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CAS: 6485-40-1
分子式: C10H14O
分子量: 150.22
沸点: 228-230 °C(lit.)
中文名称: 
(R)-2-甲基-5-(1-甲基乙烯基)-2-环己烯-1-酮
(R)-(-)-2-甲基-5-(1-甲基乙烯基)-2-环己烯-1-酮/L-香芹酮/左旋香芹酮
(R)-(-)-2-甲基-5-(1-甲基乙烯基)-2-环己烯-2-酮/L-香芹酮/左旋香芹酮
(-)-香芹酮
(R)-(-)-香芹酮
(R)-5-异丙烯基-2-甲基-2-环己烯酮
英文名称: 
2-methyl-5-(1-methylethenyl)-, (R)-2-Cyclohexen-1-one
(R)-(-)-p-mentha-8-dien-2-one
(-)-carvone
(R)-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-one
(R)-carvone
(R)-2-cyclohexen-1-on
l(-)-carvone
l-1-methyl-4-isopropenyl-6-cyclohexen-2-one
(R)-5-Isopropenyl-2-methyl-2-cyclohexenone
l-6,8(9)-p-menthadien-2-one
(R)-(-)-Carvone
l-carvone
R-(-)-5-Isopropenyl-2-methyl-2-cyclohexenone
(-)-p-mentha-8-dien-2-one
(R)-(-)-p-Mentha-6,8-dien-2-one
(R)-p-mentha-6,8-dien-2-one
2-Cyclohexen-1-one,2-methyl-5-(1-methylethenyl)-,(R)-
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格详情
L805683MACKLIN左旋香芹酮99%30元/5g;   62元/25g;   102元/100g;   366元/500g;   1520元/2.5kg;   展开
储存:室温
状态:无色到淡黄色液体
折射率:n20/D 1.498
C0703TCI(R)-(-)-Carvone>99.0%(GC)185元/25ML;   410元/100ML;   1315元/500ML;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C10H14O = 150.22
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN2206714
PubChem物质ID87565788
SDBS (AIST Spectral DB)2349
Merck Index (14)1874
MDL编号MFCD00001578

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 99.0 %
Specific rotation-59.0 to -63.0 deg(neat)

物性(参考值)

沸点231 ℃
闪点88 ℃
比重0.96
比旋光度 [α]D-61.5° (neat)
折射率1.50

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#OS8650000
403444J&KL-(-)-Carvone97%139元/25G;   250元/100G;   875元/500G;   2764元/2.5KG;   展开

基本信息

分子式C10H14O
分子量150.22
沸点227-230
闪点94
密度0.959
折光率(n20D)1.4970
比旋光度([α]20D)-63.5 to -59.5 (neat)
MDL编码MFCD00001578
Beilstein2206714
EINECS 编号229-352-5

安全信息

图形或危害标志
提示语Warning
危险说明H302
防范说明P262
WGK2
RTECSOS8650000
TSCA
A13900Alfa Aesar(R)-(-)-Carvone98%567元/50g;   2308元/250g;   4608元/1000g;   展开

应用
(R)-(-)-Carvone is used in the flavor and food industry such as chewing gum additives. It is used in air freshening products such as in essential oils as well as in aromatherapy and alternative medicine. It is used to prepare carvomenthol, carvomenthone, dihydrocarvone, carveol and limonene. It reacts with lithium dimethylcuprate to place a methyl group trans to the isopropenyl group with good stereoselectivity. It is also used as a mosquito repellent and prevent premature sprouting of potatoes. Further, it is employed as an important starting material for the synthesis of enantiopure (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1 and (4S,6R,7R)-trihydroxy-1-octyne derivatives. It is utilized as a vital raw material for the asymmetric total synthesis of natural products. In addition to this, it is used as a chiral starting material.

备注
Store in a cool place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00001578

EINECS
229-352-5

分子式
C10H14O

分子量
150.22

沸点
228-230°

闪点
93°(199°F)

密度
0.959

折射率
1.4990

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with alcohol, ether, chloroform, propylene glycol and mineral oils. Immiscible with water and glycerol.

