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CAS: 70693-62-8
分子式: H3K5O18S4
分子量: 614.76
中文名称: 
五钾双(过硫酸盐)双(硫酸盐)
英文名称: 
Potassium peroxymonosulfate sulfate
Potassium hydrogen peroxymonosulfate
potassium peroxymonosulfate sulfate (k5h3(so3(o2))2(so4)2)
potassium monopersulfate triple salt
potassium peroxomonosulfate
potassiumperoxymonosulfatesulfate,(2khso5.khso4.k2So4)
推荐供应商
货号品牌产品名称规格包装、参考价格
P821909MACKLIN过硫酸氢钾42%~46% KHSO5 basis48元/100g;   132元/500g;   256元/1kg;   568元/2.5kg;   998元/5kg;   2995元/25kg;   1568元/12X500g;   咨询
储存:室温
状态:白色粉末或颗粒
P708886MACKLIN过一硫酸氢钾复合盐Active Oxygen4.5%82元/100g;   148元/500g;   288元/1kg;   1198元/5kg;   咨询
储存:室温
状态:白色粉末或颗粒
624870J&KOxonelr monopersulfate379元/100G;   607元/1KG;   1941元/5KG;   咨询

基本信息

分子式2KHSO5KHSO4K2SO4
分子量614.76
密度1.15
MDL编码MFCD00040551
EINECS 编号274-778-7

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
H411
防范说明P260
P273
P280
P301+P312
P303+P361+P353
P305+P351+P338
UN号码3260
危险分类8
包装等级II
WGK2
TSCA
19-5395StremPotassium monoperoxysulfate OXONE585元/25g;   681元/100g;   咨询

Technical Note:

1.Reagent for the catalytic as ymmetric Shi epoxidation

2.Reagent for the synthesis of nitro heteroaromatics in water

3.Reagent for the syntheses of benzoxazoles and benzothiazoles using aryl iodides via C-H functionalization and C-O/S bond formation

4.R eagent used for bromolactonization in the as ymmetric total synthesis of (+ ) Dubiusamine c

5.Reagent for the benzofuran oxidative dearomatization cascade in the total synthesis of Integrastatin B

References: 1.J. Am. Chem. Soc., 1997, 1 19, 1 1224. 2.J. Org. Chem., 2006, 71, 1715. 3.J. Org. Chem., 2007, 72, 4093. 4.J. Org. Chem., 2008, 73, 9539. 5.Org. L ett., 2009, 1 1, 5150. 6.J. Org. Chem., 2009, 74, 6335. 7.Org. Process Res. Dev., 2014, 18, 886. 8.J. Org. Chem., 2014, 79, 7502. 9.J. Org. Chem., 2015, 80, 9132. 10.Org. L ett., 2016, 18, 1458.
089892Alfa AesarOxone®monopersulfate547元/100g;   876元/1kg;   2841元/5kg;   咨询

应用
Oxone is used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation. It is a used for rapid, and good synthesis of oxaziridines.

备注
Hygroscopic. Keep container tightly closed in a dry and well-ventilated place. Store away from water and moisture.

基本信息

MDL
MFCD00040551

EINECS
274-778-7

分子式
2KHSO5.KHSO4.K2SO4

分子量
615.50

密度
1.15

灵敏度
Hygroscopic. Ambient temperatures.

形态
Granular

溶解性
Soluble in water (100 mg/ml).

GHS危害和防范说明

GHS符号

Hazard Statements
H272-H302-H314-H318-H334-H317
May intensify fire; oxidizer.Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause allergy or asthma symptoms or breathing difficulties if inhaled.May cause an allergic skin reaction.

Precautionary Statements
P221-P210a-P303+P361+P353-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.Keep away from heat. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
8-22-34-42/43
Contact with combustible material may cause fire.Harmful if swallowed.Causes burns.May cause sensitization by inhalation and skin contact.

安全等级
17-20-22-26-36/37/39-45-60
Keep away from combustible material.When using do not eat or drink.Do not breathe dust.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C21136Alfa AesarPotassium peroxomonosulfateextra pure, min. 4.5% active oxygen1051元/100g;   1375元/1kg;   2917元/2.5kg;   咨询

基本信息

Ref#
21136

MDL
40551

分子式
H3 K5 O18 S4

分子量
614.78

安全信息

危险等级
5.1

包装组
III

228036Sigma-AldrichOXONE®, monopersulfate compound442.76元/5 G;   773.06元/100 G;   943.14元/1 KG;   2757.34元/5 KG;   13206.1元/25 KG;   咨询

