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CAS: 651-83-2
分子式: C7H2F7N
分子量: 233.09
沸点: 186℃
中文名称: 
4-氨基六氟甲苯
4-氨基-2,3,5,6-四氟三氟甲苯
英文名称: 
4-amino-heptafluorotoluene
4-amino-2,3,5,6-tetrafluorobenzotrifluoride
2,3,5,6-Tetrafluoro-4-(trifluoromethyl)aniline
2,3,5,6,α,α,α-Heptafluoro-p-toluidine
2,3,5,6-Tetrafluoro-4-aminobenzotrifluoride
4-Aminoheptafluorotoluene
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T858197MACKLIN4-氨基七氟甲苯95%66元/250mg;   139元/1g;   展开
储存:室温,干燥,惰性气体存储
状态:无色到浅黄色到黄色到浅橙色到棕色澄清液体
T1529TCI2,3,5,6-Tetrafluoro-4-aminobenzotrifluoride>97.0%(GC)465元/1G;   1150元/5G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C7H2F7N = 233.09
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN2657893
PubChem物质ID87577288
SDBS (AIST Spectral DB)19559
MDL编号MFCD00091518

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点186 ℃
闪点87 ℃
比重1.68
折射率1.43

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。
B24326Alfa Aesar2,3,5,6-Tetrafluoro-4-(trifluoromethyl)aniline98%1025元/1g;   4023元/5g;   展开

基本信息

MDL
MFCD00091518

分子式
C7H2F7N

分子量
233.09

沸点
185-187°

折射率
1.4300

形态
Liquid

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
23-26-37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

791806Sigma-AldrichYu-Wasa Auxiliary97%1674.78元/10 G;   展开

产品说明

包装

1, 10 g in poly bottle

其他说明

Acidic amides are superior directing groups for promoting C-H activation reactions with both Pd(0)/PR3 and Pd(II) catalysts.

Used in the Preparation of

  • Lactams via palladium-catalyzed olefination of arylamides with benzylacrylate, followed by 1,4-conjugate addition
  • N-(fluorinated aryl)benzamides as substrates for regioselective C-H amination reactions with O-benzoylhydroxylamines
  • Substituted succinimides via palladium-catalyzed carbonylation of N-aryl amides
  • N-aryl cyclopropanecarboxamide substrates and various amino acid ligands for palladium-catalyzed C-H activation of cyclopropanes

基本信息

线性分子式CF3C6F4NH2
分子量233.09
Beilstein2657893
MDL编号MFCD00091518
PubChem化学物质编号329768293
NACRESNA.22

产品性质

质量水平100
测定97%
形式liquid
reaction suitabilityreagent type: catalyst
reaction type: C-H Activation
折射率n20/D 1.431 (lit.)
n20/D 1.432
bp186 ℃ (lit.)
密度1.662 g/mL at 25 ℃
1.687 g/mL at 25 ℃ (lit.)
SMILES stringNc1c(F)c(F)c(c(F)c1F)C(F)(F)F
InChI1S/C7H2F7N/c8-2-1(7(12,13)14)3(9)5(11)6(15)4(2)10/h15H2
InChI keyFJOACTZFMHZHSC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
008618Fluorochem2,3,5,6-Tetrafluoro-4-aminobenzotrifluoride98%660元/1g;   1892元/5g;   5786元/25g;   展开

基本信息

CAS Number651-83-2
MDL NumberMFCD00091518
Density1.68

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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