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CAS: 6553-96-4
分子式: C15H23ClO2S
分子量: 302.86
熔点: 92-94 °C(lit.)
中文名称: 
2,4,6-三异丙基苯磺酰氯
英文名称: 
TPSCl
2,4,6-Triisopropylbenzenesulfonyl chloride
Trisyl chloride
推荐供应商
货号品牌产品名称规格包装、参考价格
T819373MACKLIN2,4,6-三异丙基苯磺酰氯97%24元/5g;   91元/25g;   361元/100g;   咨询
储存:室温,干燥
状态:白色到灰白色粉末,晶体和/或块状
T0459TCI2,4,6-Triisopropylbenzenesulfonyl Chloride>97.0%(T)605元/25G;   1690元/100G;   5490元/500G;   咨询

基本信息

纯度/分析方法>97.0%(T)
分子式/分子量C15H23ClO2S = 302.86
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (分解),加热
Reaxys-RN1218575
PubChem物质ID87576405
SDBS (AIST Spectral DB)10893
MDL编号MFCD00007433

技术规格

AppearanceWhite powder to lump
Purity(GC)min. 95.0 %
Purity(Argentometric Titration)min. 97.0 %
Melting point94.0 to 99.0 ℃
Solubility in Toluenealmost transparency

物性(参考值)

熔点96 ℃
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3261
类别8
包装类别 III
监管条件代码(*)
290099J&K2,4,6-Triisopropylbenzenesulfonyl Chloride98%109元/5G;   437元/25G;   1436元/100G;   咨询

基本信息

分子式C15H23ClO2S
分子量302.86
熔点92-94
MDL编码MFCD00007433
Beilstein1218575
EINECS 编号229-479-6

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
TSCA
A11458Alfa Aesar2,4,6-Triisopropylbenzenesulfonyl Chloride98%1330元/25g;   4514元/100g;   20370元/500g;   咨询

应用
2,4,6-Triisopropylbenzenesulfonyl chloride is used for the synthesis of glycerophospholipids as a condensing agent and in the analysis of phosphonolipids in egg yolk by HPLC/MS technique. It acts as a coupling reagent for the synthesis of oligonucleotides and as sulfonates of pyrimidine nucleosides. It also serves as a condensing agent in the synthesis of hydrogen-phosphonate diesters.

备注
Incompatible with strong bases.

基本信息

MDL
MFCD00007433

EINECS
229-479-6

分子式
C15H23ClO2S

分子量
302.87

熔点
94-97°

灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in chloroform.

Beilstein
1218575

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C15279Alfa Aesar2,4,6-Triisopropylbenzenesulfonyl Chloride97%1264元/25g;   3799元/100g;   咨询

基本信息

Ref#
15279

MDL
7433

分子式
C15 H23 Cl O2 S

分子量
302.85

形态
White to pale cream cryst powder

安全信息

危险等级
8

包装组
II

119490Sigma-Aldrich2,4,6-Triisopropylbenzenesulfonyl Chloride97%466.77元/25 G;   1579.39元/100 G;   咨询

产品说明

应用

2,4,6-三异丙基苯磺酰氯可用于通过 HPLC/MS 技术分析蛋黄中的磷脂。
它也可用于合成:

  • 具有柔性连接基2,2′-(乙二氧)双(乙胺)的二聚新霉素-新霉素偶联物。
  • 寡核苷酸合成用偶联试剂
  • 嘧啶核苷的磺酸盐这些磺酸盐可以在钯催化剂存在的情况下被亲核试剂取代。

包装

25, 100 g in glass bottle

基本信息

线性分子式[(CH3)2CH]3C6H2SO2Cl
分子量302.86
Beilstein1218575
EC 号229-479-6
MDL编号MFCD00007433
PubChem化学物质编号24847399
NACRESNA.22

产品性质

质量水平200
测定97%
mp92-94 ℃ (lit.)
溶解性ethanol: soluble 5%, clear, colorless to light yellow
SMILES stringCC(C)c1cc(C(C)C)c(c(c1)C(C)C)S(Cl)(=O)=O
InChI1S/C15H23ClO2S/c1-9(2)12-7-13(10(3)4)15(19(16,17)18)14(8-12)11(5)6/h7-11H,1-6H3
InChI keyJAPYIBBSTJFDAK-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P280 - P305 + P351 + P338 - P310
危险分类Skin Corr. 1B
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
296373Amethyst2,4,6-Triisopropylbenzenesulfonyl Chloride98%, 用于合成64元/5G;   208元/25G;   677元/100G;   咨询

基本信息

分子式C15H23ClO2S
分子量302.86
熔点92-94
MDL编码MFCD00007433
Beilstein1218575
EINECS 编号229-479-6

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
TSCA
003615Fluorochem2,4,6-Triisopropylbenzenesulfonyl Chloride97%308元/25g;   858元/100g;   咨询

基本信息

CAS Number6553-96-4
MDL NumberMFCD00007433
Melting Point93-99℃
Density1.096

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations..
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