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CAS: 66-27-3
分子式: C2H6O3S
分子量: 110.13
沸点: 202-203℃
熔点: 20 °C
中文名称: 
甲基磺酸甲酯
甲烷磺酸甲酯
英文名称: 
as-dimethyl sulfite
as-dimethyl sulphite
methanesulfonic acid methyl ester
methanesulfonic acid, methyl ester
Methanesulfonic acid,methyl ester
methanesulphonic acid methyl ester
methyl ester of methanesulfonic acid
methyl ester of methanesulphonic acid
methyl mesylate
methyl methylsulfonate
methyl methanesulfonate
methylmethanesulfonate
methyl methanesulfonic acid
methyl methanesulphonate
methyl methansulfonate
methyl methansulphonate
methylester kyseliny methansulfonove
methylmethane sulfonate
methylmethanesulphonate
methylmethansulfonat
methylmethansulfonat (german)
mms
nsc-50256
Methyl methyl sulfonate
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M838369MACKLIN甲基磺酸甲酯99%38元/1g;   56元/5g;   101元/25g;   379元/100g;   1599元/500g;   展开
储存:室温
状态:澄清无色到浅黄色液体
M742513MACKLIN甲基磺酸甲酯99.6%190元/1g;   展开
储存:室温
状态:液体
M0369TCIMethyl Methanesulfonate>98.0%(GC)1190元/25G;   2695元/100G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C2H6O3S = 110.13
外观与形状(20℃)液体
Reaxys-RN741856
PubChem物质ID87572435
SDBS (AIST Spectral DB)4248
Merck Index (14)6097
MDL编号MFCD00007557

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点59 ℃
闪点104 ℃
比重1.30
折射率1.41
溶解性(可溶于)二甲基甲酰胺,乙醚,醇

安全信息

图形或危害标志
信号词危险
危险性说明H301 : 吞咽会中毒。
H361 : 怀疑对生育能力或胎儿造成伤害。
H340 : 可能造成遗传性缺陷。
H350 : 可能致癌。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#PB2625000

运输信息

UN编号UN2810
类别6.1
包装类别 II
监管条件代码(*)
124678J&KMethyl Methanesulfonate99%121元/5G;   396元/25G;   1423元/100G;   展开

基本信息

分子式C2H6O3S
分子量110.13
沸点202-203
闪点104
密度1.3
折光率(n20D)1.4110 - 1.4150
MDL编码MFCD00007557
Beilstein1098586
EINECS 编号200-625-0

安全信息

图形或危害标志
提示语Danger
危险说明H301
H315
H319
H335
H350
防范说明P201
P261
P301+P310
P305+P351+P338
P308+P313
UN号码2810
危险分类6.1
包装等级III
WGK3
RTECSPB2625000
TSCA
957448J&KMethyl Methanesulfonate98.5%75元/100MG;   300元/500MG;   展开

基本信息

分子式C2H6O3S
分子量110.13
沸点202-203
闪点104
密度1.3
折光率(n20D)1.4110 - 1.4150
MDL编码MFCD00007557
Beilstein1098586
EINECS 编号200-625-0

安全信息

图形或危害标志
提示语Danger
危险说明H301
H315
H319
H335
H350
防范说明P201
P261
P301+P310
P305+P351+P338
P308+P313
UN号码2810
危险分类6.1
包装等级III
WGK3
RTECSPB2625000
TSCA
H55120Alfa AesarMethyl Methanesulfonate99%720元/5g;   3822元/25g;   15514元/100g;   展开

应用
Methyl methanesulfonate is a DNA adduct that adds methyl groups to Dan at 7-guanine, 3-guanine and 3-adenine.

备注
Store at room temperature with proper ventilation. Keep away from oxidizing agents.

基本信息

MDL
MFCD00007557

EINECS
200-625-0

分子式
C2H6O3S

分子量
110.13

沸点
202-203°

闪点
104°(219°F)

密度
1.3

折射率
1.4140

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Very soluble in water.

Beilstein
1098586

Merck
14,6097

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H341-H350-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.Suspected of causing genetic defects.May cause cancer.May cause respiratory irritation.

Precautionary Statements
P201-P261-P301+P310a-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Avoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
45-22-36/37/38-68
May cause cancer.Harmful if swallowed.Irritating to eyes, respiratory system and skin.Possible risk of irreversible effects.

