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CAS: 64-20-0
分子式: C4H12BrN
分子量: 154.05
沸点: 360℃
熔点: 300℃
中文名称: 
四甲基溴化铵
四甲基溴化胺
英文名称: 
Tetramethyl ammonium bromide
Methanaminium, N,N,N-trimethyl-, bromide
tetramethyl-ammoniu bromide
n,n,n-trimethyl-methanaminiu bromide
(dimethylamino)-methy methobromide
n,n,n-trimethylmethanaminium bromide
tetramethylammonium bromide
Methanaminium,N,N,N-trimethyl-,bromide
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T819490MACKLIN四甲基溴化铵试剂级, 98%42元/25g;   120元/100g;   503元/500g;   2250元/2.5kg;   展开
储存:室温,干燥
状态:白色结晶粉末
T819927MACKLIN四甲基溴化铵离子对色谱级,≥99.0%(AT)52元/2g;   199元/10g;   448元/50g;   1634元/250g;   展开
储存:室温,干燥
状态:白色粉末或晶体
T0135TCITetramethylammonium Bromide>97.0%(T)175元/25G;   1055元/500G;   展开

基本信息

纯度/分析方法>97.0%(T)
分子式/分子量C4H12BrN = 154.05
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN3620955
PubChem物质ID87576138
SDBS (AIST Spectral DB)4162
MDL编号MFCD00011626

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Nonaqueous Titration)min. 97.0 %
Solubility in Wateralmost transparency

物性(参考值)

水溶性可溶
溶解度(极微溶)乙醇
溶解性(不溶于)乙醚,氯仿

安全信息

图形或危害标志
信号词危险
危险性说明H300 : 吞咽致命。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#BS7600000

运输信息

UN编号UN2811
类别6.1
包装类别 II
监管条件代码(*)
217373J&KTetramethylammonium Bromide99%101元/25g;   332元/100G;   907元/500G;   展开

基本信息

分子式C4H12BrN
分子量154.05
熔点>300
MDL编码MFCD00011626
EINECS 编号200-581-2

安全信息

图形或危害标志
提示语Danger
危险说明H301
H316
H320
H335
防范说明P281
P305+P351+P338
P308+P313
P314
UN号码2811
危险分类6.1
包装等级II
WGK3
RTECSBS7600000
TSCA
A13368Alfa AesarTetramethylammonium Bromide98%605元/100g;   2258元/500g;   8703元/2500g;   展开

应用
Tetramethylammonium bromide acts as an ion pair reagent. It is used as a surface-active agent and an active ingredient for conditioners. Further, it is used as a softner for textiles and paper products. It is also employed as a disinfection agent, sanitizer, antimicrobial and antistatic agent. In addition to this, it plays in important role as a phase transfer catalyst in synthetic chemistry.

备注
Hygroscopic. Incompatible with oxidizing agents and strong bases.

基本信息

MDL
MFCD00011626

EINECS
200-581-2

分子式
C4H12BrN

分子量
154.06

熔点
>300°

密度
1.56

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water, alcohol, chloroform and acetone.

Beilstein
3620955

GHS危害和防范说明

GHS符号

Hazard Statements
H300-H315-H319-H335
Fatal if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280h-P305+P351+P338-P309-P310
Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
6.1

包装组
II

危险类别
25-36/37/38
Toxic if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

RTECS
BS7600000

TSCA

C18763Alfa AesarTetramethylammonium Bromide98%914元/100g;   5228元/500g;   展开

基本信息

Ref#
18763

MDL
11626

分子式
C4 H12 Br N

分子量
154.05

形态
Crystalline

安全信息

危险等级
6.1

包装组
II

195758Sigma-AldrichTetramethylammonium Bromide98%289.75元/100 G;   1037.59元/500 G;   展开

产品说明

一般描述

四甲基溴化铵(TMABr)是一字红季铵盐。已经在各种温度(20、25和30℃)下测量了其水溶液的绝对粘度。已经评估了TMABr的各种物理性质(活性系数取决于饱和度、电导系数、密度以及在水中的溶解度)。 已经研究了它对下列Fe(II) 螯合物碱水解的一级速率常数值的影响:4

  • 双(亚二氢萘基丙氨酸)(nali)
  • 双(亚二氢萘基苯基丙氨酸)(nphali)
  • 双(亚二氢萘基天冬氨酸)(nasi)
  • (亚二氢萘基组氨酸)(nhi)
  • 双(亚二氢萘基精氨酸)(nari)

四丁基溴化铵是一种季铵化合物,被广泛用作相转移催化剂。 已经在各种温度(20、25和30℃)下测量了其水溶液的绝对粘度。已经评估了TMABr的各种物理性质(活性系数取决于饱和度、电导系数、密度以及在水中的溶解度)。

应用

四甲基溴化铵可用作合成小胶体沸石Y纳米晶体的模板。
熔融状态的四丁基溴化铵可以用于以下过程:

  • 合成(2S)-5-(3-苯基-2-邻苯二甲酰亚氨基丙酰基氨基)间苯二甲酸。
  • 在不存在催化剂和有机溶剂的情况下,合成烷基取代的吡咯。
  • 在无溶剂环境中通过转硫缩醛反应从缩醛合成二硫代缩醛。
  • 通过对苯二甲酸和二异氰酸酯的聚合反应合成聚酰胺(PA)。
  • 催化硫醇加成,形成共轭烯烃。
  • 聚(氯乙烯)的脱氯化氢反应。

包装

100, 500 g in poly bottle

基本信息

线性分子式(CH3)4N(Br)
分子量154.05
Beilstein3620955
EC 号200-581-2
MDL编号MFCD00011626
PubChem化学物质编号57647797
NACRESNA.21

