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CAS: 66-99-9
分子式: C11H8O
分子量: 156.18
沸点: 160℃(19
熔点: 58-62℃
中文名称: 
2-萘亚甲基醛
2-萘甲醛
英文名称: 
2-Formylanaphthalene
2-naphthaldehyde
2-formylnaphthalene
2-naphthalenecarboxaldehyde
beta-formylnaphthalene
beta-naphthaldehyde
beta-naphthylaldehyde
beta-naphthylcarboxaldehyde
naphthalene-2-carbaldehyde
2-Naphthaldehyd
性质描述: 白色片状结晶。熔点59℃,沸点160℃(1.53kPa)。溶于乙醇、乙醚,能随水蒸气蒸出。
生产方法: 将干燥氯化氢通入无水二氯化锡和无水乙醚的混合物,至饱和后加入2-萘腈的乙醚溶液,再通入氯化氢至饱和,生成黄色的醛亚胺和四氯化锡的络合物。将络合物用水蒸气蒸馏,从馏出液滤出白色固体产物,即为粗品2-萘甲醛,经减压蒸馏,得纯品,收率约70%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N814657MACKLIN2-萘甲醛98%30元/5g;   110元/25g;   408元/100g;   1983元/500g;   9399元/2.5kg;   展开
储存:2~8°C,密封
状态:灰白色到黄色或浅灰色固体
N0003TCI2-Naphthaldehyde>98.0%(GC)250元/5G;   890元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C11H8O = 156.18
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN507750
PubChem物质ID87573417
SDBS (AIST Spectral DB)6880
MDL编号MFCD00004094

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(GC)min. 98.0 %
Melting point60.0 to 64.0 ℃
Solubility in Methanolalmost transparency

物性(参考值)

熔点60 ℃
沸点147 ℃/11 mmHg

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。

相关法规

RTECS#QJ0190010
617687J&K2-Naphthaldehyde98%202元/5G;   615元/25G;   1843元/100G;   展开

基本信息

分子式C11H8O
分子量156.18
熔点58-61
MDL编码MFCD00004094
Beilstein507750
EINECS 编号200-640-2
存储条件Freezer -20℃

安全信息

WGK3
RTECSQJ0190010
TSCA
B25157Alfa Aesar2-Naphthaldehyde98%666元/5g;   2421元/25g;   6854元/100g;   展开

应用
2-Naphthaldehyde aids in stereo-selective formation of bicyclo 2-siloxy-2-alkoxyoxetanes. It is also used as catalytic agent and petrochemical additive.

备注
Store at -20°C. Air Sensitive. Store away from string bases and oxidizing agents.

基本信息

MDL
MFCD00004094

EINECS
200-640-2

分子式
C11H8O

分子量
156.18

熔点
59-62°

沸点
160°/19mm

灵敏度
Air Sensitive. Ambient temperatures.

形态
Powder

溶解性
Soluble in hot water.

Beilstein
507750

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
QJ0190010

TSCA

C12810Alfa Aesar2-Naphthaldehyde98%577元/5g;   2073元/25g;   6893元/100g;   展开

基本信息

Ref#
12810

MDL
4094

分子式
C11 H8 O

分子量
156.18

闪点
>100

安全信息

危险等级
9

包装组
III

N206Sigma-Aldrich2-Naphthaldehyde98%402.02元/5 G;   1086.29元/25 G;   3852.4元/100 G;   展开

产品说明

应用

2-萘甲醛可作为反应物用于:

  • 脯氨酸催化的羟醛反应。
  • 不对称三组分Mannich反应。
  • 合成Hantzsch 1,4-二氢吡啶。13}
  • 不对称安息香缩合反应。
  • 合成吡唑并[1,2−b]酞嗪二酮。
  • 通过快速真空热解合成C60

包装

5, 25, 100 g in glass bottle

基本信息

线性分子式C10H7CHO
分子量156.18
Beilstein507750
EC 号200-640-2
MDL编号MFCD00004094
PubChem化学物质编号24897548
NACRESNA.22

产品性质

质量水平200
测定98%
形式crystals
mp58-61 ℃ (lit.)
储存温度−20℃
SMILES string[H]C(=O)c1ccc2ccccc2c1
InChI1S/C11H8O/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-8H
InChI keyPJKVFARRVXDXAD-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
966704Amethyst2-Naphthaldehyde98%, 用于合成78元/5G;   197元/25G;   674元/100G;   展开

基本信息

分子式C11H8O
分子量156.18
熔点58-61
MDL编码MFCD00004094
Beilstein507750
EINECS 编号200-640-2
存储条件Freezer -20℃

安全信息

防范说明P260
P262
WGK3
RTECSQJ0190010
TSCA
209194Fluorochem2-Naphthaldehyde95%220元/1g;   264元/5g;   418元/10g;   814元/25g;   2728元/100g;   展开

基本信息

CAS Number66-99-9
MDL NumberMFCD00004094
Melting Point58-65℃
Density1.6211

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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