250 G;   4674.49元/1 KG;   咨询

产品说明

应用

硅环丙烷和羰基化合物立体专一性和区域选择性反应最佳催化剂。

包装

50, 250 g in glass bottle
1 kg in glass bottle

基本信息

经验(实验)分子式CuI
分子量190.45
EC 号231-674-6
MDL编号MFCD00010978
eCl@ss38150105
PubChem化学物质编号329752013
NACRESNA.21

产品性质

质量水平200
蒸汽压10 mmHg ( 656 ℃)
测定98%
形式powder
reaction suitabilityreaction type: click chemistry
reagent type: catalyst
core: copper
mp605 ℃ (lit.)
密度5.62 g/mL at 25 ℃ (lit.)
SMILES string[Cu+].[I-]
InChI1S/Cu.HI/h;1H/q+1;/p-1
InChI keyLSXDOTMGLUJQCM-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H317 - H318 - H410
预防措施声明P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
792063Sigma-AldrichCopper(I) Iodideanhydrous, 99.995% trace metals basis888.19元/5 G;   咨询

产品说明

应用

a碘化铜在有机反应中有许多应用,包括活性自由基聚合(原子转移自由基聚合或 ATRP)和交叉偶联反应。CuI 还已经用于制造太阳能电池、光致发光和纳米晶体合成。

基本信息

经验(实验)分子式CuI
分子量190.45
EC 号231-674-6
MDL编号MFCD00010978
PubChem化学物质编号329768311
NACRESNA.23

产品性质

质量水平200
等级anhydrous
蒸汽压10 mmHg ( 656 ℃)
测定99.995% trace metals basis
形式powder
杂质≤ 55.0  ppm Trace Metal Analysis
mp605 ℃ (lit.)
密度5.62 g/mL at 25 ℃ (lit.)
application(s)battery manufacturing
SMILES string[Cu+].[I-]
InChI1S/Cu.HI/h;1H/q+1;/p-1
InChI keyLSXDOTMGLUJQCM-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H317 - H318 - H410
预防措施声明P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
8.18311Sigma-AldrichCopper(I) Iodidefor synthesis318.45元/100 G;   咨询

产品说明

分析说明

Assay (iodometric): ≥ 98.0 %

基本信息

经验(实验)分子式CuI
分子量190.45
MDL编号MFCD00010978
EC索引号231-674-6

产品性质

质量水平200
bp1290 ℃/1013 hPa
mp588 ℃
溶解性 0.08 g/L
密度5.62 g/cm3 at 20 ℃
堆积密度1400 kg/m3
储存温度2-30℃
InChI1S/Cu.HI/h;1H/q+1;/p-1
InChI keyLSXDOTMGLUJQCM-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H315 - H317 - H318 - H410
预防措施声明P261 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
945192AmethystCopper(I) Iodide98%, 用于合成75元/50G;   294元/250G;   747元/1KG;   咨询

基本信息

分子式CuI
分子量190.45
熔点605
沸点1290
MDL编码MFCD00010978
Merck14,2662
EINECS 编号231-674-6

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
H410
防范说明P261
P273
P305+P351+P338
UN号码3077
危险分类9
包装等级III
WGK3
TSCA
044771FluorochemCopper (I) iodide98%374元/100g;   1320元/500g;   2200元/1kg;   咨询

基本信息

CAS Number7681-65-4
MDL NumberMFCD00010978
Boiling Point1290℃
Melting Point605℃
Density5.67

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H372: Causes damage to organs Causes damage to thyroid by oral route through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
H411: Toxic to aquatic life with long lasting effects.
H317: May cause an allergic skin reaction
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9