产品性质

质量水平100
测定98%
mp>300 ℃ (lit.)
SMILES string[Br-].C[N+](C)(C)C
InChI1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI keyDDFYFBUWEBINLX-UHFFFAOYSA-M

安全信息

象形图GHS06
警示用语:Danger
危险声明H300
预防措施声明P301 + P330 + P331 + P310
危险分类Acute Tox. 2 Oral
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
426296Sigma-AldrichTetramethylammonium BromideACS reagent, ≥98.0%174.12元/25 G;   546.54元/100 G;   展开

产品说明

应用

Tetrabutylammonium bromide (TBAB) may be used in the molten state in the following processes:

  • Synthesis of (2S)-5-(3-phenyl-2-phthalimidylpropanoylamino)isophthalic acid.
  • Synthesis of alkyl-substituted pyrroles in the absence of catalyst and organic solvent.
  • Synthesis of dithioacetals from acetals by transthioacetalisation in a solvent free environment.
  • Synthesis of polyamides (PAs) by the polymerization of terephthalic acid and diisocyanates.
  • Catalyze the addition of thiols to conjugated alkenes.
  • Dehydrochlorination of poly(vinyl chloride).

包装

25, 100 g in poly bottle

基本信息

线性分子式(CH3)4N(Br)
分子量154.05
Beilstein3620955
EC 号200-581-2
MDL编号MFCD00011626
PubChem化学物质编号24866694
NACRESNA.21

产品性质

质量水平200
等级ACS reagent
测定≥98.0%
杂质≤0.5% trimethylamine hydrobromide
≤0.5% trimethylamine
mp>300 ℃ (lit.)
SMILES string[Br-].C[N+](C)(C)C
InChI1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI keyDDFYFBUWEBINLX-UHFFFAOYSA-M

安全信息

象形图GHS06
警示用语:Danger
危险声明H300
预防措施声明P301 + P330 + P331 + P310
危险分类Acute Tox. 2 Oral
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
V900079Sigma-AldrichTetramethylammonium BromideVetec, reagent grade, 98%90.02元/25 G;   263.46元/100 G;   展开

产品说明

包装

25, 100 g in poly bottle

法律信息

Vetec is a trademark of sigma-aldrich International GmbH

基本信息

线性分子式(CH3)4N(Br)
分子量154.05
Beilstein3620955
EC 号200-581-2
MDL编号MFCD00011626
PubChem化学物质编号329829519

产品性质

等级reagent grade
产品线Vetec
测定98%
mp>300 ℃ (lit.)
SMILES string[Br-].C[N+](C)(C)C
InChI1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI keyDDFYFBUWEBINLX-UHFFFAOYSA-M

安全信息

象形图GHS06
警示用语:Danger
危险声明H300
预防措施声明P301 + P330 + P331 + P310
危险分类Acute Tox. 2 Oral
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
87708SupelcoTetramethylammonium Bromidesuitable for ion pair chromatography, LiChropur, ≥99.0% (AT)4781.02元/10 G;   展开

产品说明

一般描述

Ion-pairing reagents, when used as mobile phase additives, promote the analysis of ionic and highly polar substances on reversed phase HPLC columns. The purity of mobile phase additives is of highest significance for their effective application. sigma-aldrich makes available a variety of tailor-made reagents for anionic (quaternary ammonium and phosphonium salts) and cationic (alkanesulfonates) separations. All mobile phase additives are tested thoroughly with special consideration on the demands of modern reversed phase HPLC:

推荐产品

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

基本信息

线性分子式(CH3)4N(Br)
分子量154.05
Beilstein3620955
EC 号200-581-2
MDL编号MFCD00011626
PubChem化学物质编号329769598
NACRESNB.21

产品性质

质量水平100
描述cationic
测定≥99.0% (AT)
质量LiChropur
technique(s)ion pair chromatography: suitable
mp>300 ℃ (lit.)
λ10 % in H2O
紫外吸收λ: 240 nm Amax: 0.06
λ: 250 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02
适用性corresponds to standard for filter test
SMILES string[Br-].C[N+](C)(C)C
InChI1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI keyDDFYFBUWEBINLX-UHFFFAOYSA-M

安全信息

象形图GHS06
警示用语:Danger
危险声明H300
预防措施声明P301 + P330 + P331 + P310
危险分类Acute Tox. 2 Oral
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
302678AmethystTetramethylammonium bromide, for analysis用于分析59元/25G;   162元/100G;   482元/500G;   展开

基本信息

分子式C4H12BrN
分子量154.05
熔点>300
MDL编码MFCD00011626
EINECS 编号200-581-2

安全信息

图形或危害标志
提示语Danger
危险说明H301
H316
H320
H335
防范说明P281
P305+P351+P338
P308+P313
P314
UN号码2811
危险分类6.1
包装等级II
WGK3
RTECSBS7600000
TSCA
901935AmethystTetramethylammonium Bromide98%, 试剂级58元/25G;   113元/100G;   401元/500G;   展开

基本信息

分子式C4H12BrN
分子量154.05
熔点>300
MDL编码MFCD00011626
EINECS 编号200-581-2

安全信息

图形或危害标志
提示语Danger
危险说明H301
H316
H320
H335
防范说明P281
P305+P351+P338
P308+P313
P314
UN号码2811
危险分类6.1
包装等级II
WGK3
RTECSBS7600000
TSCA
494404FluorochemTetramethylammonium Bromide98%308元/100g;   1408元/500g;   13618元/5kg;   展开

基本信息

CAS Number64-20-0
MDL NumberMFCD00011626

安全信息

图形或危害标志
危险性说明 H300: Fatal if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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