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CAS: 636-61-3
分子式: C4H6O5
分子量: 134.08
熔点: 98-104℃
中文名称: 
D(+)-羟基丁二酸
D(+)-羟基琥珀酸
D-(+)-苹果酸
(R)-羟基丁二酸
D-苹果酸
D(+)-苹果酸
D-丁醇二酸
英文名称: 
hydroxy-, ( R )-Butanedioic acid
l(+)-malic aci
l(+)-malic acid
d(+)-malic acid
D-Malic acid
d-(+)-malic acid
(R)-(+)-2-Hydroxysuccinic acid
(R)-(+)-Hydroxysuccinic acid
D-(+)-Apple Acid
Butanedioic acid,hydroxy-,(R)-
推荐供应商
货号品牌产品名称规格包装、参考价格
D813473MACKLIND-苹果酸99%28元/1g;   59元/5g;   99元/25g;   299元/100g;   1364元/500g;   2698元/1kg;   咨询
储存:室温
状态:白色至淡黄色粉末
折射率:6.5 ° (C=10, Acetone)
M0021TCID-(+)-Malic Acid>98.0%(GC)(T)330元/5G;   1045元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C4H6O5 = 134.09
外观与形状(20℃)固体
Reaxys-RN1723540
PubChem物质ID87572139
SDBS (AIST Spectral DB)10028
Merck Index (14)5707
MDL编号MFCD00004245

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Optical purity(GC)min. 98.0 ee%
Purity(Neutralization titration)min. 98.0 %
Melting point101.0 to 105.0 ℃

物性(参考值)

熔点103 ℃
比旋光度 [α]D6.5° (C=10,Acetone)

安全信息

图形或危害标志
信号词危险
危险性说明H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。

相关法规

RTECS#ON7260000
120279J&KD-(+)-Malic Acid99%68元/1G;   272元/5G;   824元/25G;   2715元/100G;   咨询

基本信息

分子式C4H6O5
分子量134.09
熔点98-102
比旋光度([α]20D)+ 6.0° to + 7.0° (C=10, Acetone)
MDL编码MFCD00004245
Beilstein1723540
Merck14,5707
EINECS 编号211-262-2
存储条件Room temperature

安全信息

图形或危害标志
提示语Danger
危险说明H315
H318
H335
防范说明P261
P280
P305+P351+P338
WGK3
RTECSON7260000
TSCA
A11688Alfa AesarD-(+)-Malic Acid98+%261元/1g;   937元/5g;   1879元/25g;   咨询

应用
D-(+)-Malic acid used as an acidulant and flavoring agent, food additive. And it is also used in the place of the less sour citric acid in sour sweets.

备注
Store in cool, dry conditions in well sealed containers. Keep container tightly closed.

基本信息

MDL
MFCD00004245

EINECS
211-262-2

分子式
C4H6O5

分子量
134.09

熔点
100-104°

密度
1.60

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in methanol, ethanol, acetone, ether.

Beilstein
1723540

Merck
14,5707

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H318-H335
Causes skin irritation.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
37/38-41
Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
26-37/39-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.This material and its container must be disposed of as hazardous waste

RTECS
ON7260000

TSCA

C15350Alfa AesarD(+)-Malic acid98%750元/1g;   1258元/5g;   5382元/25g;   咨询

基本信息

Ref#
15350

MDL
4245

分子式
C4 H6 O5

分子量
134.09

02300Sigma-AldrichD-(+)-Malic acidunnatural form, ≥97.0% (T)497.3元/1G;   730.96元/5G;   1413.4元/25G;   咨询

产品说明

应用

D-(+)-苹果酸可用于:

  • 作为对映选择性全合成 (−)-erinapyrone B的起始材料。
  • 作为从各种醛、苯胺和亚磷酸二乙酯合成α-氨基膦酸酯的手性有机催化剂。

其他说明

斯克里普斯代谢组学和质谱技术中心独立生成的串联质谱数据可在PDF ( 02300.pdf ) 中查看或下载。斯克里普斯代谢物组学和质谱技术中心的METLIN代谢物数据库中有测试代谢物。要了解更多信息,请访问sigma.com/metlin。

基本信息

线性分子式HO2CCH2CH(OH)CO2H
分子量134.09
Beilstein1723540
EC 号211-262-2
MDL编号MFCD00004245
PubChem化学物质编号329747411
NACRESNA.22

产品性质

质量水平200
测定≥97.0% (T)
旋光性[α]20/D +28.0±2°, c = 5.5% in pyridine
质量unnatural form
mp98-102 ℃ (lit.)
SMILES stringO[C@H](CC(O)=O)C(O)=O
InChI1S/C4H6O5/c5-2(4(8)9)1-3(6)7/h2,5H,1H2,(H,6,7)(H,8,9)/t2-/m1/s1
InChI keyBJEPYKJPYRNKOW-UWTATZPHSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H315 - H318 - H335
预防措施声明P261 - P280 - P305 + P351 + P338
危险分类Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
46940-USupelcoD-Malic acidanalytical standard508.71元/1 KIT;   咨询

产品说明

应用

有关合适仪器技术的更多信息,请参考产品′分析证书。如需进一步支持,请联系技术服务。

基本信息

线性分子式HO2CCH2CH(OH)CO2H
分子量134.09
Beilstein1723540
EC 号211-262-2
MDL编号MFCD00004245
PubChem化学物质编号329757271
E编号E296
NACRESNA.24

产品性质

质量水平100
等级analytical standard
CofAcurrent certificate can be downloaded
包装ampule of 100 mg
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp98-102 ℃ (lit.)
application(s)cleaning products
cosmetics
food and beverages
personal care
格式neat
储存温度2-30℃
SMILES stringO[C@H](CC(O)=O)C(O)=O
InChI1S/C4H6O5/c5-2(4(8)9)1-3(6)7/h2,5H,1H2,(H,6,7)(H,8,9)/t2-/m1/s1
InChI keyBJEPYKJPYRNKOW-UWTATZPHSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H315 - H318 - H335
预防措施声明P280 - P302 + P352 - P305 + P351 + P338 + P310
危险分类Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
040082FluorochemD-(+)-Malic Acid99%220元/1g;   462元/25g;   1188元/100g;   5346元/500g;   咨询

基本信息

CAS Number636-61-3
MDL NumberMFCD00004245

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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