CAS 645-45-4; 3-苯丙基; hydrocinnamoyl chloride

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货号

品牌

产品名称

规格

包装、参考价格

P742720

MACKLIN

3-苯基丙酰氯

Standard for GC, ≥99.8%(GC)

128元/1g;

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储存：室温, 密封, 干燥
状态：液体

P815469

MACKLIN

3-苯基丙酰氯

98%

30元/5g; 50元/25g; 189元/100g; 935元/500g;

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储存：室温,干燥,密封
状态：无色到浅黄色液体
折射率：n20/D 1.5265(lit.)

H0696

TCI

3-Phenylpropionyl Chloride

>97.0%(GC)(T)

290元/25G;

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基本信息

纯度/分析方法	>97.0%(GC)(T)
分子式/分子量	C₉H₉ClO = 168.62
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
Reaxys-RN	742586
PubChem物质ID	87571065
SDBS (AIST Spectral DB)	22634
MDL编号	MFCD00000748

技术规格

Appearance	Colorless to Light yellow to Light orange clear liquid
Purity(GC)	min. 97.0 %
Purity(Argentometric Titration)	min. 97.0 %

物性(参考值)

沸点	225 ℃
闪点	108 ℃
比重	1.14
折射率	1.53

安全信息

图形或危害标志
信号词	危险
危险性说明	H332 : 吸入有害。 H314 : 造成严重皮肤灼伤和眼损伤。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P234 : 只能在原容器中存放。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P390 : 吸收溢出物，防止材料损坏。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

相关法规

RTECS#

MW5652395

运输信息

UN编号	UN3265
类别	8
包装类别	III
监管条件代码(*)

393594

J&K

3-Phenylpropionyl Chloride

98%

164元/5G; 536元/25G; 1763元/100G;

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基本信息

分子式	C₉H₉ClO
分子量	168.62
熔点	-7 - -5
沸点	107
闪点	108
密度	1.135
折光率(n20D)	1.5260 - 1.5280
MDL编码	MFCD00000748
Beilstein	742586
EINECS 编号	211-443-6

安全信息

图形或危害标志
提示语	Danger
危险说明	H314 H331
防范说明	P261 P280 P305+P351+P338
UN号码	3265
危险分类	8
包装等级	II
WGK	3
RTECS	MW5652395
TSCA	是

A10860

Alfa Aesar

3-Phenylpropionyl Chloride

98%

838元/10g; 2927元/50g; 16531元/250g;

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应用
The 3-phenylpropionate (dihydrocinnamoyl) ester has been used as a protecting group in nucleoside synthesis. Used in the synthesis of 1-Phenyl-3-methyl-4-acyl-5- pyrazolones. N-(3-phenyl-n-propyl)-1-phenyl-2-aminopropane were prepared by acylation of the appropriate amine with 3-phenylpropionyl chloride followed by reduction of the resulting amide with either LiA1H4. For the preparation of the phenylacetyl (PA) and 3-phenylpropionyl (PP) derivatives, the corresponding amino acids were coupled in the usual manner with phenylacetyl chloride or 3-phenylpropionyl chloride in the presence of either NaOH(PA-LD- and DL-Pgly. 3-Phenylpropionyl chloride (4) was treated with diazomethane to give diazoketone. Allyloxy resin 12 was acylated with 3-phenylpropionyl chloride and treated with 50% TFA for 1 h followed by treatment with Pd(PPh3)4/PPh3 in solution to furnish the desired hydrox- amic acid.

备注
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, amines, alcohols, active metals, bases, water, moisture.

基本信息

MDL
MFCD00000748

EINECS
211-443-6

分子式
C₆H₅(CH₂)₂COCl

分子量
168.62

熔点
-7°

沸点
225°

闪点
108°(226°F)

密度
1.135

折射率
1.5265

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Soluble in water (reacts), and ether.

Beilstein
742586

GHS危害和防范说明

GHS符号

Hazard Statements
H332-H314-H318
Harmful if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
20-34
Harmful by inhalation.Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

RTECS
MW5652395

TSCA
是

C13438

Alfa Aesar

Hydrocinnamoyl Chloride

98%

1759元/25g; 5108元/100g;

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基本信息

Ref#
13438

MDL
748

分子式
C9 H9 Cl O

分子量
168.62

闪点
108

密度
1137

形态
Liquid

安全信息

危险等级
8

包装组
II

249440

Sigma-Aldrich

Hydrocinnamoyl Chloride

98%

250.15元/5 G; 481.43元/25 G;

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产品说明

一般描述

已经通过循环伏安法研究了在含有高氯酸四烷基铵的乙腈中的汞阴极处的氢肉桂酰氯的还原。

应用

氢肉桂酰氯已用于：

防污剂(+)-马来酸内酯 A 的对映选择性合成
氢肉桂酰基-法呢基-L-半胱氨酸甲酯的合成

包装

5, 25 g in glass bottle

基本信息

线性分子式	C₆H₅CH₂CH₂COCl
分子量	168.62
Beilstein	742586
EC 号	211-443-6
MDL编号	MFCD00000748
PubChem化学物质编号	24854993

产品性质

质量水平	100
测定	98%
形式	liquid
折射率	n20/D 1.5265 (lit.)
bp	107 ℃/11 mmHg (lit.)
mp	−7-−5 ℃ (lit.)
密度	1.135 g/mL at 25 ℃ (lit.)
SMILES string	ClC(=O)CCc1ccccc1
InChI	1S/C9H9ClO/c10-9(11)7-6-8-4-2-1-3-5-8/h1-5H,6-7H2
InChI key	MFEILWXBDBCWKF-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314 - H331
预防措施声明	P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 3 Inhalation - Skin Corr. 1B
储存分类代码	6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK	WGK 3
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

990984

Amethyst

3-Phenylpropionyl Chloride

98%, 用于合成

68元/5G; 172元/25G; 542元/100G;

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基本信息

分子式	C₉H₉ClO
分子量	168.62
熔点	-7 - -5
沸点	107
闪点	108
密度	1.135
折光率(n20D)	1.5260 - 1.5280
MDL编码	MFCD00000748
Beilstein	742586
EINECS 编号	211-443-6

安全信息

图形或危害标志
提示语	Danger
危险说明	H314 H332
防范说明	P280 P305+P351+P338 P314
UN号码	3265
危险分类	8
包装等级	II
WGK	3
RTECS	MW5652395
TSCA	是

448612

Fluorochem

3-Phenylpropanoyl chloride

95%

220元/1g; 264元/10g; 506元/25g; 1606元/100g;

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基本信息

CAS Number	645-45-4
MDL Number	MFCD00000748
Boiling Point	225℃
Density	1.14

安全信息

图形或危害标志
危险性说明	H290: May be corrosive to metals. H314: Causes severe skin burns and eye damage. H332: Harmful if inhaled.
防范说明	P234: Keep only in original container. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P363: Wash contaminated clothing before reuse. P390: Absorb spillage to prevent material damage. P405: Store locked up. P406: Store in corrosive resistant/ container with a resistant inner liner. P501: Dispose of contents/container to local regulations.