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CAS: 76513-69-4
分子式: C6H15ClOSi
分子量: 166.72
沸点: 57-59℃(8
英文名称: 
(2-Chloromethoxyethyl)trimethylsilane
2-(Chloromethoxy)ethyltrimethylsilane
SEM-Chloride
2-(trimethylsilyl)ethoxymethyl chloride
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基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C6H15ClOSi = 166.72
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (分解),加热
Reaxys-RN3587289
PubChem物质ID87566351
MDL编号MFCD00009919

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点59 ℃/8 mmHg
闪点46 ℃
比重0.95

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

运输信息

UN编号UN2920
类别8 / 3
包装类别 II
监管条件代码(*)
178729J&K2-(Trimethylsilyl)ethoxymethyl chloride95%, 含稳定剂: 10 ppm N,N-二异丙基乙胺293元/1ML;   941元/5ml;   3278元/25ml;   咨询

基本信息

分子式C6H15ClOSi
分子量166.72
沸点170-172
闪点46
密度0.942
折光率(n20D)1.4350
MDL编码MFCD00009919
Beilstein3587289
EINECS 编号278-483-4
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H226
H314
H318
防范说明P280
P305+P351+P338
P310
P301+P330+P331
UN号码2920
危险分类8
次要危险性3
包装等级II
WGK3
327348J&K2-(Trimethylsilyl)ethoxymethyl chloride90%, 含稳定剂: 10 ppm N,N-二异丙基乙胺201元/1ML;   646元/5ML;   2511元/25ML;   咨询

基本信息

分子式C6H15ClOSi
分子量166.72
沸点170-172
闪点46
密度0.942
折光率(n20D)1.4350 - 1.4370
MDL编码MFCD00009919
Beilstein3587289
EINECS 编号278-483-4
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H226
H314
H318
防范说明P280
P305+P351+P338
P310
P301+P330+P331
UN号码2920
危险分类8
次要危险性3
包装等级II
WGK3
H55074Alfa Aesar2-(Chloromethoxy)ethyltrimethylsilanetech. 90%, stab. with 0.1% N,N-Diisopropylethylamine452元/1g;   960元/5g;   3747元/25g;   咨询

应用
2-(Chloromethoxy)ethyltrimethylsilane is used in the preparation of SEM [2-(trimethylsilyl)ethoxy]methyl]-ethers. It serves as a phenol protecting group in the synthesis of laterifluorones. Further, it reacts with 1H-imidazole to prepare 1-(2-trimethylsilanyl-ethoxymethyl)-1H-imidazole.

备注
Store in a cool place. Moisture sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00009919

EINECS
278-483-4

分子式
C6H15ClOSi

分子量
166.72

沸点
170-172°

闪点
46°(115°F)

密度
0.942

折射率
1.4350

灵敏度
Keep Cold. Moisture Sensitive. Store under Nitrogen.

形态
Liquid

Beilstein
3587289

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H314-H318
Flammable liquid and vapour.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
10-34
Flammable.Causes burns.

安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C21902Alfa Aesar2-(Trimethylsilyl)ethoxymethyl chloride90%, tech., stabilized3251元/5ml;   11047元/25ml;   34007元/100ml;   咨询

基本信息

Ref#
21902

MDL
9919

分子式
C6 H15 Cl O Si

分子量
166.72

闪点
46

密度
0.94

形态
Colorless liquid

安全信息

危险等级
8

包装组
II

S03978Fluorochem2-(Chloromethoxyethyl)trimethyl silane95%1100元/5g;   2200元/25g;   6380元/100g;   咨询

基本信息

CAS Number76513-69-4
MDL NumberMFCD00009919
Boiling Point57-59℃/8mmHg
Density0.95

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use CO2, dry chemical powder, alcoholic or polymer foam for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local.
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