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CAS: 6315-52-2
分子式: C16H18O6S2
分子量: 370.44
熔点: 126-129℃
中文名称: 
乙二醇二邻甲苯磺酸盐
英文名称: 
Ethylene di(p-toluenesulfonate)
Ethylene ditosylate
Ethylene glycol ditosylate
1,2-Bis(tosyloxy)ethane
1,2-Bis(p-toluenesulfonyloxy)ethane
Ethylene Glycol Bis(p-toluenesulfonate)
ethylene glycol bis-p-toluenesulfonate
1,2-ethanediol bis(4-methylbenzenesulfonate)
推荐供应商
货号品牌产品名称规格包装、参考价格详情
E836656MACKLIN亚乙基二(p-甲苯磺酸盐)97%29元/5g;   104元/25g;   389元/100g;   1826元/500g;   展开
储存:室温,密封,干燥
状态:白色晶体粉末
E0438TCI1,2-Bis(tosyloxy)ethane>99.0%(HPLC)835元/25G;   2110元/100G;   展开

基本信息

纯度/分析方法>99.0%(HPLC)
分子式/分子量C16H18O6S2 = 370.43
外观与形状(20℃)固体
Reaxys-RN2399520
PubChem物质ID87569694
MDL编号MFCD00008549

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 99.0 area%
Melting point126.0 to 129.0 ℃

物性(参考值)

熔点128 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
B21539Alfa AesarEthylene glycol bis-p-toluenesulfonate97%1053元/10g;   3759元/50g;   11945元/250g;   展开

应用
Ethylene di(p-toluenesulfonate) [Ethylene glycol ditosylate] has been used in the synthesis of, cyclohexyl-fused 1,4,7-triazacyclononane, 1,2-ethylenecalix[6]arene, 1,3- and 1,4-calix[6]crown-3, 1,3- and 1,4-calix[6]crown-4, 1,4-calix[6]benzocrown-4, 1,2- and 1,3-calix[6]crown-5.

备注
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

基本信息

MDL
MFCD00008549

分子式
C16H18O6S2

分子量
370.45

熔点
122-127°

灵敏度
Ambient temperatures.

形态
Crystals

溶解性
Slightly soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

296791Sigma-AldrichEthylene di(p-toluenesulfonate)97%249.76元/5 G;   1154.18元/25 G;   展开

产品说明

应用

Ethylene di(p-toluenesulfonate) [Ethylene glycol ditosylate] has been used in the synthesis of:

  • cyclohexyl-fused 1,4,7-triazacyclononane
  • 1,2-ethylenecalix[6]arene, 1,3- and 1,4-calix[6]crown-3, 1,3- and 1,4-calix[6]crown-4, 1,4-calix[6]benzocrown-4, 1,2- and 1,3-calix[6]crown-5

包装

5, 25 g in glass bottle

基本信息

线性分子式[CH3C6H4SO3CH2-]2
分子量370.44
Beilstein2399520
MDL编号MFCD00008549
PubChem化学物质编号24857876
NACRESNA.22

产品性质

测定97%
mp124-127 ℃ (lit.)
SMILES stringCc1ccc(cc1)S(=O)(=O)OCCOS(=O)(=O)c2ccc(C)cc2
InChI1S/C16H18O6S2/c1-13-3-7-15(8-4-13)23(17,18)21-11-12-22-24(19,20)16-9-5-14(2)6-10-16/h3-10H,11-12H2,1-2H3
InChI keyLZIPBJBQQPZLOR-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
228146FluorochemEthane-1,2-diyl bis(4-methylbenzenesulfonate)95%264元/5g;   462元/10g;   858元/25g;   2574元/100g;   展开

基本信息

CAS Number6315-52-2
MDL NumberMFCD00008549

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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