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CAS: 66-71-7
分子式: C12H8N2
分子量: 180.20
沸点: >330°C
熔点: 97 - 102 °C
中文名称: 
1,10-二氮杂菲
1,10-菲罗啉
1,10-菲咯啉
邻菲咯啉
1,10-菲咯啉(无水)
1,10-邻二氮杂菲(无水)
1,10-邻二氮杂菲
邻菲罗啉
英文名称: 
4,5-Phenanthroline
β-Phenanthroline
o-Phenanthrolin
1,10-Phenanthroline
o-Phenanthroline
1,10-fenanthrolin
1,10-o-phenanthroline
4,5-diazaphenanthrene
beta-phenanthroline
orthophenanthroline
1,10-Phenanthroline anhydrous
展开更多英文名
性质描述: 一水物为白色结晶性粉末。熔点93-94℃,无水物熔点为117℃,溶于300份水,70份苯,溶于醇和丙酮。
生产方法: 将邻苯二胺与甘油、硝基苯及浓硫酸一起加热,或改用8-氨基喹啉为原料,都可制备该品。
用途: 电镀添加剂,分析试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
O762230MACKLIN二氮杂菲溶液2.5g/L in H2O110元/100ml;   398元/500ml;   展开
储存:室温, 避光
物化性质:二氮杂菲溶液(2.5 g/L):称取 0.25 g 二氮杂菲加纯水 90 mL,加热并不断搅拌至溶解,冷却后加纯水至100 mL。
P816251MACKLIN1,10-菲罗啉,无水97%30元/5g;   61元/25g;   207元/100g;   809元/500g;   3650元/2.5kg;   展开
储存:室温, 干燥, 密封
状态:白色到米黄色到粉色粉末
P887808MACKLIN1,10-菲罗啉,无水Indicator,99%65元/5g;   258元/25g;   735元/100g;   1696元/500g;   展开
储存:室温, 干燥, 密封
状态:白色到米黄色到粉色粉末
P2099TCI1,10-Phenanthroline>98.0%(T)(HPLC)355元/5G;   960元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C12H8N2 = 180.21
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN126461
Merck Index (14)7214
MDL编号MFCD00011678

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 98.0 %
Melting point118.0 to 122.0 ℃
Watermax. 1.0 %

物性(参考值)

熔点120 ℃
最大吸收波长265(DMSO) nm

安全信息

图形或危害标志
信号词危险
危险性说明H301 : 吞咽会中毒。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P391 : 收集溢出物。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#SF8300000

运输信息

UN编号UN2811
类别6.1
包装类别 III
监管条件代码(*)
337793J&K1,10-Phenanthroline99%205元/5G;   521元/25G;   1582元/100G;   展开

基本信息

分子式C12H8N2
分子量180.21
熔点114-117
MDL编码MFCD00011678
Beilstein126461
Merck14,7214
EINECS 编号200-629-2

安全信息

图形或危害标志
提示语Danger
危险说明H301
H410
防范说明P273
P301+P310
UN号码2811
危险分类6.1
包装等级III
WGK3
RTECSSF8300000
TSCA
07-1650Strem1,10-Phenanthroline, anhydrous99%570元/5g;   2224元/25g;   6714元/100g;   展开
A13163Alfa Aesar1,10-Phenanthroline99%, may contain up to 1.5% water459元/5g;   1428元/25g;   4396元/100g;   展开

应用
1,10-Phenanthroline, anhydrous is used as a chelating agent, used as bidendate nitrogen ligands in Heck type reactions as an alternative to phospine ligands. It is widely used as an indicator for alkyllithium reagents and an inhibitor of metallopeptidase enzymes. It is also used in the analysis formulations in end-user industries like food, beverage and pharmaceuticals.

备注
Hygroscopic. Incompatible with strong oxidizing agents and strong acids. Store in a tightly closed container. Store in a cool, dry, well-ventilated area.

基本信息

MDL
MFCD00011678

EINECS
200-629-2

分子式
C12H8N2

分子量
180.21

熔点
116-119°

沸点
>330°

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in acetone and ethanol. Slightly soluble in water.

Beilstein
126461

Merck
14,7214

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H400-H410
Toxic if swallowed.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P264-P270-P301+P310a-P321-P405-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
25-50/53
Toxic if swallowed.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
45-60-61
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
SF8300000

TSCA

131377Sigma-Aldrich1,10-Phenanthroline≥99%291.08元/2.5 G;   560.75元/5 G;   1782.47元/25 G;   3872.65元/100 G;   展开

产品说明

应用

1,10-菲咯啉可用作:

  • 阴极缓冲层,以提高有机太阳能电池的效率。
  • 常规螯合剂,用于研究其在Fenton反应-鲁米诺化学发光系统中的功效。
  • 温和的铜(II)催化有机硼酸和亚磺酸盐的交叉偶联的配体,从而形成芳基和烯基砜。
  • 一种用于金属分光光测定和二氧化碳光催化还原的通用配体。
  • 金属大环化合物合成砌块。

包装

25, 100 g in poly bottle
2.5, 5 g in glass bottle

基本信息

经验(实验)分子式C12H8N2
分子量180.21
EC 号200-629-2
MDL编号MFCD00011678
eCl@ss39210124
PubChem化学物质编号24848008
NACRESNA.22

产品性质

质量水平200
测定≥99%
形式powder
mp114-117 ℃ (lit.)
SMILES stringc1cnc2c(c1)ccc3cccnc23
InChI1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H
InChI keyDGEZNRSVGBDHLK-UHFFFAOYSA-N
Gene Informationhuman ... FNTA(2339)

安全信息

象形图GHS06GHS09
警示用语:Danger
危险声明H301 - H410
预防措施声明P264 - P270 - P273 - P301 + P310 - P391 - P405
危险分类Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
8.41491Sigma-Aldrich1,10-Phenanthroline(anhydrous) for synthesis405.32元/5 G;   528.37元/25 G;   展开

产品说明

分析说明

Assay (HClO₄): ≥ 99.0 %
Melting range (lower value): ≥ 115 °C
Melting range (upper value): ≤ 119 °C
Identity (IR): passes test

基本信息

经验(实验)分子式C12H8N2
分子量180.21
MDL编号MFCD00011678
EC索引号200-629-2

产品性质

质量水平200
效能132 mg/kg LD50, oral (Rat)
mp117-119 ℃
溶解性 2.69 g/L
储存温度2-30℃
InChI1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H
InChI keyDGEZNRSVGBDHLK-UHFFFAOYSA-N

安全信息

象形图GHS06GHS09
警示用语:Danger
危险声明H301 - H410
预防措施声明P264 - P270 - P273 - P301 + P310 - P391 - P405
危险分类Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
906298Amethyst1,10-Phenanthroline99%, 用于合成57元/5G;   114元/25G;   383元/100G;   1530元/500G;   展开

基本信息

分子式C12H8N2
分子量180.21
熔点114-117
MDL编码MFCD00011678
Beilstein126461
Merck14,7214
EINECS 编号200-629-2

安全信息

图形或危害标志
提示语Danger
危险说明H301
H410
防范说明P273
P301+P310
UN号码2811
危险分类6.1
包装等级III
WGK3
RTECSSF8300000
TSCA
076839Fluorochem1,10-Phenanthroline98%220元/5g;   396元/25g;   1078元/100g;   展开

基本信息

CAS Number66-71-7
MDL NumberMFCD00150061
Boiling Point>330℃
Melting Point113-122℃

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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