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CAS: 696-59-3
分子式: C6H12O3
分子量: 132.16
沸点: 145-147℃
熔点: -45-147℃
中文名称: 
2,5-二甲氧基四氢呋喃
四氢-2,5-二甲氧基呋喃
英文名称: 
2,5-Dimethoxytetrahydrofuran
Tetrahydro-2,5-dimethoxyfuran
tetrahydro-2,5-dimethoxy-Furan
tetrahydro-2,5-dimethoxy-fura
2,5-dimethoxytetrahydrofuran, mixture of cis- and trans isomers
Furan,tetrahydro-2,5-dimethoxy-
2,5-Dimethoxytetrahydrofuran,mixture of cis and trans
2,5-Dimethoxytetrahydrofuran,cis +trans
dimethoxytetra hydrofuran(tetrahydro-2,5-demethoxy-furan)
性质描述: 无色液体。沸点145-147℃,52-54℃(2.93kPa),相对密度1.023(20/4℃),折光率1.4182-1.4184,闪点35℃。能与水、乙醇、乙醚混溶。受热易分解。
生产方法: 由2,5-二甲氧基二氢呋喃([332-77-4])经催化氢化而得。将呋喃用甲醇醚化,在接近常压下催化氢化也可以制备该品,但收率较低。
用途: 该品为抗胆碱药物阿托品硫酸盐的中间体。还用作照相坚膜剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807291MACKLIN2,5-二甲氧基四氢呋喃98%,mixture of cis and trans30元/25g;   83元/100g;   403元/500g;   1990元/2.5kg;   展开
储存:室温,易燃物区域
状态:无色到浅黄色液体
折射率:n20/D 1.418
D0986TCI2,5-Dimethoxytetrahydrofuran (cis- and trans- mixture)>98.0%(GC)180元/25G;   310元/100G;   995元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C6H12O3 = 132.16
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN104261
PubChem物质ID87567570
MDL编号MFCD00005359

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %(total of isomer)

物性(参考值)

沸点146 ℃
闪点35 ℃
比重1.03
折射率1.42
溶解性(可与之混溶)乙醇,丙酮,苯,乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号UN1993
类别3
包装类别 III
监管条件代码(*)
296831J&K2,5-Dimethoxytetrahydrofuran98%, 顺反异构体混合物306元/100G;   1001元/500G;   1817元/1KG;   展开

基本信息

分子式C6H12O3
分子量132.16
熔点-45
沸点145-148
闪点35
密度1.021
折光率(n20D)1.4160-1.4190
MDL编码MFCD00005359
Beilstein104261
EINECS 编号211-797-1
存储条件Flammables

安全信息

图形或危害标志
提示语Warning
危险说明H226
H315
H319
H335
防范说明P261
P280
P305+P351+P338
UN号码1993
危险分类3
包装等级III
WGK1
A11687Alfa Aesar2,5-Dimethoxytetrahydrofurancis + trans, 98%725元/100g;   2372元/500g;   展开

应用
2,5-Dimethoxytetrahydrofuran is a tetrahydrofuran derivative that finds application in proteomics research and in organic synthesis. It is also used as an intermediate for atropine sulfate, which is an anticholinergic drug. Further, it acts as a precursor of butanediol. In addition to this, it is used as a photographic hardener and as disinfectant in formulations.

备注
Incompatible with strong oxidizing agents and strong acids.

基本信息

MDL
MFCD00005359

EINECS
211-797-1

分子式
C6H12O3

分子量
132.16

熔点
-45°

沸点
145-147°

闪点
35°(95°F)

密度
1.020

折射率
1.4180

灵敏度
Air Sensitive. Light Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Miscible with methanol, diethyl ether and tetrahydrofuran. Immiscible with water.

Beilstein
104261

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-36/37/38
Flammable.Irritating to eyes, respiratory system and skin.

安全等级
7-26-33-37
Keep container tightly closed.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.

TSCA

C11567Alfa Aesar2,5-Dimethoxytetrahydrofuran99%, mixture of cis- and trans isomers605元/100g;   2037元/500g;   展开

基本信息

Ref#
11567

MDL
5359

分子式
C6 H12 O3

分子量
132.16

闪点
35

密度
1021

形态
Colourless liquid

安全信息

危险等级
3

包装组
III

8.02961Sigma-Aldrich2,5-Dimethoxytetrahydrofuran(mixture of cis- and trans isomers) for synthesis331.9元/25 ML;   376.47元/50 ML;   733.04元/250 ML;   展开

产品说明

分析说明

含量(GC, area%): ≥ 97.0 %(a/a)
密度(d 20 °C/ 4 °C):1.022 - 1.024
鉴定(IR):通过测试

基本信息

线性分子式(OCH3)2C4H6O
分子量132.16
MDL编号MFCD00005359
EC索引号211-797-1

产品性质

质量水平200
蒸汽压5 hPa ( 20 ℃)
测定≥97.0% (GC)
形式liquid
自燃温度>205 ℃
效能2040 mg/kg LD50, oral (Rat)
expl. lim.2.0-12.3 % (v/v)
pH值(酸碱度)5 (20 ℃, 300 g/L in H2O)
bp145-148 ℃/1.013 hPa
mp-45 ℃
转变温度flash point 35 ℃
溶解性 300 g/L
密度1.02 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C6H12O3/c1-7-5-3-4-6(8-2)9-5/h5-6H,3-4H2,1-2H3
InChI keyGFISDBXSWQMOND-UHFFFAOYSA-N

安全信息

象形图GHS02GHS06
警示用语:Danger
危险声明H226 - H315 - H331
预防措施声明P210 - P233 - P240 - P241 - P303 + P361 + P353 - P304 + P340 + P311
危险分类Acute Tox. 3 Inhalation - Flam. Liq. 3 - Skin Irrit. 2
储存分类代码3 - Flammable liquids
WGKWGK 1
闪点(F)100.4 °F - closed cup
闪点(C)38 ℃ - closed cup
381450Amethyst2,5-Dimethoxytetrahydrofuran98%, 用于合成58元/25G;   135元/100G;   488元/500G;   展开

基本信息

分子式C6H12O3
分子量132.16
熔点-45
沸点145-148
闪点35
密度1.021
折光率(n20D)1.4160-1.4190
MDL编码MFCD00005359
Beilstein104261
EINECS 编号211-797-1
存储条件Flammables

安全信息

图形或危害标志
提示语Warning
危险说明H226
H315
H319
H335
防范说明P261
P280
P305+P351+P338
UN号码1993
危险分类3
包装等级III
WGK1
133100Fluorochem2,5-Dimethoxytetrahydrofuran95%506元/25g;   836元/100g;   3322元/500g;   展开

基本信息

CAS Number696-59-3
MDL NumberMFCD00005359
Boiling Point145-147℃
Density1.03

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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