产品说明

一般描述

OXONE®单过硫酸钾氧酮是一种钾三元盐,主要用作稳定、易处理、无毒的氧化剂。

应用

用于卤化a、b不饱和羰基化合物的氧化剂和催化生成用于酒精氧化高价碘试剂的氧化剂。

2-碘氧基苯磺酸是一种非常活跃的催化剂,可选择性地将醇氧化为醛、酮、羧酸和烯酮与过氧单磺酸钾反应

α,β-不饱和羰基化合物与过氧单磺酸钾®和氢卤酸(HBr, HCl)的便捷卤化反应
据报道,使用缓冲的 OXONE 可以快速有效地从亚胺合成氧氮杂环丙烷。也用于研究美术颜料的褪色。
OXONE®单过硫酸盐化合物可作为过渡金属氧化剂的替代品,用于将醛类转化为羧酸或酯类。
用于卤化α,β不饱和羰基化合物和催化生成用于酒精氧化的高价碘试剂的氧化剂。

包装

100 g in poly bottle
5 g in glass bottle
5 kg in poly drum
1 kg in poly bottle
25 kg in fiber drum

法律信息

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

基本信息

线性分子式KHSO5 · 0.5KHSO4 · 0.5K2SO4
分子量307.38
MDL编号MFCD00040551
PubChem化学物质编号57648006
NACRESNA.21

产品性质

蒸汽压<0.0000017 hPa
质量水平100
测定>4.0% active oxygen basis (by Na2S2O3, titration)
形式powder
reaction suitabilityreagent type: oxidant
pH值(酸碱度)2.1 (77 ℃, 30 g/L)
SMILES string[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O
InChI1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5
InChI keyHJKYXKSLRZKNSI-UHFFFAOYSA-I
911356Sigma-AldrichOXONE®, monopersulfate compoundfree-flowing, Redi-Dri523.64元/100 G;   咨询

产品说明

一般描述

OXONE®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.

应用

用于卤化a、b不饱和羰基化合物的氧化剂和催化生成用于酒精氧化高价碘试剂的氧化剂。

2-碘氧基苯磺酸是一种非常活跃的催化剂,可选择性地将醇氧化为醛、酮、羧酸和烯酮与过氧单磺酸钾反应

α,β-不饱和羰基化合物与过氧单磺酸钾®和氢卤酸(HBr, HCl)的便捷卤化反应
据报道,使用缓冲的 OXONE 可以快速有效地从亚胺合成氧氮杂环丙烷。也用于研究美术颜料的褪色。
OXONE®单过硫酸盐化合物可作为过渡金属氧化剂的替代品,用于将醛类转化为羧酸或酯类。
用于卤化α,β不饱和羰基化合物和催化生成用于酒精氧化的高价碘试剂的氧化剂。
Redi-Dri is an innovative packaging product line that helps eliminate clumping material by adding extra packaging process steps without any chemical additives, anti-clumping agents, or hydrophobic compounds. Redi-Dri offers a more convenient and safer way to handle the products.

法律信息

OXONE is a registered trademark of E. I. du Pont de Nemours and Company
Redi-Dri is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式KHSO5 · 0.5KHSO4 · 0.5K2SO4
分子量307.38
MDL编号MFCD00040551

产品性质

产品线Redi-Dri
测定>4.0% active oxygen basis (by Na2S2O3
by Na2S2O3 basis
, titration)
形式powder
质量free-flowing
pH值(酸碱度)2-3 (10 g/L in aqueous solution, pH <6.0)
SMILES string[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O
InChI1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5
InChI keyHJKYXKSLRZKNSI-UHFFFAOYSA-I

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H411
预防措施声明P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
8.18401Sigma-AldrichPotassium hydrogen monopersulfatefor synthesis322.51元/100 G;   397.48元/500 G;   咨询

产品说明

分析说明

Assay (iodometric): 43.0 - 47.0 %

基本信息

经验(实验)分子式H3K5O18S4
分子量614.76
MDL编号MFCD00040551
EC索引号274-778-7

产品性质

质量水平200
效能>2000 mg/kg LD50, oral (Rat)
reaction suitabilityreagent type: oxidant
pH值(酸碱度)2-3 (20 ℃, 10 g/L in H2O)
溶解性soluble 250-300 g/L
密度2.35 g/cm3 at 20 ℃

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H411
预防措施声明P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
BIOC-054N-500MGAccuStandardPotassium monopersulfate triple salt232元/500mg;   咨询
Potassium monopersulfate triple salt过一硫酸氢钾复合盐70693-62-8
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