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CAS: 623-24-5
分子式: C8H8Br2
分子量: 263.96
沸点: 245 °C(lit.)
熔点: 143-145 °C(lit.)
中文名称: 
二溴对二甲苯
对-二溴甲苯
英文名称: 
Benzene,1,4-bis[bromomethyl]-
1,4-bis(bromomethyl)-benzen
α,α'-Dibromo-p-xylene
1,4-Bis(bromomethyl)benzene
p-Xylylene dibromide
à,à'-Dibromo-p-xylene
alpha,alpha'-Dibromo-p-xylene
p-Xylylene Bromide
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D806356MACKLINα,α'-二溴对二甲苯97%45元/5g;   155元/25g;   505元/100g;   2505元/500g;   4253元/1kg;   9382元/2.5kg;   展开
储存:室温
状态:白色到灰白色粉末,晶体和/或块状
折射率:1.614
D0216TCIα,α'-Dibromo-p-xylene>98.0%(GC)670元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C8H8Br2 = 263.96
外观与形状(20℃)固体
应避免的情况
Reaxys-RN1100019
PubChem物质ID87566929
SDBS (AIST Spectral DB)2021
MDL编号MFCD00000182

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Melting point144.0 to 147.0 ℃
Solubility in hot Toluenealmost transparency

物性(参考值)

熔点145 ℃
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H330 : 吸入致命。
H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P234 : 只能在原容器中存放。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN2928
类别6.1 / 8
包装类别 II
监管条件代码(*)
274426J&Kα,α'-Dibromo-p-xylene97%148元/5G;   573元/25G;   1770元/100G;   展开

基本信息

分子式C8H8Br2
分子量263.96
熔点143-145
沸点245
MDL编码MFCD00000182
Beilstein1100019
EINECS 编号210-781-1

安全信息

图形或危害标志
提示语Danger
危险说明H314
H330
防范说明P280
P305+P351+P338
P310
UN号码3448
危险分类6.1
包装等级II
WGK3
TSCA
A13939Alfa Aesarp-Xylylene Dibromide97%862元/10g;   2429元/50g;   展开

应用
It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals.

备注
Incompatible with alcohols, bases, amines, oxidizing agents. Avoid moisture.

基本信息

MDL
MFCD00000182

EINECS
210-781-1

分子式
C8H8Br2

分子量
263.96

熔点
144-148°

沸点
245°

密度
2.012

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water (react), and toluene.

Beilstein
1100019

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
6.1

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

C11294Alfa Aesaralpha,alpha'-Dibromo-p-xylene97%1668元/25g;   5338元/100g;   展开

基本信息

Ref#
11294

MDL
182

分子式
C8 H8 Br2

分子量
263.95

密度
2012

形态
White to cream cryst powder

安全信息

危险等级
6.1

包装组
II

S363081,4-BIS-BROMOMETHYL-BENZENEAldrichCPR1908.94元/100MG;   展开

产品说明

其他说明

Please note that sigma-aldrich provides this product to early discovery researchers as part of a collection of rare and unique chemicals. sigma-aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH'S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT AS-IS AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

基本信息

线性分子式C8H8Br2
分子量263.961
MDL编号MFCD00000182
34440Sigma-Aldrichα,α′-Dibromo-p-xylenepurum, ≥98.0% (GC)950.5元/25 G;   3500.81元/100 G;   展开

产品说明

应用

α, α′-Dibromo-p-xylene may be used in the preparation of:

  • third-generation bis(1-pyrazolyl)methane ligands
  • 5,5′-[(p-phenyl­enedimethyl­ene)dithio]bis­(1-phen­yl-1H-1,2,3,4-tetra­zole)
  • new bis 1,10-phenanthroline ligand (composed of two subunits of 7-(p-anisyl)-1,10-phenanthroline (phen) joined by p-(CH2)2C6H4(CH2)2 space groups at 4 positions), via Skraup synthesis
  • stereoisomers of α,α′-bis[3-(N,N-diethylcarbamoyl)-piperidino]-p-xylene

基本信息

线性分子式C6H4(CH2Br)2
分子量263.96
Beilstein1100019
EC 号210-781-1
MDL编号MFCD00000182
PubChem化学物质编号329754742
NACRESNA.22

产品性质

质量水平100
等级purum
测定≥98.0% (GC)
bp245 ℃ (lit.)
mp143-145 ℃ (lit.)
溶解性dioxane: soluble 1 g/10 mL (hot)
SMILES stringBrCc1ccc(CBr)cc1
InChI1S/C8H8Br2/c9-5-7-1-2-8(6-10)4-3-7/h1-4H,5-6H2
InChI keyRBZMSGOBSOCYHR-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
D44804Sigma-Aldrichα,α′-Dibromo-p-xylene97%377.73元/5 G;   1493.18元/25 G;   3177.48元/100 G;   展开

基本信息

线性分子式C6H4(CH2Br)2
分子量263.96
Beilstein1100019
EC 号210-781-1
MDL编号MFCD00000182
PubChem化学物质编号24893876
NACRESNA.22

产品性质

质量水平100
测定97%
bp245 ℃ (lit.)
mp143-145 ℃ (lit.)
SMILES stringBrCc1ccc(CBr)cc1
InChI1S/C8H8Br2/c9-5-7-1-2-8(6-10)4-3-7/h1-4H,5-6H2
InChI keyRBZMSGOBSOCYHR-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
940079Amethystα,α'-Dibromo-p-xylene97%, 试剂级89元/5G;   295元/25G;   984元/100G;   展开

基本信息

分子式C8H8Br2
分子量263.96
熔点143-145
沸点245
MDL编码MFCD00000182
Beilstein1100019
EINECS 编号210-781-1

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P314
UN号码3448
危险分类6.1
包装等级II
WGK3
TSCA
041016Fluorochemp-Xylylene Dibromide97%308元/5g;   660元/25g;   2508元/100g;   9438元/500g;   展开

基本信息

CAS Number623-24-5
MDL NumberMFCD00000182

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H331: Toxic if inhaled.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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