Beilstein
2206714

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302
Combustible liquid.Harmful if swallowed.

Precautionary Statements
P280f
Wear protective clothing.

安全信息

危险类别
22
Harmful if swallowed.

安全等级
36
Wear suitable protective clothing.

欧盟危险品标志

RTECS
OS8650000

TSCA

C15459Alfa AesarL(-)-Carvone99%516元/5g;   834元/100g;   2223元/500g;   展开

基本信息

Ref#
15459

MDL
1578

分子式
C10 H14 O

分子量
150.22

闪点
88

密度
0.958

形态
Colorless liquid

W224901Sigma-AldrichL-Carvone≥97%, FCC, FG404.65元/;   801.49元/1 KG;   2902.51元/5 KG;   展开

基本信息

经验(实验)分子式C10H14O
分子量150.22
FEMA编号2249
Beilstein2206714
EC 号229-352-5
MDL编号MFCD00001578
PubChem化学物质编号24900948
Flavis编号7.147
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
agencyfollows IFRA guidelines
meets purity specifications of JECFA
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 178/2002
FCC
FDA 21 CFR 117
蒸汽密度5.2 (vs air)
蒸汽压0.4 mmHg ( 20 ℃)
测定≥97%
旋光性[α]20/D −61°, neat
组成contains IFRA restricted Carvone
折射率n20/D 1.497 (lit.)
bp227-230 ℃ (lit.)
密度0.959 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查herbaceous; spearmint
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物carvone
SMILES stringCC(=C)[C@@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1
InChI keyULDHMXUKGWMISQ-SECBINFHSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P261 - P264 - P270 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)192.2 °F - closed cup
闪点(C)89 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
W224908Sigma-AldrichL-Carvonenatural, 99%, FG433.21元/;   658.1元/100 G;   3757.23元/1 KG;   展开

产品说明

一般描述

L-Carvone is one of the key constituents of spearmint (Mentha spicata) oil. Studies indicate that it is a potent feeding-deterrent to stored product beetles.

包装

1 kg in poly bottle
100, 500 g in poly bottle

基本信息

经验(实验)分子式C10H14O
分子量150.22
FEMA编号2249
Beilstein2206714
EC 号229-352-5
欧洲委员会编号146
MDL编号MFCD00001578
PubChem化学物质编号329830468
Flavis编号7.012
NACRESNA.21

产品性质

质量水平400
等级FG
Halal
Kosher
natural
agencyfollows IFRA guidelines
meets purity specifications of JECFA
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 178/2002
FDA 21 CFR 117
蒸汽密度5.2 (vs air)
蒸汽压0.4 mmHg ( 20 ℃)
测定99%
组成contains IFRA restricted carvone
折射率n20/D 1.497 (lit.)
bp227-230 ℃ (lit.)
密度0.959 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查herbaceous; spearmint
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物carvone
SMILES stringCC(=C)[C@@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1
InChI keyULDHMXUKGWMISQ-SECBINFHSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P261 - P264 - P270 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)192.2 °F - closed cup
闪点(C)89 ℃ - closed cup
124931Sigma-Aldrich(R)-(-)-Carvone98%265.99元/5 ML;   560.93元/100 ML;   1499.82元/500 ML;   展开

产品说明

一般描述

(R)-(−)-香芹酮是一种单萜类化合物。其在气相中的臭氧分解反应已有报道。醛(甲醛)和双自由基为主要产物。它可参与非手性八唑酮的非对映选择性合成。

应用

(R)-(−)-香芹酮可用作合成对映纯(R)-(+)-3-甲基-6-异丙烯基-环庚-3-烯酮-1(一种在萜类化合物合成过程中形成的有用中间体)的起始试剂。它可以用作合成不同保护的(4S,6R,7R)-三羟基-1-辛炔衍生物的起始试剂。
手性原料。

包装

5 mL in glass bottle
100, 500 mL in poly bottle

基本信息

经验(实验)分子式C10H14O
分子量150.22
Beilstein2206714
EC 号229-352-5
MDL编号MFCD00001578
PubChem化学物质编号24847635
NACRESNA.22

