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CAS: 696-62-8
分子式: C7H7IO
分子量: 234.03
沸点: 237℃(726
熔点: 46-51℃
中文名称: 
对碘苯甲醚
4-碘苯甲醚
4-甲氧基碘苯
对碘茴香醚
4-碘茴香醚
英文名称: 
4-Iodophenylmethyl ether
benzene,1-iodo-4-methoxy-
anisole,4-iodo-
1-iodo-4-methoxybenzene
4-Iodomethoxy-benzene
1-iodo-4-methoxy-benzen
4-iodoanisole
p-Iodoanisole
4-Iodophenyl methyl ether
4-Methoxyiodobenzene
性质描述: 白色针状结晶。熔点51-52℃,沸点237℃(96.8kPa)。溶于醇、醚等有机溶剂,不溶于水。见光易分解析出碘。
生产方法: 由苯甲醚与氯化碘反应而得。将苯甲醚加入冰醋酸中,搅拌并缓缓加入氯碘。加毕升温回流3.5h。冷却,倒入冰水中,析出对碘苯甲醚。将其分出后用5%亚硫酸钠洗去游离碘,然后水洗,减压蒸馏,收集沸点140-160℃(5.33kPa)馏分,冷至0℃过滤。用甲醇洗涤、重结晶,即得成品。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
I811789MACKLIN4-碘苯甲醚97%29元/5g;   65元/25g;   219元/100g;   1041元/500g;   展开
储存:室温,避光
状态:白色到黄色到棕色粉末,晶体或块状
I0378TCI4-Iodoanisole>99.0%(GC)320元/25G;   980元/100G;   2690元/500G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C7H7IO = 234.04
外观与形状(20℃)固体
应避免的情况
Reaxys-RN1906692
PubChem物质ID87571731
SDBS (AIST Spectral DB)680
MDL编号MFCD00001056

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(GC)min. 99.0 %
Melting point49.0 to 52.0 ℃
Solubility in Methanolalmost transparency

物性(参考值)

熔点51 ℃
沸点240 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
557266J&K4-Iodoanisole98%166元/25G;   516元/100G;   2064元/500G;   展开

基本信息

分子式C7H7IO
分子量234.03
熔点50-53
沸点237
闪点112
MDL编码MFCD00001056
Beilstein1906692
EINECS 编号211-789-7

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
A12144Alfa Aesar4-Iodoanisole98+%645元/25g;   1702元/100g;   7643元/500g;   展开

应用
4-Iodoanisole is used in wide range of medicals industrial applications as well as in human and animal nutrition products, pharmaceutical intermediates, polarizing films for Liquid Crystal Display (LCD) chemicals. Iodine derivatives are also used as organic building blocks, analytical reagents.

备注
Light sensitive. Store in the dark. Store away from oxidizing agents, light.

基本信息

MDL
MFCD00001056

EINECS
211-798-7

分子式
C7H7IO

分子量
234.04

熔点
48-52°

沸点
240°

闪点
>110°(230°F)

灵敏度
Light Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in ethanol, ether, chloroform.

Beilstein
1906692

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C12232Alfa Aesar4-Iodoanisole98%844元/25g;   2106元/100g;   8396元/500g;   展开

基本信息

Ref#
12232

MDL
1056

分子式
C7 H7 I O

分子量
234.04

闪点
>110

形态
White to pale brown cryst powder

I7608Sigma-Aldrich4-Iodoanisole98%366.92元/25 G;   1147.26元/100 G;   展开

基本信息

线性分子式IC6H4OCH3
分子量234.03
Beilstein1906692
EC 号211-798-7
MDL编号MFCD00001056
PubChem化学物质编号24896119
NACRESNA.22

产品性质

质量水平100
测定98%
bp237 ℃/726 mmHg (lit.)
mp50-53 ℃ (lit.)
SMILES stringCOc1ccc(I)cc1
InChI1S/C7H7IO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
InChI keySYSZENVIJHPFNL-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)233.6 °F - closed cup
闪点(C)112 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
001304Fluorochem4-Iodoanisole99%550元/25g;   1166元/100g;   4070元/500g;   展开

基本信息

CAS Number696-62-8
MDL NumberMFCD00001056
Boiling Point237℃
Melting Point47-54℃
Density1.7904

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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