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CAS: 6609-56-9
分子式: C8H7NO
分子量: 133.15
沸点: 135 °C12 mm Hg(lit.)
中文名称: 
邻甲氧基苄腈
邻氰基苯甲醚
2-甲氧基苄腈
邻甲氧基苯甲腈
2-甲氧基苯甲腈
邻甲氧基苯腈
英文名称: 
2-methoxybenzonitrile
o-Anisonitrile
1-Cyano-2-methoxybenzene
2-Cyanoanisole
性质描述: 无色液体。沸点140℃(2.4kPa),114℃(0.8kPa),熔点24.5℃,相对密度1.093,折光率1.5465。
生产方法: 将邻氨基苯甲醚用亚硝酸钠重氮化制成重氮盐溶液,加到氰化亚铅溶液中,再加苯。将混合物放置10-15h后进行水蒸气蒸馏,从馏出液中分出苯层,用氯化钙干燥后蒸除苯,剩余物减压蒸馏,收集120-122.5℃(1.2kPa馏分,得邻甲氧基苄腈,收率64.5-67.3%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
M814194MACKLIN2-甲氧基氰苯98%32元/5g;   105元/25g;   391元/100g;   1890元/500g;   5680元/2.5kg;   咨询
储存:室温
状态:无色到黄色液体或固体
折射率:n20/D 1.5465(lit.)
M1280TCI2-Methoxybenzonitrile>98.0%(GC)350元/5G;   690元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C8H7NO = 133.15
外观与形状(20℃)固体
Reaxys-RN2207134
PubChem物质ID87573237
SDBS (AIST Spectral DB)22702
MDL编号MFCD00001783

技术规格

AppearanceWhite to Almost white powder to lump
Purity(GC)min. 98.0 %

物性(参考值)

熔点25 ℃
沸点256 ℃
折射率1.55
水溶性微溶
溶解性(易溶于)乙醚,乙醇

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

运输信息

UN编号UN2811
类别6.1
包装类别 III
监管条件代码(*)
142354J&K2-Methoxybenzonitrile99%276元/5G;   1072元/25G;   咨询

基本信息

分子式C8H7NO
分子量133.15
沸点256
闪点113
密度1.093
折光率(n20D)1.5465
MDL编码MFCD00001783
Beilstein2207134
EINECS 编号229-559-0

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
UN号码3276
危险分类6.1
包装等级III
WGK3
TSCA
L01293Alfa Aesar2-Methoxybenzonitrile98%877元/5g;   2902元/25g;   8486元/100g;   咨询

基本信息

MDL
MFCD00001783

EINECS
229-559-0

分子式
C8H7NO

分子量
133.15

沸点
256°

闪点
>110°(230°F)

密度
1.093

折射率
1.5465

Beilstein
2207134

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-36/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

C43316Alfa Aesar2-Methoxybenzonitrile99%1013元/5g;   3339元/25g;   咨询

基本信息

Ref#
43316

MDL
1783

分子式
C8 H7 N O

分子量
133.15

闪点
113

安全信息

危险等级
6.1

包装组
III

033909Fluorochem2-Methoxybenzonitrile98%220元/1g;   242元/10g;   484元/25g;   1364元/100g;   咨询

基本信息

CAS Number6609-56-9
MDL NumberMFCD00001783
Boiling Point135℃
Melting Point24.5℃
Density1.093

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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