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CAS: 693-98-1
分子式: C4H6N2
分子量: 82.10
沸点: 267-268℃
熔点: 142-145℃
中文名称: 
2-甲基-1H-咪唑
2-甲基咪唑
2-甲基-1,3-氮杂茂
2-甲基甘恶啉
英文名称: 
2-methyl-1H-Imidazole
2-Methylimidazole
2-Methylglyoxaline
2-methyl-imidazol
2-methyl-1h-imidazol
2-Methyl-1H-imidazole
1H-Imidazole,2-methyl-
Glyoxalethyline
p-Oxal-methyline
性质描述: 针状结晶体。熔点为136℃,沸点267℃。溶于水和醇,难溶于冷苯。
生产方法: 由2-甲基咪唑啉消除脱氢而得。将2-甲基咪唑啉加热熔融(熔点107℃),小心加入活性镍,升温至200-210℃反应2h。降温至150℃以下,加水溶解,趁热压滤,分离活性镍,将滤液浓缩至温度在140℃以上,放料冷却即得2-甲基咪唑。用该法生产纯度为≥98%的产品,1t产品消耗乙二胺(95%)1095kg、乙腈975kg。较好的方法是用乙二醛和醛作原料。
用途: 该品是药物灭滴灵和饲料促长剂二甲唑的中间体,也是环氧树脂及其他树脂的固化剂。作为环氧树脂的中温固经剂时,可以单独使用,但主要用作粉末成型和粉末涂装的固化促进剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M915172MACKLIN2-甲基咪唑98%, 粉末36元/25g;   74元/100g;   208元/500g;   765元/2.5kg;   2598元/10kg;   2465元/12X500g;   展开
储存:室温,密封
状态:白色到浅黄色粉末
M813135MACKLIN2-甲基咪唑98%30元/25g;   53元/100g;   118元/500g;   439元/2.5kg;   1426元/10kg;   2858元/25kg;   1389元/12X500g;   展开
储存:室温,密封
状态:白色到淡黄色/奶油色晶体
M0345TCI2-Methylimidazole>98.0%(GC)(T)160元/25G;   295元/100G;   660元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C4H6N2 = 82.11
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1368
PubChem物质ID87572415
SDBS (AIST Spectral DB)3587
MDL编号MFCD00005190

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point144.0 to 148.0 ℃
Solubility in Wateralmost transparency

物性(参考值)

熔点144 ℃
沸点268 ℃
闪点155 ℃
最大吸收波长211(CH3CN) nm
水溶性可溶
溶解性(可溶于)乙醇
溶解度(极微溶)

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H360 : 可能对生育能力或胎儿造成伤害。
H371 : 可能损害器官。
H373 : 长期或反复接触可能损害器官。
H341 : 怀疑可造成遗传性缺陷。
H351 : 怀疑致癌。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P308+P311 : 如接触到或有疑虑:呼叫急救中心/医生。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

相关法规

RTECS#NI7175000

运输信息

UN编号UN3263
类别8
包装类别 II
监管条件代码(*)
159278J&K2-Methylimidazole99%129元/100G;   513元/500G;   2025元/2.5KG;   展开

基本信息

分子式C4H6N2
分子量82.11
熔点142-143
沸点267-268
MDL编码MFCD00005190
EINECS 编号211-765-7

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
防范说明P280
P305+P351+P338
P310
UN号码3259
危险分类8
包装等级II
WGK2
RTECSNI7175000
A17063Alfa Aesar2-Methylimidazole97%289元/100g;   927元/500g;   6820元/2500g;   展开

应用
2-Methylimidazole is used as a raw material for the preparation of nitroimidazole antibiotics, which is useful in combat anaerobic bacterial and parasitic infections. It acts as a ligand in coordination chemistry. It is also employed as a hardener or accelerator for epoxy resin and auxiliary agent for textile dyes. Further, it acts as a catalyst for refolding of enhanced colored fluorescent protein. It is also useful as a building block in the synthesis of biologically active compounds. In addition to this, it is used as an active pharmaceutical ingredient intermediate such as metronidazole and dimetridazole.

备注
Incompatible with strong oxidizing agents, acids, acid chlorides and acid anhydrides.

基本信息

MDL
MFCD00005190

EINECS
211-765-7

分子式
C4H6N2

分子量
82.11

熔点
142-144°

沸点
267-268°

闪点
155°(311°F)

灵敏度
Ambient temperatures.

形态
Crystals

溶解性
Soluble in water and ethanol.

Beilstein
1368

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-34
Harmful if swallowed.Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
NI7175000

TSCA

C12700Alfa Aesar2-Methylimidazole99%408元/100g;   1241元/500g;   2438元/1kg;   展开

基本信息

Ref#
12700

MDL
5190

分子式
C4 H6 N2

分子量
82.1

闪点
155

形态
White cream crystals

安全信息

危险等级
8

包装组
III

Y0001320Ondansetron impurity FEuropean Pharmacopoeia (EP) Reference Standard1572.16元/ ;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

包装

Unit quantity: 10 mg. Subject to change. The product is delivered as supplied by the issuing Pharmacopoeia. For the current unit quantity, please visit the EDQM reference substance catalogue.

注意

Please find SDS provided by EDQM here..

其他说明

Sales restrictions may apply.

基本信息

经验(实验)分子式C4H6N2
分子量82.10
Beilstein1368
MDL编号MFCD00005190
PubChem化学物质编号329831364
NACRESNA.24

产品性质

等级pharmaceutical primary standard
蒸汽压<1 mmHg ( 0 ℃)
manufacturer/tradenameEDQM
bp267-268 ℃ (lit.)
mp142-143 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
储存温度2-8℃
SMILES stringCc1ncc[nH]1
InChI1S/C4H6N2/c1-4-5-2-3-6-4/h2-3H,1H3,(H,5,6)
InChI keyLXBGSDVWAMZHDD-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07GHS08
警示用语:Danger
危险声明H302 - H314 - H351 - H360Df
预防措施声明P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Repr. 1B - Skin Corr. 1C
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
M50850Sigma-Aldrich2-Methylimidazole99%497.05元/100 G;   2090.52元/500 G;   展开

产品说明

一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了能源效率。点击此处,查看更多详情。

包装

100, 500 g in poly bottle

基本信息

经验(实验)分子式C4H6N2
分子量82.10
Beilstein1368
EC 号211-765-7
MDL编号MFCD00005190
PubChem化学物质编号24896976
NACRESNA.22

产品性质

质量水平200
蒸汽压<1 mmHg ( 0 ℃)
测定99%
环保替代产品特性Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
bp267-268 ℃ (lit.)
mp142-143 ℃ (lit.)
环保替代产品分类Enabling
SMILES stringCc1ncc[nH]1
InChI1S/C4H6N2/c1-4-5-2-3-6-4/h2-3H,1H3,(H,5,6)
InChI keyLXBGSDVWAMZHDD-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07GHS08
警示用语:Danger
危险声明H302 - H314 - H351 - H360Df
预防措施声明P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Repr. 1B - Skin Corr. 1C
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
FAC-004NAccuStandard2-Methylimidazole232元/100mg;   展开
2-Methylimidazole2-甲基咪唑693-98-1
157400Fluorochem2-Methylimidazole98%462元/25g;   704元/100g;   1760元/500g;   展开

基本信息

CAS Number693-98-1
MDL NumberMFCD00005190
Boiling Point267℃
Melting Point142-148℃
Density1.096

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H351: Suspected of causing cancer ..
H360: May damage fertility or the unborn child ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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