安全等级
53-20-23-26-36/37/39-45-60
Avoid exposure - obtain special instructions before use.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

RTECS
PB2625000

TSCA

C15689Alfa AesarMethyl Methanesulfonate99%734元/5g;   3130元/25g;   8287元/100g;   展开

基本信息

Ref#
15689

MDL
7557

分子式
C2 H6 O3 S

分子量
110.13

闪点
104

密度
1.3

形态
Colorless to pale yellow liquid

安全信息

危险等级
6.1

包装组
III

129925Sigma-AldrichMethyl Methanesulfonate99%772.56元/5 G;   2056.31元/25 G;   3450.2元/100 G;   展开

产品说明

包装

5, 25, 100 g in glass bottle

原理

DNA 加合物;优先地将甲基加合到 DNA 的 7-鸟嘌呤,也可加合到 3-腺嘌呤和 3-鸟嘌呤。

基本信息

线性分子式CH3SO3CH3
分子量110.13
Beilstein1098586
EC 号200-625-0
MDL编号MFCD00007557
PubChem化学物质编号24847934
NACRESNA.22

产品性质

质量水平100
测定99%
形式liquid
折射率n20/D 1.414 (lit.)
bp202-203 ℃ (lit.)
密度1.3 g/mL at 25 ℃ (lit.)
SMILES stringCOS(C)(=O)=O
InChI1S/C2H6O3S/c1-5-6(2,3)4/h1-2H3
InChI keyMBABOKRGFJTBAE-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08GHS09
警示用语:Danger
危险声明H301 - H315 - H319 - H334 - H340 - H351 - H361fd - H373 - H411
预防措施声明P201 - P273 - P301 + P310 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Muta. 1B - Repr. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT RE 2 Inhalation
靶器官Lungs
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)219.2 °F - closed cup
闪点(C)104 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
78697SupelcoMethyl Methanesulfonatecertified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland1754.27元/120 mg;   展开

产品说明

一般描述

该认证标准物质(CRM)根据ISO/IEC 17025ISO 17034进行生产和认证。该CRM可追溯到来自NMI的原材料,如 NIST或NMIJ。
证书上给出了定量核磁共振法认证的内容,包括不确定性和失效日期。
请访问http://www.sigma-aldrich.com下载您的证书。
该认证标准物质(CRM)根据ISO/IEC 17025和ISO 17034进行生产和认证。该CRM可追溯来自NMI的原始材料,如NIST或NMIJ。NMR定量信息已包括在认证内容中。证书上已给出不确定性和失效日期。请在http://www.sigma-aldrich.com下载您的证书。

甲磺酸甲酯属于烷基磺酸酯类,是潜在的基因毒性杂质 (GTI)。

应用

甲磺酸甲酯可用作认证标准物质,用于通过气相色谱-三重四级杆质谱联用法定量检测药物制剂中的分析物。
有关合适仪器技术的更多信息,请参考产品分析证书。如需进一步支持,请联系技术服务。

包装

无底玻璃瓶。内含物在插入的融合锥体内。

原理

DNA 加合物;优先地将甲基加合到 DNA 的 7-鸟嘌呤,也可加合到 3-腺嘌呤和 3-鸟嘌呤。

法律信息

TraceCERT is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式CH3SO3CH3
分子量110.13
Beilstein1098586
EC 号200-625-0
MDL编号MFCD00007557
PubChem化学物质编号329768176
NACRESNA.24

产品性质

质量水平300
等级certified reference material
TraceCERT®
产品线TraceCERT®
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
折射率n20/D 1.414 (lit.)
bp202-203 ℃ (lit.)
密度1.3 g/mL at 25 ℃ (lit.)
application(s)environmental
pharmaceutical
格式neat
储存温度2-8℃
SMILES stringCOS(C)(=O)=O
InChI1S/C2H6O3S/c1-5-6(2,3)4/h1-2H3
InChI keyMBABOKRGFJTBAE-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08GHS09
警示用语:Danger
危险声明H301 - H315 - H319 - H334 - H340 - H351 - H361fd - H373 - H411
预防措施声明P202 - P260 - P273 - P301 + P310 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Muta. 1B - Repr. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT RE 2 Inhalation
靶器官Lungs
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)219.2 °F - closed cup
闪点(C)104 ℃ - closed cup
912927AmethystMethyl Methanesulfonate99%, 用于合成114元/5G;   383元/25G;   1356元/100G;   展开

基本信息

分子式C2H6O3S
分子量110.13
沸点202-203
闪点104
密度1.3
折光率(n20D)1.4110 - 1.4150
MDL编码MFCD00007557
Beilstein1098586
EINECS 编号200-625-0

安全信息

图形或危害标志
提示语Danger
危险说明H301
H315
H319
H335
H350
防范说明P201
P261
P301+P310
P305+P351+P338
P308+P313
UN号码2810
危险分类6.1
包装等级III
WGK3
RTECSPB2625000
TSCA
APP-9-132AccuStandardMethyl methanesulfonate ,100 μg/mL in Dichloromethane100 μg/mL in Dichloromethane309元/1mL;   展开
Methyl methanesulfonate甲基磺酸甲酯66-27-3100 µg/mL
AS-E0431AccuStandardMethyl methanesulfonate (95-98%) ,1000 μg/mL in Acetonitrile1000 μg/mL in Acetonitrile494元/1mL;   展开
Methyl methanesulfonate甲基磺酸甲酯66-27-31 mg/mL
241054FluorochemMethyl Methanesulfonate99%264元/1g;   484元/5g;   1320元/25g;   3080元/100g;   展开

基本信息

CAS Number66-27-3
MDL NumberMFCD00007557
Boiling Point59℃
Density1.3

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H340: May cause genetic defects ..
H350: May cause cancer ..
H361fd: Reproductive toxicity
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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