CAS 7051-34-5; 环丙基溴甲烷; Cyclopropylmethylbromide

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货号

品牌

产品名称

规格

包装、参考价格

B802660

MACKLIN

(溴甲基)环丙烷

97%

29元/1g; 34元/5g; 124元/25g; 481元/100g;

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储存：2~8°C
状态：无色到黄色液体
折射率：n20/D 1.457(lit.)

B1382

TCI

(Bromomethyl)cyclopropane

>97.0%(GC)

295元/5G; 990元/25G;

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基本信息

纯度/分析方法	>97.0%(GC)
分子式/分子量	C₄H₇Br = 135.00
外观与形状(20℃)	液体
储存温度	0-10℃
应避免的情况	加热
Reaxys-RN	605296
PubChem物质ID	125308638
SDBS (AIST Spectral DB)	21947
MDL编号	MFCD00001306

技术规格

Appearance	Colorless to Light yellow clear liquid
Purity(GC)	min. 97.0 %

物性(参考值)

沸点	106 ℃
闪点	41 ℃
比重	1.42
折射率	1.47

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H226 : 易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号	UN1993
类别	3
包装类别	III
监管条件代码(*)

140139

J&K

(Bromomethyl)cyclopropane

96%

178元/1G; 398元/5G; 1194元/25G;

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基本信息

分子式	C₄H₇Br
分子量	135.00
沸点	105-107
闪点	42
密度	1.392
折光率(n20D)	1.4750 - 1.4790
MDL编码	MFCD00001306
Beilstein	605296
EINECS 编号	230-331-8
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Warning
危险说明	H226 H302 H315 H319 H335
防范说明	P210 P261 P280 P301+P312 P302+P352
UN号码	1993
危险分类	3
包装等级	III
WGK	3
TSCA	否

L01122

Alfa Aesar

(Bromomethyl)cyclopropane

97%

777元/1g; 2508元/5g; 9669元/25g;

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应用
(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents. It has been used as a synthetic building block for the introduction of the cyclopropylmethyl group.

备注
Protect from heat. Store away from oxidizing agents. Incompatible with strong bases, strong oxidizing agents.

基本信息

MDL
MFCD00001306

EINECS
230-331-8

分子式
C₄H₇Br

分子量
135.00

沸点
111-112°

闪点
41°(105°F)

密度
1.410

折射率
1.4770

灵敏度
Keep Cold.

形态
Liquid

溶解性
Not miscible in water.

Beilstein
605296

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H302-H315-H319-H335
Flammable liquid and vapour.Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-22-36/37/38
Flammable.Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
23-26-36/37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

C22181

Alfa Aesar

(Bromomethyl)cyclopropane

96%

1024元/1g; 2578元/5g; 14535元/25g;

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基本信息

Ref#
22181

MDL
1306

分子式
C4 H7 Br

分子量
135

闪点
41

密度
1.38

形态
Liquid

安全信息

危险等级
3

包装组
III

125318

Amethyst

(Bromomethyl)cyclopropane

96%, 用于合成

82元/5G; 222元/25G; 654元/100G; 2567元/500g;

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基本信息

分子式	C₄H₇Br
分子量	135.00
沸点	105-107
闪点	42
密度	1.392
折光率(n20D)	1.4750 - 1.4790
MDL编码	MFCD00001306
Beilstein	605296
EINECS 编号	230-331-8
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Warning
危险说明	H226 H302 H315 H319 H335
防范说明	P210 P261 P280 P301+P312 P302+P352 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	III
WGK	3
TSCA	否

003713

Fluorochem

Cyclopropylmethyl Bromide

98%

528元/25g; 1210元/100g;

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基本信息

CAS Number	7051-34-5
MDL Number	MFCD00001306
Boiling Point	105-107℃
Density	1.392

安全信息

图形或危害标志
危险性说明	H226: Flammable liquid and vapour. H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use CO2 for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.