产品性质

质量水平100
蒸汽密度5.2 (vs air)
蒸汽压0.4 mmHg ( 20 ℃)
测定98%
形式liquid
旋光性[α]20/D −61°, neat
折射率n20/D 1.497 (lit.)
bp227-230 ℃ (lit.)
密度0.959 g/mL at 25 ℃ (lit.)
SMILES stringCC(=C)[C@@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1
InChI keyULDHMXUKGWMISQ-SECBINFHSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P261 - P264 - P270 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)192.2 °F - closed cup
闪点(C)89 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
22060Supelco(-)-Carvoneanalytical standard618.28元/5 ML;   展开

产品说明

一般描述

(-)-Carvone, a monoterpene ketone which is the main active component of mentha plant species like Mentha spicata. It has antinociceptive activity which is found to be associated with decreased peripheral nerve excitability.

应用

It has been used as reference standard in TLC analysis to detect the presence of ketonic monoterpene in Aloysia species.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

基本信息

经验(实验)分子式C10H14O
分子量150.22
Beilstein2206714
EC 号229-352-5
MDL编号MFCD00001578
PubChem化学物质编号329752242
NACRESNA.24

产品性质

质量水平100
等级analytical standard
测定≥99.0% (sum of enantiomers, GC)
旋光性[α]20/D −61.5±2°, neat
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
折射率n20/D 1.498
bp228-230 ℃ (lit.)
密度0.960 g/mL at 20 ℃ (lit.)
application(s)agriculture
cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care
格式neat
SMILES stringCC(=C)[C@@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1
InChI keyULDHMXUKGWMISQ-SECBINFHSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P261 - P264 - P270 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)192.2 °F - closed cup
闪点(C)89 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
00290595(-)-Carvoneprimary reference standard3285.75元/100 MG;   展开

产品说明

一般描述

Produced and qualified by HWI pharma services GmbH.
Exact content by quantitative NMR can be found on the certificate.

应用

Reference Standard in the analysis of herbal medicinal products

基本信息

经验(实验)分子式C10H14O
分子量150.22
Beilstein2206714
EC 号229-352-5
MDL编号MFCD00001578
PubChem化学物质编号329747032
NACRESNA.24

产品性质

等级primary reference standard
保质期limited shelf life, expiry date on the label
manufacturer/tradenameHWI
bp228-230 ℃ (lit.)
密度0.960 g/mL at 20 ℃ (lit.)
SMILES stringCC(=C)[C@@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1
InChI keyULDHMXUKGWMISQ-SECBINFHSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P261 - P264 - P270 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)192.2 °F - closed cup
闪点(C)89 ℃ - closed cup
PHL80099(-)-Carvonephyproof® Reference Substance3048.57元/100 MG;   展开

产品说明

一般描述

This substance is a primary reference substance with assigned absolute purity (considering chromatographic purity, water, residual solvents, inorganic impurities). The exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG

法律信息

phyproof is a registered trademark of PhytoLab GmbH & Co. KG

基本信息

经验(实验)分子式C10H14O
分子量150.22
Beilstein2206714
MDL编号MFCD00001578

产品性质

等级primary reference standard
产品线phyproof® Reference Substance
测定≥95.0% (GC)
形式liquid
manufacturer/tradenamePhytoLab
bp228-230 ℃ (lit.)
密度0.960 g/mL at 20 ℃ (lit.)
储存温度2-8℃
SMILES stringCC(=C)[C@@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1
InChI keyULDHMXUKGWMISQ-SECBINFHSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P261 - P264 - P270 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)192.2 °F - closed cup
闪点(C)89 ℃ - closed cup
240922Fluorochem(R)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone95%220元/25g;   506元/100g;   2332元/500ml;   展开

基本信息

CAS Number6485-40-1
MDL NumberMFCD00001578
Boiling Point231℃
Melting Point9.86℃
Density0.959

安全信息

图形或危害标志
危险性说明 H317: May cause an allergic skin reaction.
防范说明 P261: Avoid breathing .
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see . on this label).
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to local regulations..
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