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CAS: 71597-85-8
分子式: C6H7BO3
分子量: 137.92
熔点: >230 °C(lit.)
中文名称: 
4-羟基苯硼酸
对羟基苯硼酸
英文名称: 
4-hydroxybenzeneboronic acid
4-Hydroxyphenylboronic acid
4-Boronophenol
推荐供应商
货号品牌产品名称规格包装、参考价格
H804864MACKLIN4-羟基苯硼酸97%29元/1g;   45元/5g;   206元/25g;   815元/100g;   4010元/500g;   咨询
储存:2~8℃
状态:白色到灰白色到橙色到红色到棕色粉末或晶体
H1228TCI4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride)160元/1G;   550元/5G;   咨询

基本信息

分子式/分子量C6H7BO3 = 137.93
外观与形状(20℃)固体
Reaxys-RN2963491
PubChem物质ID87559892
MDL编号MFCD01074628

技术规格

AppearanceWhite to Gray to Brown powder to crystal
Purity(Neutralization titration)97.0 to 115.0 %

物性(参考值)

熔点232 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
246703J&K4-Hydroxyphenylboronic acid98%140元/1G;   389元/5G;   1239元/25G;   咨询

基本信息

分子式C6H7BO3
分子量137.93
熔点>230
MDL编码MFCD01074628
Beilstein2963491

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA否
L15594Alfa Aesar4-Hydroxybenzeneboronic acid97%659元/1g;   2419元/5g;   咨询

应用
4-Hydroxybenzeneboronic acid is used for Suzuki-Miyaura coupling and Stille coupling and potential for introducing different alkyl groups, palladium-catalyzed aminocarbonylation and cross-coupling reactions, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles. It is also used in preparation of rod-like dendronized polymers.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.

基本信息

MDL
MFCD01074628

EINECS
000-000-0

分子式
C6H7BO3

分子量
137.93

熔点
ca 285° dec.

灵敏度
Ambient temperatures.

溶解性
Soluble in water

Beilstein
2963491

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

C36942Alfa Aesar4-Hydroxyphenylboronic acid97%908元/1g;   2806元/5g;   咨询

基本信息

Ref#
36942

MDL
01074628

分子式
C6 H7 B O3

分子量
137.93

523976Sigma-Aldrich4-Hydroxyphenylboronic acid≥95.0%166.64元/1 G;   363.51元/5 G;   咨询

产品说明

应用

4-羟基苯硼酸可用作以下反应的反应物:

  • Suzuki-Miyaura 偶联反应和Stille 偶联反应
  • 钯催化的氨基羰基化和交叉偶联反应
  • 制备可用作无膦催化剂的生物负载钯纳米颗粒的Suzuki 反应
  • Cu 2 O 催化四唑的好氧氧化交叉偶联反应

它也可用于制备/促进:
  • PDK1 抑制活性(癌细胞生长、存活和肿瘤发生抑制剂)
  • 通过大分子单体途径和活性 ROMP 反应形成含G4 和 G5 酯树突的棒状树枝状聚合物
  • 雌激素环巴胺类似物作为音猬因子信号传导抑制剂用于抗癌化疗
  • 治疗革兰氏阴性菌感染的酶抑制剂
  • 通过钯催化的Suzuki-Miyaura交叉偶联生成的寡聚芳烃(oligoarene)

包装

1, 5 g in glass bottle

其他说明

含有不定量的酸酐

基本信息

线性分子式HOC6H4B(OH)2
分子量137.93
MDL编号MFCD01074628
PubChem化学物质编号24874383
NACRESNA.22

产品性质

质量水平100
测定≥95.0%
mp>230 ℃ (lit.)
SMILES stringOB(O)c1ccc(O)cc1
InChI1S/C6H7BO3/c8-6-3-1-5(2-4-6)7(9)10/h1-4,8-10H
InChI keyCOIQUVGFTILYGA-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
226587Amethyst4-Hydroxyphenylboronic acid98%, 用于合成61元/1G;   116元/5G;   281元/25G;   875元/100G;   4370元/500G;   咨询

基本信息

分子式C6H7BO3
分子量137.93
熔点>230
MDL编码MFCD01074628
Beilstein2963491

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA否
050303Fluorochem4-Hydroxyphenylboronic acid98%220元/1g;   264元/5g;   704元/25g;   1980元/100g;   咨询

基本信息

CAS Number71597-85-8
MDL NumberMFCD01074628
Melting Point264-267℃
Density1.32

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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