CAS 6294-89-9; 肼基甲酸甲酯; hydrazinecarboxylic acid, methyl ester

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货号

品牌

产品名称

规格

包装、参考价格

M813208

MACKLIN

肼甲酸甲酯

97%

29元/25g; 35元/100g; 145元/500g; 286元/1kg;

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储存：室温
状态：白色晶体

C1098

TCI

Methyl Carbazate

>98.0%(GC)(T)

230元/25G; 1590元/500G;

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基本信息

纯度/分析方法	>98.0%(GC)(T)
分子式/分子量	C₂H₆N₂O₂ = 90.08
外观与形状(20℃)	固体
Reaxys-RN	1679395
PubChem物质ID	87566129
SDBS (AIST Spectral DB)	23604
MDL编号	MFCD00007594

技术规格

Appearance	White to Light yellow powder to crystal
Purity(GC)	min. 98.0 %
Purity(Nonaqueous Titration)	min. 98.0 %
Melting point	72.0 to 74.0 ℃

物性(参考值)

熔点	73 ℃
沸点	108 ℃/12 mmHg

安全信息

图形或危害标志
信号词	危险
危险性说明	H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P311 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。呼叫急救中心/医生。 P403 + P233 : 存放在通风良好的地方。保持容器密闭。 P405 : 存放处须加锁。

运输信息

UN编号	UN2811
类别	6.1
包装类别	III
监管条件代码(*)

420793

J&K

Methyl hydrazinocarboxylate

99%

101元/25G; 337元/100G; 1153元/500G;

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基本信息

分子式	C₂H₆N₂O₂
分子量	90.08
熔点	70-73
沸点	108
MDL编码	MFCD00007594
Beilstein	1679395
EINECS 编号	228-560-3

安全信息

图形或危害标志
提示语	Danger
危险说明	H301 H315 H319 H335
防范说明	P261 P301+P310 P302+P352 P305+P351+P338 P405
UN号码	2811
危险分类	6.1
包装等级	III
WGK	3
TSCA	是

A14548

Alfa Aesar

Methyl Carbazate

98%

1351元/100g; 4597元/500g; 18256元/2500g;

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应用
Methyl carbazate was used in the preparation of methyl 3-(4-methyl-benzyl-idene)carbazate. It was also used in the synthesis of imidazo[1,5-d][1,2,4]triazines. It is used as pharmaceutical intermediate.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00007594

EINECS
228-560-3

分子式
C₂H₆N₂O₂

分子量
90.08

熔点
70-73°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water.

Beilstein
1679395

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
25-36/37/38
Toxic if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

TSCA
是

C16614

Alfa Aesar

Methyl hydrazinocarboxylate

97%

1140元/100g; 3593元/500g; 12687元/2.5kg;

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基本信息

Ref#
16614

MDL
7594

分子式
C2 H6 N2 O2

分子量
90.08

形态
White to pale cream cryst powder

安全信息

危险等级
6.1

包装组
III

151653

Sigma-Aldrich

Methyl hydrazinocarboxylate

97%

671.68元/100 G; 1672.02元/500 G;

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产品说明

应用

肼基甲酸甲酯(甲氧基羰酰肼)用于 3-(4-甲基苯亚甲基)咔唑酸甲酯的制备。也用于咪唑并 [1,5-d] [1,2,4] 三嗪的合成。

包装

100, 500 g in poly bottle

基本信息

线性分子式	H₂NNHCO₂CH₃
分子量	90.08
EC 号	228-560-3
MDL编号	MFCD00007594
PubChem化学物质编号	24849157
NACRES	NA.22

产品性质

质量水平	200
测定	97%
bp	108 ℃/12 mmHg (lit.)
mp	70-73 ℃ (lit.)
SMILES string	COC(=O)NN
InChI	1S/C2H6N2O2/c1-6-2(5)4-3/h3H2,1H3,(H,4,5)
InChI key	WFJRIDQGVSJLLH-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

094656

Fluorochem

Methyl hydrazinocarboxylate

97%

220元/1g; 308元/25g; 726元/100g; 2442元/500g;

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基本信息

CAS Number	6294-89-9
MDL Number	MFCD00007594

安全信息

图形或危害标志
危险性说明	H301: Toxic if swallowed. H311: Toxic in contact with skin. H331: Toxic if inhaled.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P311: Call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P361: Remove/Take off immediately all contaminated clothing. P363: Wash contaminated clothing before reuse. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.