| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| E823981 | MACKLIN | 4-氯乙酰乙酸乙酯 | 98% | 29元/10ml; 42元/50ml; 94元/250ml; 300元/1L; 1475元/5L; | 展开 |
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| C0911 | TCI | Ethyl 4-Chloroacetoacetate | >95.0%(GC) | 225元/25G; 1690元/500G; | 展开 |
基本信息 | 纯度/分析方法 | >95.0%(GC) | | 分子式/分子量 | C6H9ClO3 = 164.59 | | 外观与形状(20℃) | 液体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 1761275 | | PubChem物质ID | 87565964 | | SDBS (AIST Spectral DB) | 10328 | | MDL编号 | MFCD00000939 |
技术规格 | Appearance | Colorless to Light orange to Yellow clear liquid | | Purity(GC) | min. 95.0 % |
物性(参考值) | 熔点 | -8 ℃ | | 沸点 | 120 ℃/15 mmHg | | 闪点 | 96 ℃ | | 比重 | 1.21 | | 折射率 | 1.45 | | 水溶性 | 不溶 |
安全信息 | 图形或危害标志 |   | | 信号词 | 危险 | | 危险性说明 | H301 : 吞咽会中毒。
H314 : 造成严重皮肤灼伤和眼损伤。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。
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相关法规 运输信息 | UN编号 | UN2922 | | 类别 | 8 / 6.1 | | 包装类别 | III | | 监管条件代码(*) | |
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| 114658 | J&K | Ethyl 4-Chloroacetoacetate | 98% | 170元/50G; 685元/250G; 1803元/1KG; | 展开 |
基本信息 | 分子式 | C6H9ClO3 | | 分子量 | 164.59 | | 沸点 | 115 | | 闪点 | 105 | | 密度 | 1.218 | | 折光率(n20D) | 1.4520 | | MDL编码 | MFCD00000939 | | Beilstein | 1761275 | | EINECS 编号 | 211-317-0 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H301
H314 | | 防范说明 | P280
P305+P351+P338
P301+P310 | | UN号码 | 2922 | | 危险分类 | 8 | | 次要危险性 | 6.1 | | 包装等级 | II | | WGK | 3 | | RTECS | AK5110000 | | TSCA | 是 |
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| A15641 | Alfa Aesar | Ethyl 4-Chloroacetoacetate | 97% | 276元/50g; 1009元/250g; 2716元/1000g; | 展开 |
应用
Ethyl 4-chloroacetoacetate is used as a precursor in the preparation of phosphorous ylides. It finds application in regular film coating, pharmaceutical coating and formulation. 备注
Incompatible with strong acids, strong bases, reducing agents and strong oxidizing agents. Store in a cool place. 基本信息 MDL
MFCD00000939 EINECS
211-317-0 分子式
C6H9ClO3 分子量
164.59 熔点
-8° 沸点
220° 闪点
92°(198°F) 密度
1.212 折射率
1.4520 灵敏度
Ambient temperatures. 形态
Liquid 溶解性
Miscible with water and most organic solvents. Beilstein
1761275 GHS危害和防范说明 GHS符号
 Hazard Statements
H227-H301-H314-H318-H401-H411
Combustible liquid.Toxic if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.Toxic to aquatic life.Toxic to aquatic life with long lasting effects. Precautionary Statements
P210e-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
6.1 包装组
II 危险类别
25-34-51/53
Toxic if swallowed.Causes burns.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 安全等级
26-36/37/39-45-57
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Use appropriate container to avoid environmental contamination. 欧盟危险品标志
 RTECS
AK5110000 TSCA
是 |
| C17764 | Alfa Aesar | Ethyl 4-Chloroacetoacetate | 98% | 608元/50g; 1929元/250g; | 展开 |
基本信息 Ref#
17764 MDL
939 分子式
C6 H9 Cl O3 分子量
164.59 闪点
96 密度
1.21 安全信息 危险等级
6.1 包装组
II |
| 180769 | Sigma-Aldrich | Ethyl 4-Chloroacetoacetate | 95% | 312.19元/50 G; 987.38元/250 G; | 展开 |
产品说明 应用 4-氯乙酰乙酸乙酯用于合成磷叶立德。 包装 50, 250 g in glass bottle 基本信息 | 线性分子式 | ClCH2COCH2CO2C2H5 | | 分子量 | 164.59 | | Beilstein | 1761275 | | EC 号 | 211-317-0 | | MDL编号 | MFCD00000939 | | PubChem化学物质编号 | 24850895 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 95% | | 形式 | liquid | | 折射率 | n20/D 1.452 (lit.) | | bp | 115 ℃/14 mmHg (lit.) | | 密度 | 1.218 g/mL at 25 ℃ (lit.) | | SMILES string | CCOC(=O)CC(=O)CCl | | InChI | 1S/C6H9ClO3/c1-2-10-6(9)3-5(8)4-7/h2-4H2,1H3 | | InChI key | OHLRLMWUFVDREV-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H301 + H311 - H314 - H411 | | 预防措施声明 | P270 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 | | 危险分类 | Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B | | 储存分类代码 | 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials | | WGK | WGK 3 | | 闪点(F) | 206.6 °F - closed cup | | 闪点(C) | 97 ℃ - closed cup | | 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
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| 690295 | Sigma-Aldrich | Ethyl 4-Chloroacetoacetate | Arxada quality, ≥97.0% (GC) | 3204.12元/1 KG; 70888.1元/25 KG; | 展开 |
基本信息 | 线性分子式 | ClCH2COCH2CO2C2H5 | | 分子量 | 164.59 | | Beilstein | 1761275 | | EC 号 | 211-317-0 | | MDL编号 | MFCD00000939 | | PubChem化学物质编号 | 329761327 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | ≥97.0% (GC) | | 形式 | liquid | | 质量 | Arxada quality | | manufacturer/tradename | Arxada AG | | 杂质 | ≤0.04% metyl-4-chloroacetoacetate | | 折射率 | n20/D 1.452 (lit.) | | bp | 115 ℃/14 mmHg (lit.) | | 密度 | 1.218 g/mL at 25 ℃ (lit.) | | 储存温度 | 2-8℃ | | SMILES string | CCOC(=O)CC(=O)CCl | | InChI | 1S/C6H9ClO3/c1-2-10-6(9)3-5(8)4-7/h2-4H2,1H3 | | InChI key | OHLRLMWUFVDREV-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H301 + H311 - H314 - H411 | | 预防措施声明 | P270 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 | | 危险分类 | Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B | | 储存分类代码 | 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials | | WGK | WGK 3 | | 闪点(F) | 206.6 °F - closed cup | | 闪点(C) | 97 ℃ - closed cup | | 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
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| 214988 | Fluorochem | Ethyl 4-chloro-3-oxobutanoate | 95% | 264元/50g; 528元/100g; 1100元/250g; | 展开 |
基本信息 | CAS Number | 638-07-3 | | MDL Number | MFCD00000939 | | Density | 1.218 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
| | 防范说明 | P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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