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CAS: 693-23-2
分子式: C12H22O4
分子量: 230.30
沸点: 245℃(10
熔点: 125-130℃
中文名称: 
十二烷二酸
1,10-癸二酸
月桂二酸
十二碳二酸
十二双酸
十二碳二元酸
正十二烷二元酸
英文名称: 
1,10-decandicarboxylic acid
1,12-Dodecanoic acid
Decane-1,10-dicarboxylic acid
Dodecanedioic acid
1,10-decanedicarboxylic acid
1,10-dicarboxydecane
1,12-dodecanedioic acid
decamethylenedicarboxylic acid
性质描述: 白色粉末状或片状结晶。熔点128.7-129℃,沸点254℃(2.0kPa),245℃(1.33kPa),摩尔燃烧热6.740MJ/mol。在水中溶解度小,热稳定性好。
生产方法: 工业上可将丁二烯三聚得环十二碳三烯,再经加氢制成环十二烷,再用硝酸氧化经过环十二烷酮而得十二双酸。也可由环已烷为原料,在甲醇中与过氧化氢反应,制成烷氧基环已基过氧化物,再开环、二聚,生成十二双酸甲酯。再经皂化,即可制得十二双酸。实验室制备时,以环十二烷醇为原料,经硝酸氧化可得十二双酸。
用途: 该品与六次甲基二胺缩合,可制得工程塑料尼龙6-12;与辛醇、丁醇等醇类生成的二酯,可作为聚氯乙烯、硝酸纤维素、乙酸纤维素的增塑剂,与辛醇合成的二酯还用作喷气式发动机和燃气轮机用高级润滑油,或低温润滑脂的基础油料;十二双酸还可用作饱和聚酯的改性剂,金属的沉淀剂以及香料、特殊聚氨酯的原料。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807315MACKLIN十二烷二酸99%45元/100g;   149元/500g;   490元/2.5kg;   1566元/10kg;   展开
储存:室温
状态:白色到奶油色粉末或晶体
D792768MACKLIN十二烷二酸10mM in DMSO186元/1ml;   展开
储存:-20°C
状态:白色至奶油状粉末或晶体
D0013TCIDodecanedioic Acid>99.0%(GC)145元/25G;   560元/500G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C12H22O4 = 230.30
外观与形状(20℃)固体
Reaxys-RN1782580
PubChem物质ID87566767
SDBS (AIST Spectral DB)5866
MDL编号MFCD00002735

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 99.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point128.0 to 132.0 ℃
Solubility in hot Methanolalmost transparency

物性(参考值)

熔点129 ℃
水溶性实际上不溶
溶解性(可溶于)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#JR2370000
112352J&K1,10-Decanedicarboxylic Acid99%73元/25G;   153元/100G;   489元/500G;   展开

基本信息

分子式C12H22O4
分子量230.30
熔点127-129
沸点245
闪点220
MDL编码MFCD00002735
Beilstein1782580
EINECS 编号211-746-3

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGKnwg
RTECSJR2370000
TSCA
A10387Alfa AesarDodecanedioic Acid99%2093元/250g;   6531元/1000g;   展开

应用
Dodecanedioic acid is used as an intermediate for plasticizers, lubricants and adhesives. It is also used in antiseptics, top-grade coatings, painting materials, corrosion inhibitor and surfactant. It finds application in engineering plastics such as nylon 612.

备注
Incompatible with strong oxidizing agents and reducing agents.

基本信息

MDL
MFCD00002735

EINECS
211-746-3

分子式
HO2C(CH2)10CO2H

分子量
230.31

熔点
127-131°

沸点
244-245°/10mm

闪点
227°(440°F)

密度
1.150

灵敏度
Ambient temperatures.

形态
Powder or flakes

溶解性
Soluble in water, ethanol, hot methanol, hot toluene and hot acetic acid.

Beilstein
1782580

GHS危害和防范说明

GHS符号

Hazard Statements
H319
Causes serious eye irritation.

Precautionary Statements
P280i-P264-P305+P351+P338-P337+P313
Wear eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.If eye irritation persists: Get medical advice/attention.

安全信息

危险类别
36
Irritating to eyes.

安全等级
26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
JR2370000

TSCA

C11188Alfa Aesar1,10-Decanedicarboxylic Acid99%532元/5g;   806元/100g;   1774元/500g;   展开

基本信息

Ref#
11188

MDL
2735

分子式
C12 H22 O4

分子量
230.3

闪点
220

D1009Sigma-AldrichDodecanedioic Acid99%1021.54元/100 G;   1172.28元/500 G;   展开

产品说明

包装

100, 500 g in poly bottle

其他说明

斯克里普斯代谢组学和质谱技术中心独立生成的串联质谱数据可在PDF D1009.pdf 中查看或下载。斯克里普斯代谢物组学和质谱技术中心的METLIN代谢物数据库中有测试代谢物。要了解更多信息,请访问sigma.com/metlin。

基本信息

线性分子式HOOC(CH2)10COOH
分子量230.30
Beilstein1782580
EC 号211-746-3
MDL编号MFCD00002735
PubChem化学物质编号24893317
NACRESNA.22

产品性质

质量水平100
蒸汽压21 mmHg ( 222 ℃)
测定99%
bp245 ℃/10 mmHg (lit.)
mp127-129 ℃ (lit.)
溶解性H2O: slightly soluble 30 g/L at 23 ℃
SMILES stringOC(=O)CCCCCCCCCCC(O)=O
InChI1S/C12H22O4/c13-11(14)9-7-5-3-1-2-4-6-8-10-12(15)16/h1-10H2,(H,13,14)(H,15,16)
InChI keyTVIDDXQYHWJXFK-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKnwg
闪点(F)428.0 °F - closed cup
闪点(C)220 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
229150FluorochemDodecanedioic Acid95%220元/1g;   286元/25g;   990元/500g;   展开

基本信息

CAS Number693-23-2
MDL NumberMFCD00002735
Melting Point129℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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