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CAS: 624-84-0
分子式: CH4N2O
分子量: 60.06
熔点: 54-58℃
中文名称: 
甲酸肼
甲酰肼
英文名称: 
formic acid, hydrazide
carbazaldehyde
formal hydrazine
formhydrazid
formhydrazide
formic hydrazide
formohydrazide
formylhydrazide
formylhydrazine
formyl-hydrazin
hydrazinecarboxaldehyde
n-formylhydrazine
formic acid hydrazide
展开更多英文名
性质描述: 黄色叶状体或针状体结晶。熔点54℃。溶于苯,乙醇,乙醚,氯仿。
生产方法: 由甲酸乙酯与水合肼反应则得。将85%水合肼小心地加入甲酸乙酯和95%乙醇的溶液中,搅拌10min。当反应缓和后,将反应液加热回流18h,减压蒸出大部分水分和乙醇,即得糖浆状物粗品,进一步精制得到甲酰肼成品。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
F809631MACKLIN甲酰肼99%30元/5g;   128元/25g;   453元/100g;   1925元/500g;   咨询
储存:2~8°C,干燥
状态:白色到粉色粉末晶体和/或块状
F0667TCIFormohydrazide>97.0%(HPLC)360元/25G;   1070元/100G;   咨询

基本信息

纯度/分析方法>97.0%(HPLC)
分子式/分子量CH4N2O = 60.06
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿),加热
Reaxys-RN635759
PubChem物质ID354334127
MDL编号MFCD00007589

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 97.0 area%
Purity(Nonaqueous Titration)min. 95.0 %
Melting point56.0 to 61.0 ℃

物性(参考值)

熔点59 ℃
沸点90 ℃/0.7 mmHg

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#LQ8615000
552375J&KFormic Acid Hydrazide99%326元/25G;   1024元/100G;   咨询

基本信息

分子式CH4N2O
分子量60.06
熔点52-57
闪点112
MDL编码MFCD00007589
Beilstein635759
EINECS 编号210-867-9

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSLQ8615000
TSCA
A14901Alfa AesarFormic Acid Hydrazide98%1240元/25g;   3911元/100g;   咨询

应用
Formic acid hydrazide is used as a precursor in the preparation of 1,2,4-triazole derivatives. It is also used in the synthesis of 6-N-formylamino-12,13-dihydro-1,11-dihydroxy-13-(beta-D-glucopyranosyl)-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole-5,7(6H)-dione, which is an anticancer agent.

备注
Hygroscopic. Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00007589

EINECS
210-867-9

分子式
HCONHNH2

分子量
60.06

熔点
55-59°

闪点
>110°(230°F)

灵敏度
Keep Cold. Hygroscopic.

形态
Crystalline powder

溶解性
Soluble in water, ethanol and acetone.

Beilstein
635759

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
LQ8615000

TSCA

C37606Alfa AesarFormic Acid Hydrazide90%3318元/25g;   12024元/100g;   咨询

基本信息

Ref#
37606

MDL
7589

分子式
C H4 N2 O

分子量
60.06

闪点
112

形态
White cryst powder

安全信息

危险等级
6.1

包装组
III

166375Sigma-AldrichFormic Hydrazide567.84元/25 G;   1569.88元/100 G;   咨询

产品说明

应用

甲酰肼被用于合成1,2,4-三唑衍生物。它还被用于合成新型抗癌剂,6-N-甲酰氨基-12,13-二氢-1,11-二羟基-13-(β-D-吡喃葡萄糖基)-5H-吲哚[2,3-a]-吡咯并[3,4-c]咔唑-5,7(6H)-二酮。

包装

25, 100 g in glass bottle

基本信息

线性分子式HCONHNH2
分子量60.06
Beilstein635759
EC 号210-867-9
MDL编号MFCD00007589
PubChem化学物质编号24850161
NACRESNA.22

产品性质

质量水平100
mp52-57 ℃ (lit.)
溶解性water: soluble 2.5%, clear, colorless
SMILES string[H]C(=O)NN
InChI1S/CH4N2O/c2-3-1-4/h1H,2H2,(H,3,4)
InChI keyXZBIXDPGRMLSTC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)233.6 °F - closed cup
闪点(C)112 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
500444FluorochemFormic Acid Hydrazide95%264元/5g;   704元/25g;   2288元/100g;   10054元/500g;   咨询

基本信息

CAS Number624-84-0
MDL NumberMFCD00007589

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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