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CAS: 6320-01-0
分子式: C6H5BrS
分子量: 189.08
沸点: 123-124℃
中文名称: 
间溴苯硫酚
3-溴苯硫酚
英文名称: 
3-Bromobenzenethiol
3-Bromophenyl mercaptan
m-Bromothiophenol
3-bromothiophenol
性质描述: 沸点123-124℃(5.32kPa),119-121℃(2.67-2.93kPa),相对密度1.832,折光率1.6324,闪点105℃。
生产方法: 由间溴苯胺盐酸经重氮化、置换而得。将间溴苯胺酸盐、水加入反应锅,搅拌下慢慢滴加浓盐酸使全部溶解。冷却至0℃左右,缓缓滴加亚硝酸钠溶液,加毕,保温0.5h,得间溴苯胺重氮化溶液备用。另将乙基黄原酸钾水溶液加入反应锅,加热至45-50℃,缓缓加入重氮液,加毕,保温0.5h。用苯提取,提取液回收苯后,加入乙醇和氢氧化钾搅拌回流7h,回收乙醇至干,用3.6倍量的水使全部溶解,以稀硫酸调节pH至4,过滤,用苯提取,回收苯,减压蒸馏,收集120℃(2.93kPa)馏分而得成品。
用途: 医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
B802442MACKLIN3-溴苯硫酚98%36元/1g;   82元/5g;   405元/25g;   1549元/100g;   咨询
储存:2~8°C
状态:无色到浅黄色液体
折射率:n20/D 1.634(lit.)
B2348TCI3-Bromobenzenethiol>98.0%(GC)820元/5G;   2150元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C6H5BrS = 189.07
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN1926242
PubChem物质ID87565171
MDL编号MFCD00009603

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点121 ℃/22 mmHg
闪点105 ℃
比重1.60
折射率1.63

安全信息

图形或危害标志
信号词危险
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN1760
类别8
包装类别 III
监管条件代码(*)
102214J&K3-Bromothiophenol98%135元/1G;   344元/5G;   1372元/25G;   咨询

基本信息

分子式C6H5BrS
分子量189.07
沸点123-124
闪点105
密度1.832
折光率(n20D)1.6340
MDL编码MFCD00009603
Beilstein1926242
EINECS 编号228-664-9

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
UN号码3334
危险分类9
包装等级III
WGK3
TSCA
B25092Alfa Aesar3-Bromothiophenol97%559元/1g;   1906元/5g;   9030元/25g;   咨询

基本信息

MDL
MFCD00009603

EINECS
228-664-9

分子式
C6H5BrS

分子量
189.08

沸点
119-121°/21mm

闪点
105°(221°F)

密度
1.599

折射率
1.6324

形态
Liquid

Beilstein
1926242

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
23-26-37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

C30371Alfa Aesar3-Bromothiophenol95%963元/1g;   3242元/5g;   咨询

基本信息

Ref#
30371

MDL
9603

分子式
C6 H5 Br S

分子量
189.07

闪点
105

密度
1632

安全信息

危险等级
6.1

包装组
III

001578Fluorochem3-Bromothiophenol98%220元/1g;   4026元/25g;   11352元/100g;   咨询

基本信息

CAS Number6320-01-0
MDL NumberMFCD00009603
Boiling Point119-121℃/40mmHg
Density1.6

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations..
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