CAS 69550-28-3; 氯代三叔丁基磷化金(i); chlorotri-t-butylphosphinegold(i)

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CAS:

69550-28-3

分子式:

(C₄H₉)₃PAuCl

分子量:

434.74

熔点:

>300 °C

中文名称:

氯代三叔丁基磷化金(i)

英文名称:

chlorotri-t-butylphosphinegold(i)

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货号

品牌

产品名称

规格

包装、参考价格

详情

C805755

MACKLIN

氯代三叔丁基磷化金(I)

97%

559元/100mg; 981元/250mg; 2863元/1g;

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储存：室温
状态：白色到浅黄色粉末

79-0740

Strem

Chlorotri-t-butylphosphinegold(I)

99%

1665元/250mg; 4965元/1g;

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Technical Notes:

1.Catalyst used for cycloisomerization reactions of 2-(2-propynyl)pyridine N-oxides

2.Catalystused for the cycloisomerization of1.6-diynes.

3.Catalyst used for cycloisomerizations terminated by sp3C-H bond insertion.

4.Synthesis of aromatic ketones by a transition metal-catalyzed tandem sequence.

References: 1.Chem. Commun,, 2012, 48, 7622. 2.Angew. Chem., Int. Ed., 2011, 50, 2583. 3.J. Am. Chem. Soc., 2009, 131, 2809. 4. J. Am. Chem. Soc., 2006, 128, 7436. :

682705

Sigma-Aldrich

Chloro(tri-tert-butylphosphine)gold(I)

1086.29元/250 MG; 3058.01元/1 G;

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产品说明

应用

Gold Catalysts — 21st Century ′Gold Rush′

Useful catalyst in a variety of C-C bond forming reactions, including cyclopropanation.

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

线性分子式	(C₄H₉)₃PAuCl
分子量	434.74
MDL编号	MFCD09753040
PubChem化学物质编号	329760506

产品性质

质量水平	100
reaction suitability	core: gold reagent type: catalyst
mp	>300 ℃
SMILES string	Cl[Au].CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI	1S/C12H27P.Au.ClH/c1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-9H3;;1H/q;+1;/p-1
InChI key	JLXSZGSXDDQSJF-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Danger
危险声明	H301
预防措施声明	P301 + P310
危险分类	Acute Tox. 3 Oral
储存分类代码	6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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